Herbicidal sulfonamides

ABSTRACT

This invention relates to a novel class of sulfonylureas and their use as herbicides and plant growth regulants.

RELATED APPLICATIONS

This application is a continuation in part of application Ser. No. 085,852, filed on Aug. 17, 1987, now abandoned which was a continuation in part of U.S. application Ser. No. 920,051, filed Oct. 17, 1986, now abandoned.

BACKGROUND OF THE INVENTION

The compounds of this invention are highly active, novel 3-substituted methyl sulfonylureas which are useful as herbicides and plant growth regulants.

EP-A-44,209 (Cognate) discloses herbicidal sulfonamides of formula ##STR1## wherein R is H, F, Cl, Br, NO₂, CF₃, C₁ -C₃ alkyl or C₁ -C₃ alkoxy;

R₁ is H, Cl or C₁ -C₄ alkyl;

R₂ is H or CH₃ ; and

L is, among other values, CO₂ R₁₀, CONR₃ R₄, CN, Cl, Br, NR₃ R₄, S(O)_(n) R₇, SO₂ NR₃ R₄, OR₉ and OC(O)R₁₁.

EP-A-112,803 discloses, in part, herbicidal sulfonamides of formula ##STR2##

South African patent application No. 84/2722 discloses herbicidal sulfonamides of formula ##STR3## wherein A is CR₆ R₇ XR₈, CR₉ R₁₀ R₁₁ or CHR₇ SCQR₂₁ ;

R₉ and R₁₀ are, among other values, H or CH₃ ;

R₁₁ is COR₂₄ or a C₁ -C₄ alkyl group substituted with, among other values, CN, NO₂, OH, C₁ -C₄ alkoxy, C₁ -C₄ alkylthio, C₁ -C₄ alkylsulfinyl, C₁ -C₄ alkylsulfonyl, C₁ -C₄ haloalkoxy, NR₁₂ R₁₃, SO₂ NR₁₅ R₁₆, SC(O)R₁₈, OC(O)R₁₈ and OSO₂ R₁₇ ;

R¹ includes H, halogen, NO₂, CN, C₁ -C₄ haloalkyl and COR¹⁸ ; and

R² includes H, halogen, C₁ -C₄ alkyl and C₁ -C₄ alkoxy.

EP-A-162,723 discloses 2,5-substituted herbicidal sulfonamides of formula ##STR4## wherein R is H or CH₃ ;

R₁ is C₁ -C₃ alkyl; and

R₂ is C₂ -C₆ alkoxy, C₁ -C₆ alkylthio, C₃ -C₆ alkenyl, C₃ -C₆ alkynyloxy, C₃ -C₆ alkenylthio, C₃ -C₆ alkynylthio, OCH₂ CH₂ OCH₃, OCH₂ CH₂ SCH₃, CH₂ F, CHF₂, OCF₂ H, OCH₂ CH₂ F, OCH₂ CHF₂, OCH₂ CF₃, OCH₂ CH₂ Cl, C₂ -C₆ alkyl substituted with 1-3 atoms of F or Cl or C₁ -C₄ alkyl substituted with C₁ -C₂ alkoxy or C₁ -C₂ alkylthio;

South African patent application No. 84/5216 discloses herbicidal sulfonylureas of the formula ##STR5## wherein R₁ and R₂ independently include H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy or C₁ -₄ alkylthio which are optionally substituted by halogen, NO₂, OSO₂ (C₁ -₄ alkyl), OSO₂ CF₃ or C₁ -C₄ alkoxycarbonyl;

X is CH or N;

R₆ and R₇ include H or C₁ -C₄ alkyl; and

R₈ is C₁ -C₄ alkyl, C₂ -C₄ alkenyl or benzyl.

EP-A-204,513, published 12/10/86 discloses herbicidal sulfonylureas of the formula ##STR6## wherein G is O, S, SO or SO₂ ;

m is 0 or 1;

n is 0, 1 or 2;

E is a single bond, CH₂ or O;

Q is a tetrazole or tetrazolinone;

A includes pyrimidines and triazines; and

R₁ includes H, C₁ to C₃ alkyl, C₁ to C₃ haloalkyl and C₁ -C₂ alkyl substituted by C₁ -C₂ alkoxy, C₁ -C₂ haloalkoxy, C₁ -C₂ alkylthio, C₁ -C₂ haloalkylthio, C₁ -C₂ haloalkylthio or CN.

EP-A-205,348, published Dec. 17, 1986, discloses herbicidal sulfonylureas of the formula ##STR7## wherein R₁ includes halogen, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, CO₂ R₃, CONR₄ R₅, SO₂ NR₄ R₅ and certain heterocyclic aromatic moieties;

R₂ includes a variety of substituted methyl moieties; and

A is one of seven heteroaromatic radicals.

U.S. Pat. No. 4,515,626 discloses herbicidal 4-cyclopropyl pyrimidinyl and triazinyl benzenesulfonylureas.

U.S. Pat. No. 4,545,811 discloses herbicidal 4-(haloalkoxy or haloalkylthio)pyrimidinyl and triazinyl benzenesulfonylureas.

U.S. Pat. No. 4,510,325 discloses herbicidal compounds of the formula ##STR8## wherein X is O,S,SO or SO₂ ;

A includes substituted C₁ -C₆ alkyl and optionally substituted C₂ -C₆ alkenyl; and

R₂ includes H, halogen, C₁ -C₅ alkyl and C₁ -C₄ haloalkyl.

EP-A-192,489 discloses herbicidal compounds of the formula ##STR9## wherein J is NHR₂, NR₃ R₄ or NR₂ 'NR₃ 'R₄ '.

U.S. Pat. No. 4,594,097 discloses herbicidal alkynyl-substituted benzenesulfonylureas.

U.S. Pat. No. 4,443,243 discloses herbicidal alkoxyalkynyl and thioalkynyl benzenesulfonylureas.

South African patent application No. 82/7439 discloses 4-aminopyrimidinyl and triazinyl benzenesulfonylureas.

South African patent application No. 83/6449 discloses herbicidal substituted-alkenyl benzenesulfonylureas.

EP-A-111,442 discloses herbicidal orthoheterocyclic benzenesulfonylureas.

South African patent application No. 84/2245 discloses herbicidal compounds of the formula ##STR10## wherein A is C₁ -C₆ haloalkyl; provided that A is not CF₃ or CR^(a) R^(b) R^(c) ;

R^(a) is H, Cl or C₁ -C₄ alkyl;

R^(b) is H or CH₃ ; and

R^(c) is Cl or Br.

U.S. Pat. No. 4,310,346 discloses herbicidal o-sulfonamide sulfonylureas.

SUMMARY OF THE INVENTION

This application pertains to novel compounds of Formula I, agriculturally suitable compositions containing them and their method-of-use as preemergent and/or postemergent herbicides or plant growth regulants. ##STR11## wherein E is CH₂ or a single bond;

W is O or S;

R is H or CH₃ ;

R_(X) is H, F, Cl, CH₃, OCH₃, N(CH₃)₂ or OCHF₂ ;

R₁ is F, Cl, Br, NO₂, C₁ -C₄ alkyl, C₂ -C₄ alkenyl, C₂ -C₄ haloalkenyl, C₂ -C₄ alkynyl, C₁ -C₄ haloalkyl, C₁ -C₄ alkoxy, OCH₂ CH₂ OCH₃, C₁ -C₄ haloalkoxy, C₃ -C₄ alkenyloxy, C₂ -C₄ haloalkenyloxy, C₃ -C₄ alkynyloxy, CO₂ R₃, CONR₄ R₅, SO₂ NR₄ 'R₅ ', S(O)_(n) R₆, OSO₂ R₇, C₁ -C₂ alkyl substituted with C₁ -C₂ alkoxy, OH or C₁ -C₂ alkylthio, CH₂ CN, C₆ H₅, ##STR12## R₂ is ##STR13## R₃ is C₁ -C₄ alkyl, C₃ -C₄ alkenyl, C₃ -C₄ alkynyl, ##STR14## CH₂ CH₂ Cl, CH₂ CH₂ F, or C₁ -C₂ alkyl substituted with OCH₃, SCH₃ or CN;

R₄ is C₁ -C₃ alkyl or C₁ -C₂ alkoxy;

R₄ ' is C₁ -C₃ alkyl or C₁ -C₂ alkoxy;

R₅ is H or C₁ -C₃ alkyl;

R₅ ' is H or C₁ -C₃ alkyl;

R₄ and R₅ may be taken together to form --(CH₂)₃ -- or --(CH₂)₄ --;

R₄ ' and R₅ ' may be taken together to form --(CH₂)₃ -- or --(CH₂)₄ --;

R₆ is C₁ -C₃ alkyl, --CH₂ CH═CH₂ or CH₂ C.tbd.CH;

R₇ is C₁ -C₃ alkyl or N(CH₃)₂ ;

R₈ is H, C₁ -C₄ alkyl, C₃ -C₄ alkenyl, C₃ -C₄ alkynyl, CH₂ CH₂ Cl, CH₂ CH₂ F, C₁ -C₂ alkyl substituted with OCH₃ or SCH₃ or C₃ -C₆ cycloalkyl;

R₉ is C₁ -C₂ alkyl;

R₁₀ and R₁₁ are independently C₁ -C₂ alkyl, C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, NHCH₃ or N(CH₃)₂ ;

R₁₂ and R₁₃ are independently H or C₁ -C₂ alkyl;

R₁₄ is C₁ -C₃ alkyl;

R₁₅ is H or CH₃ ;

R₁₆ is H, C₁ -C₂ alkyl or F;

R₁₇ is H or C₁ -C₂ alkyl;

R₁₇ is H, C₁ -C₂ alkyl, CN, Cl, OCH₃, SCH₃ or N(CH₃)₂ ;

R₁₈ is C₁ -C₂ alkyl;

R₁₉ is H, Si(CH₃)₃ or C₁ -C₂ alkyl;

R₂₀ is H or C₁ -C₂ alkyl;

R₂₁ is H, C₁ -C₃ alkyl or allyl;

R₂₂ is C₁ -C₂ alkyl or C₁ -C₂ haloalkyl;

R₂₃ is H, CH₃, Cl or Br;

R₂₄ is H or CH₃ ;

p is 1 or 2;

n is 0, 1 or 2;

A is ##STR15## X is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ haloalkyl, C₁ -C₄ haloalkylthio, C₁ -C₄ alkylthio, halogen, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino or di(C₁ -C₃ alkyl)amino;

Y is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ haloalkylthio, C₁ -C₄ alkylthio, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino, di(C₁ -C₃ alkyl)amino, C₃ -C₄ alkenyloxy, C₃ -C₄ alkynyloxy, C₂ -C₅ alkylthioalkyl, C₂ -C₅ alkylsulfinylalkyl, C₂ -C₅ alkylsulfonylalkyl, C₁ -C₄ haloalkyl, C₂ -C₄ alkynyl, C₃ -C₅ cycloalkyl, azido, cyano, ##STR16## m is 2 or 3; Q₁ and Q₂ are independently O or S;

R_(a) is H or C₁ -C₃ alkyl;

R_(b) and R_(c) are independently C₁ -C₃ alkyl;

Z is CH, N, CCH₃, CC₂ H₅, CCl or CBr;

Y₁ is O or CH₂ ;

X₁ is CH₃, OCH₃, OC₂ H₅ or OCF₂ H;

X₂ is CH₃, C₂ H₅ or CH₂ CF₃ ;

Y₂ is OCH₃, OC₂ H₅, SCH₃, SC₂ H₅, CH₃ or CH₂ CH₃ ;

X₃ is CH₃ or OCH₃ ;

Y₃ is H or CH₃ ;

X₄ is CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃ or Cl;

Y₄ is CH₃, OCH₃, OC₂ H₅ or Cl;

and their agriculturally suitable salts; provided that

(1) when X is halogen, then Z is CH and Y is OCH₃, OC₂ H₅, NH₂, NHCH₃, N(CH₃)₂, OCF₂ H, OCF₂ Br or N(OCH₃)CH₃ ;

(2) when X or Y is C₁ haloalkoxy, then Z is CH;

(3) when W is S, then R is H, A is A-1, Z is CH or N, and Y is CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃, C₂ H₅, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CH(OCH₃)₂ or ##STR17## (4) when the total number of carbon atoms of X and Y is greater than four, then the combined number of carbons of R₁ and R₂ is less than or equal to six;

(5) when R₂ is --C(O)R₁₇, --C(R₂₃) (R₁₇)Cl or --C(R₂₄)(R₁₇)Br then Y is other than cyclopropyl;

(6) when Y is C₂ -C₅ alkylthioalkyl, C₂ -C₅ alkylsulfinylalkyl or C₂ -C₅ alkylsulfonylalkyl, then R₂ is other than --CH(R₁₇)NO₂, ##STR18## (7) X₄ and Y₄ are not simultaneously Cl; (8) when R₄ ' is C₁ -C₂ alkoxy and R₅ ' is H, then R₂ is other than CH(R₁₇)CN, C(R₂₃) (R₁₇)Cl and C(R₂₄)(R₁₇)Br;

(9) when R₂ is C(O)R₁₇, C(R₂₃)(R₁₇)Cl or C(R₂₄)(R₁₇)Br, then R₁ is other than C₁ -C₄ haloalkyl or C₂ alkyl substituted with C₁ -C₂ alkoxy, OH or C₁ -C₂ alkylthio;

(10) when R₂ is C(R₂₃)(R₁₇)Cl or C(R₂₄)(R₁₇)Br, then X and Y are other than C₁ -C₄ haloalkoxy or C₁ -C₄ haloalkylthio;

(11) when R₂ is C(R₂₃)(R₁₇)Cl or C(R₂₄)(R₁₇)Br, then R₁ is other than C₁ -C₄ haloalkoxy, C₃ -C₄ alkenyloxy, C₂ -C₄ haloalkenyloxy, C₂ -C₄ alkynyl, C₃ -C₄ alkynyloxy, C₂ -C₄ haloalkenyl and R₁ --A through R₁ --W;

(12) when R₁ is R₁ --X, R₁ --Y, R₁ --Z, R₁ --AA, R₁ --AB, R₁ --AC or R₁ --AD, then R₂ is other than CH(R₁₆)CN, C(R₂₃)--(R₁₇)Cl and C(R₂₄)(R₁₇)Br;

(13) when R₂ is C(O)R₁₇, then R₁ is other than SO₂ NR₄ 'R₅ '; and

(14) when R₁ is CO₂ R₃ then both R₁₂ and R₁₃ are other than H.

In the above definitions, the term "alkyl", used either alone or in compound words such as "alkylthio" or "haloalkyl", denotes straight chain or branched alkyl, e.g., methyl, ethyl, n-propyl, isopropyl or the different butyl isomers.

Alkoxy denotes methoxy, ethoxy, n-propoxy, isopropoxy and the different butoxy isomers.

Alkenyl denotes straight chain or branched alkenes, e.g., vinyl, 1-propenyl, 2-propenyl, 3-propenyl and the different butenyl isomers.

Alkynyl denotes straight chain or branched alkynes, e.g., ethynyl, 1-propynyl, 2-propynyl and the different butynyl isomers.

Cycloalkyl denotes cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl.

The term "halogen", either alone or in compound words such as "haloalkyl", denotes fluorine, chlorine, bromine or iodine. Further, when used in compound words such as "haloalkyl" said alkyl may be mono-halogenated or fully substituted with halogen atoms, which may be the same or different. Examples of haloalkyl include CH₂ CH₂ F, CF₂ CF₃ and CH₂ CHFCl. Similarly, haloalkoxy, haloalkylthio, haloalkenyl and haloalkenyloxy would be defined as mono- or poly-substituted with the same or different halogen atoms.

The total number of carbon atoms in a substituent group is indicated by the C_(i) -C_(j) prefix where i and j are numbers from 1 to 5. For example, C₁ -C₃ alkylsulfonyl would designate methylsulfonyl through propylsulfonyl, C₂ alkoxyalkoxy would designate OCH₂ OCH₃ ; C₄ alkoxyalkoxy would designate the various isomers of an alkoxy group substituted with a second alkoxy group containing a total of 4 carbon atoms, examples including OCH₂ OCH₂ CH₂ CH₃ and OCH₂ CH₂ OCH₂ CH₃ ; as a further example, C₂ cyanoalkyl would designate CH₂ CN and C₃ cyanoalkyl would designate CH₂ CH₂ CN and CH(CN)CH₃.

PREFERRED COMPOUNDS

Preferred for reasons of increased ease of synthesis and/or greater herbicidal efficacy are:

1. Compounds of Formula I where

W is O.

2. Compounds of Preferred 1 where

E is a single bond;

X is C₁ -C₂ alkyl, C₁ -C₂ alkoxy, Cl, F, Br, I, OCF₂ H, CH₂ F, CF₃, OCH₂ CH₂ F, OCH₂ CHF₂, OCH₂ CF₃, CH₂ Cl or CH₂ Br; and

Y is H, C₁ -C₂ alkyl, C₁ -C₂ alkoxy, CH₂ OCH₃, CH₂ OCH₂ CH₃, NHCH₃, N(OCH₃)CH₃, N(CH₃)₂, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CH₂ SCH₃, ##STR19## OCF₂ H, SCF₂ H, OCF₂ Br, cyclopropyl, C.tbd.CH or C.tbd.CCH₃ ;

Z is CH or N;

R_(a) is H or CH₃ ;

R₂₃ is H; and

R₂₄ is H.

3. Compounds of Preferred 2 where

R₂ is --CH₂ CN, --CH₂ N₃, ##STR20## R₁₇ ' is H, C₁ -C₂ alkyl, Cl or CN.

4. Compounds of Preferred 3 where A is A-1.

5. Compounds of Preferred 4 where

R₁ is F, Cl, Br, NO₂, C₁ -C₃ alkyl, C₁ -C₂ alkyl substituted with 1-3 F or Cl or 1 Br, C₂ -C₃ alkenyl, C₂ -C₃ alkenyl substituted with 1-3 F or Cl, C₁ -C₂ alkoxy, C₁ -C₂ alkoxy substituted with 1-3 F or Cl or 1-Br, allyloxy, propargyloxy, OC(Cl)═CHCl, CO₂ CH₃, CO₂ C₂ H₅, CO₂ CH₂ CH═CH₂, CO₂ CH₂ CH₂ Cl, CO₂ CH₂ CH₂ OCH₃, CONH(C₁ -C₂ alkyl), CONCH₃ (C₁ -C₂ alkyl), SO₂ N(OCH₃)CH₃, SO₂ NH(C₁ -C₂ alkyl), SO₂ N(C₁ -C₂ alkyl)₂, S(O)_(n) C₁ -C₃ alkyl, OSO₂ C₁ -C₃ alkyl, C₁ -C₂ alkyl substituted with OCH₃ or SCH₃, C₆ H₅ and R₁ --A, R₁ --B, R₁ -- C, R₁ --D, R₁ --E, R₁ --F, R₁ --G, R₁ --H, R₁ --I, R₁ --J, R₁ --K, R₁ --L, R₁ --M, R₁ --N, R₁ --O, R₁ --P, R₁ --Q, R₁ --R, R₁ --S, R₁ --T, R₁ --U, R₁ --V, R₁ --W, R₁ --X, R₁ --Y, R₁ --Z, R₁ --AA, R₁ --AB, R₁ --AC or R₁ --AD;

6. Compounds of Preferred 5 where

X is CH₃, OCH₃, OCH₂ CH₃, Cl, OCF₂ H or OCH₂ CF₃ ; and

Y is CH₃, OCH₃, C₂ H₅, CH₂ OCH₃, NHCH₃ or CH(OCH₃)₂.

7. Compounds of Preferred 6 where

R is H;

R₁ is F, Cl, Br, NO₂, CH₃, CF₃ C₁ -C₂ alkoxy, allyloxy, OC(Cl)═CHCl, CO₂ CH₃, CO₂ C₂ H₅, CO₂ NHCH₃, CO₂ N(CH₃)₂, SO₂ NHCH₃ SO₂ N(CH₃)₂, SO₂ CH₃, SO₂ C₂ H₅, OSO₂ CH₃, OSO₂ C₂ H₅, R₁ --A, R₁ --B, R₁ --C, R₁ --X, R₁ --Z or R₁ --AB; and

R_(X) is H.

Specifically Preferred for reasons of greatest ease of synthesis and/or greatest herbicidal efficacy are:

2-(cyanomethyl)-6-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]aminosulfonyl]benzoic acid, ethyl ester, m.p. 201°-204° C.; and

2-(acetoxymethyl)-6-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]aminosulfonyl]benzoic acid, ethyl ester, m.p. 175°-176° C.

DETAILED DESCRIPTION OF THE INVENTION Synthesis

The compounds of Formula I can be prepared from sulfonamides of Formula II and heterocyclic amines of Formula III by one or more methods described in the literature. ##STR21## Several representative routes are described below.

U.S. Pat. No. 4,394,506 (issued 7/19/83) teaches the conversion of sulfonamides to sulfonyl isocyanates and sulfonyl isothiocyanates, and their subsequent coupling with heterocyclic amines of Formula III to give sulfonylureas.

U.S. Pat. No. 4,398,939 (issued 8/16/83) teaches the formation of n-butylsulfonylureas from sulfonamides followed by phosgenation to give the sulfonyl isocyanates. Alternatively, the sulfonamides can be treated with thionyl chloride followed by phosgenation to afford the sulfonyl isocyanates. Additionally, methylcarbamate derivatives of compounds of Formula III react with sulfonamides in the presence of trimethylaluminum to give sulfonylureas.

U.S. Pat. No. 4,443,245 (issued 4/17/84) teaches two methods for the synthesis of sulfonylureas. Either a phenyl carbamate of a sulfonamide and a heterocyclic amine, or a sulfonamide and a phenyl carbamate of a heterocyclic amine couple to give a sulfonylurea in an inert solvent with base.

The preparation of sulfonamides from sulfonyl chlorides is widely reported in the literature; for reviews see: F. Hawking and J. S. Lawrence. "The Sulfonamides," H. K. Lewis and Co., London, 1950 and E. H. Northey, "The Sulfonamides and Allied Compounds," Reinhold Publishing Corp., New York, 1948.

Additionally, primary sulfonamides, such as those of Formula II, can be formed by removal of an N-t-butyl protecting group from the corresponding secondary sulfonamide with trifluoroacetic acid (J. D. Catt and W. L. Matier, J. Org. Chem., 39, 566 (1974)) or polyphosphoric acid (J. G. Lombardino, J. Org. Chem., 36 (1971), 1843).

The requisite sulfonyl chlorides may be synthesized by known methods or with slight modifications thereof, by one skilled in the art. Several representative teachings are listed below.

Aromatic nitro groups may be transformed into sulfonyl chlorides by reduction, diazotization and coupling with sulfur dioxide/cupric chloride as taught in U.S. Pat. No. 4,310,346 (issued 1/12/82).

European Publication No. 94,821 (published 11/23/83) describes the displacement of aromatic halides with thiolate anions and subsequent oxidative chlorination to yield sulfonyl chlorides.

Halogen-metal exchange of aromatic halides or proton-metal exchange of aromatics followed by quenching with sulfur dioxide gives sulfinate salts. These salts yield sulfonyl chlorides upon reaction with N-chlorosuccinimide as taught in U.S. Pat. No. 4,481,029 (issued 11/6/84). Directed proton-metal exchange of aromatic compounds has been reviewed by Gschwend and Rodriguez, Org. Reactions, 26 (1979), 1. Directed lithiation of aryl-N-t-butylsulfonamides is described by J. G. Lombardino, J. Org. Chem., 36 (1971), 1843. Also, aryllithiums may be converted directly to arylsulfonyl chlorides with sulfuryl chloride as described in S. N. Bhattacharya, et. al., J. Chem. Soc. C, (1968), 1265.

Electrophilic chlorsulfonation of an aromatic ring to give a sulfonyl chloride is well known in the literature. This technique works best for alkyl aryl ethers and alkyl aromatics. Its application is described by E. H. Huntress and F. H. Carten, J. Am. Chem. Soc., 62 (1940), 511-14 and 603-4.

Transformation of phenols to sulfonyl chlorides can be accomplished by the formation of a thiocarbamate, rearrangement, hydrolysis and oxidative chlorination as described by M. S. Newman and H. A. Kames, J. Org. Chem., 31 (1966), 3980.

Compounds of Formula II can be prepared by a variety of methods known in the literature. The most universal scheme, where benzyl halides of Formula IV are reacted with the appropriate reagent, is shown below. ##STR22## wherein U is SO₂ NH₂ or a previously described sulfonamide precursor, and X¹ is Cl, Br or I and R₂ is of the structure --CH(R₁₇)--. Some specific methods are listed below.

NITRILES (R₂ ═CH(R₁₇)CN)

Nitriles can be prepared by nucleophilic displacement of benzyl halides, usually benzyl chlorides or bromides, with potassium or sodium cyanide. Many solvents are applicable, but frequently dimethylsulfoxide is used. Thus, a benzyl bromide of formula IV can be contacted with potassium cyanide in dimethylsulfoxide for 0.5 h to 24 h at 20° to 140° C. For a review of this reaction, refer to Friedrich and Wallenfels, in Rappoport, "The Chemistry of the Cyano Group", pp. 77-86, Interscience Publishers, New York, 1970.

ISONITRILES (R₂ ═CH(R₁₇)NC)

Heavy metal cyanides and benzylhalides react to give isonitriles. The reaction is best carried out in the dark using silver cyanide and a benzyl iodide. Typical procedures are given by A. Gautier, Ann. Chem., 142 (1867), 28 and H. L. Jackson and B. C. McKusick, Org. Syn., Col. Vol. IV, 438.

AZIDES (R₂ ═CH(R₁₇)N₃)

Compounds of Formula II may be prepared by reacting an azide anion with a benzyl halide. Typically sodium azide in alcohol or wet acetone is mixed with a benzyl bromide at 20°-100° C. This nucleophilic displacement is reviewed in Biffin, Miller and Paul, in Patai, "The Chemistry of the Azido Group," pp. 57-119, Interscience Pub., New York, 1971.

PHOSPHONATES (R₂ ═CH(R₁₇)P(O)R₁₀ R₁₁)

Alkyl phosphites are heated with benzylic halides to give phosphonates. The reaction is known as the Arbuzov reaction and it is reviewed by Arbuzov, Pure Appl. Chem., 9 (1964), 307-335.

AMINES (R₂ ═CH(R₁₇)NR₁₂ R₁₃)

Tertiary amines are prepared by alkylation of a secondary amine with a benzylic halide. The reaction is well documented in the literature.

Primary amines can be prepared by reduction of compounds of Formula II where R₂ is azide. Generally lithium aluminum hydride or hydrogen and palladium catalyst are used.

NITRO (R₂ ═CH(R₁₇)NO₂)

Nitrites react with benzylic halides to give benzylic nitro compounds. The reaction is usually carried out with sodium nitrite on a benzylic bromide in dimethylformamide or dimethylsulfoxide. When silver nitrite is used, diethyl ether at 0°-25° C. are the preferred reaction conditions. The reaction is exhaustively discussed by N. Kornblum, Org. Reactions, 12 (1962), 101.

SELENO ETHERS (R₂ ═CH(R₁₇)SeR₁₄)

Alkali alkylselenides can be prepared by in situ combination of an alkali metal t-butoxide with the selenol HSeR₁₄ in the solvent to be used for the displacement reaction. The selenols, HSeR₁₄, can be prepared by a variety of methods reviewed by D. L. Klayman, "Selenols and their Derivatives" in Organic Selenium Compounds: Their Chemistry and Biology, D. L. Klayman, W. H. H. Gunther ed., New York, 1973, and K. J. Irgolic and M. V. Kudchadker, "Organic Chemistry of Selenium" in Selenium, R. A. Zingaro, W. C. Cooper ed., Van Nostrand Reinhold, New York, 1974.

Benzyl halides may be formed through a variety of methods described in the literature. Several are listed below.

BENZYLIC CHLORIDES (X¹ ═Cl)

Treatment of alkyl benzene derivatives with N-chlorosuccinimide, NCS, in a suitable solvent, such as carbon tetrachloride or dichloromethane, and catalyzed by light or a free radical initiator, such as azoisobutyronitrile or benzoyl peroxide, gives the benzylic chloride.

Treatment of a benzylic alcohol with thionyl chloride, either neat or in the presence of a base such as pyridine, gives the benzylic chloride. For typical examples, see H. Gilman and J. E. Kirby, J. Am. Chem., Soc., 51, 3475 (1929) and M. S. Newman, J. Am. Chem. Soc., 62, 2295 (1940).

BENZYLIC BROMIDES (X¹ ═Br)

Treatment of alkyl benzene derivatives with N-bromosuccinimide by a method analogous to the case of N-chlorosuccinimide gives the benzylic bromide. Benzylic alcohols in an inert solvent such as benzene or dichloromethane react with phosphorus tribromide to give benzylic bromides.

BENZYLIC IODIDES (X¹ ═I)

Treatment of a benzylic chloride or benzylic bromide with sodium iodide gives the benzylic iodide. The reaction, known as the Finkelstein reaction, works well in refluxing acetone.

Benzylic alcohols may be treated with iodine and phosphorus (red) or phosphorus (red) and phosphorus (yellow) to give the benzylic iodide.

ESTERS (R₂ ═CH(R₁₇)OCOR₂₂

Reaction of a benzyl bromide or iodide with a carboxylic acid salt in a dipolar aprotic solvent, results in good yields of the carboxylic esters. For a leading reference see Parker, Adv. Org. Chem., 5, (1965) 1-46.

METHANESULFONATES (R₂ ═CH(R₁₇)OSO₂ CH₃)

Primary and secondary alcohols react with methanesulfonyl chloride in dry pyridine at room temperature to give mesylates, usually in good yield. The reaction is well documented in the literature.

Compounds of Formula II, where R₂ contains an oxygen functionality, such as an aldehyde or ketone, may be prepared by a variety of methods known to one skilled in the art. Two such routes are shown below. ##STR23##

Primary and secondary benzylic halides may be oxidized to aldehydes and ketones, respectively using dimethylsulfoxide. For reviews of this reaction see Durst, Adv. Org. Chem., 285-388 (1969) pp. 343-356 and W. Epstein and F. Sweat, Chem. Rev., 67 (1967), 247-60.

Primary benzylic alochols may be oxidized to aldehydes and secondary benzylic alcohols may be oxidized to ketones by one skilled in the art. One or more of a variety of methods, such as an oxidizing agent, catalytic dehydrogenation, Oppenauer oxidation or halosuccinimide oxidation may be used.

Acetals, thioacetals, ketals and thioketals are easily prepared by one skilled in the art from compounds of Formula V.

Oximes, and oxime ethers of Formula Va are easily prepared by one skilled in the art from compounds of Formula V and hydroxylamine or o-alkylhydroxylamine with or without an appropriate base. ##STR24## wherein R₁₇ ' is H or C₁ -C₂ alkyl.

Additionally, compounds of the Formula Ia can be prepared from VII by treatment with an appropriate salt or amine. ##STR25## wherein M is Na⁺ or K⁺

Q is CN, OCH₃ and SCH₃.

The reaction is effected by reacting VII with at least one molor equivalent of M-Q in an inert solvent such as acetone, methyl ethyl ketone, tetrahydrofuran, dimethylformamide or methanol. The reaction is carried out at 0° C. to 80° C. for one to twenty-four hours.

Compounds of the Formula VII are themselves readily prepared from the corresponding carboxylic acids, VIII. ##STR26##

The carboxylic acids are converted to their acid chlorides which are in turn converted to N-alkoxyamides. Subsequent reaction of the amides with a suitable halogenating agent provides compounds of the Formula VII.

Benzylic alcohols and alkyl benzene derivatives are either known or may be prepared by one skilled in the art.

The heterocylic amines A-1 to A-7 are either known, disclosed in this application or can be prepared by methods obvious to one skilled in the art.

For a review of the synthesis and reactions of 2-aminopyrimidines (A-1, Z═CH) see The Chemistry of Heterocyclic Compounds, Vol 16, Wiley-Interscience, New York (1962). For a review of the synthesis and reactions of 2-amino-1,3,5-triazines (A-1, Z═N) see The Chemistry of Heterocyclic Compounds, Vol. 13, Wiley-Interscience, New York (1959), F. C. Schaefer, U.S. Pat. No. 3,154,537 and F. C. Schaefer and K. R. Huffman J. Org. Chem., 28 (1963), 1812.

The synthesis of bicyclic amines A-2 and A-3 is taught in U.S. Pat. No. 4,339,267.

The synthesis of amino furo[2,3-d]pyrimidines, A-4, is taught in U.S. Pat. No. 4,487,626.

The synthesis of aminotriazoles, A-5, is taught in U.S. Pat. No. 4,421,550.

The synthesis of aminomethylheterocycles, A-6, is taught in U.S. Pat. No. 4,496,392.

The synthesis of aminocyano hetereocycles, A-7, is taught in European Publication No. 125,864 (published 11/21/84).

Agriculturally suitable salts of compounds of Formula I are also useful herbicides and can be prepared in a number of ways known to the art. For example, metal salts can be made by contacting compounds of Formula I with a solution of an alkali or alkaline earth metal salt having a sufficiently basic anion (e.g. hydroxide, alkoxide, carbonate or hydride). Quaternary amine salts can be made by similar techniques.

Salts of compounds of Formula I can also be prepared by exchange of one cation for another. Cationic exchange can be effected by direct contacting of an aqueous solution of a salt of a compound of Formula I (e.g., alkali metal or quaternary amine salt) with a solution containing the cation to be exchanged. This method is most effective when the desired salt containing the exchanged cation is insoluble in water, e.g., a copper salt, and can be separated by filtration.

Exchange may also be effected by passing an aqueous solution of a salt of a compound of Formula I (e.g., an alkali metal or quaternary amine salt) through a column packed with a cation exchange resin containing the cation to be exchanged. In this method, the cation of the resin is exchanged for that of the original salt of the resin is exchanged for that of the original salt and the desired product is eluted from the column. This method is particularly useful when the desired salt is water-soluble, e.g., a potassium, sodium or calcium salt.

Acid addition salts, useful in this invention, can be obtained by reacting a compound of Formula I with a suitable acid, e.g., p-toluenesulfonic acid, trichloroacetic acid or the like.

The preparation of the compounds of this invention is further illustrated by the following examples.

EXAMPLE 1 Ethyl 2-Amino-6-methylbenzoate

A reaction mixture of 185 g of ethyl 6-methyl-2-nitrobenzoate and 176 g of powdered iron in 343 mL of glacial acetic acid and 2200 mL of ethanol was heated at reflux for 5 hours. The reaction mixture was allowed to cool, diluted with excess water and extracted with ethyl acetate. The organic layer was dried over sodium sulfate, filtered and concentrated to an orange oil 148.3 g.

NMR (CDCl₃, 90 MHz): 1.32 (t, CH₃, 3H); 2.40 (s, CH₃, 3H); 4.25 (q, CH₂, 2H); 6.25 (br s, NH₂, 2H); 6.50 (d, ArH, 2H); and 7.05 (dd, ArH, 1H).

EXAMPLE 2 2-Carboethoxy-N-(1,1-dimethylethyl)-3-methylbenzenesulfonamide

To 31.5 g of ethyl 2-amino-6-methylbenzoate in 65 mL of concentrated hydrochloric acid and 185 mL of glacial acetic acid at 0° C. was added a solution of 13.0 g of sodium nitrite in 28 mL of H₂ O, keeping the temperature below 5° C. The solution was stirred an additional one-half hour and then poured portionwise into a suspension of 7.8 g of cupric chloride dihydrate, 16.0 mL of anhydrous sulfur dioxide and 140 mL of glacial acetic acid at 15° C. The resulting reaction mixture was warmed to room temperature and stirred an additional 3.5 hours. The reaction mixture was poured into 1 liter of ice/water and the solids filtered to give 35.5 g of a yellow solid. The solids were dissolved in 350 mL of tetrahydrofuran and treated at -50° to -60° C. with 46 mL of tert-butyl amine. The reaction mixture was warmed to 0° C. over 2 hours and then the solids were removed by filtration. Removal of the solvent provided 31.0 g of an orange solid. Recrystallization from ethanol/water provided 30 g of a pale yellow solid, m.p. 89°-91° C.

¹ HNMR (90 MHz, CDCl₃): 1.15 (s, CH₃, 9H); 1.34 (t, CH₃, 3H); 2.31 (s, CH₃, 3H); 4.40 (q, CH₂, 2H); 5.22 (br s, NH, 1H); 7.44 (d, ArH, 2H); and 7.85 (dd, ArH, 1H).

EXAMPLE 3 2-Bromomethyl-2-carboethoxy-N-(1,1-dimethylethyl)benzenesulfonamide

A mixture of 67.0 g of 2-carboethoxy-N-(1,1-dimethylethyl)-3-methylbenzenesulfonamide and 47.6 g of NBS and 0.5 g of azobisisobutyronitrile in 700 mL of carbontetrachloride was heated at reflux for 3 hours. The resulting reaction mixture was allowed to cool and the solids removed by filtration. Concentration provided a waxy yellow solid which was washed with 1:1 hexane/n-butyl chloride to yield 44.36 g of a white solid, m.p. 74°-75° C.

¹ HNMR (200 MHz, CDCl₃): 1.25 (s, CH₃, 9H); 1.47 (t, CH₃, 3H); 4.50 (q, CH₂, 2H); 4.54 (s, CH₂, 2H); 5.20 (s, NH, 1H); 7.43-7.65 (m, ArH, 2H); and 8.02 (d, ArH, 1H).

EXAMPLE 4 3-Bromomethyl-2-carboethoxybenzenesulfonamide

A solution of 5.7 g of 3-bromomethyl-2-carboethoxy-N-(1,1-dimethylethyl)benzenesulfonamide in 60 mL of trifluoroacetic acid was stirred at room temperature for 16 hours. Concentration provided a viscous oil which was triturated with n-butyl chloride. The solids were collected to yield 3.91 g of a white solid, m.p. 138°-140° C.

¹ HNMR (90 MHz, CDCl₃): 1.40 (t, CH₃, 3H); 4.48 (q, CH₂, 2H); 4.62 (s, CH₂, 2H); 6.95 (br s, NH₂, 2H); and 7.4-8.2 (m, ArH, 3H).

EXAMPLE 5 3-Azidomethyl-2-carboethoxybenzenesulfonamide

A solution of 1.64 g of 3-bromomethyl-2-carboethoxybenzenesulfonamide and 0.43 g of sodium azide in ethanol was heated to reflux for 3 hours. The resulting reaction mixture was cooled to room temperature and the ethanol was removed on the rotovap. The residue was partitioned between water and ethyl acetate. The organic phase was dried over magnesium sulfate, filtered and concentrated to give 1.32 g of a waxy solid.

¹ HNMR (200 MHz, CDCl₃): 1.40 (t, CH₃, 3H); 4.46 (q, CH₂, 2H); 4.47 (s, CH₂, 2H); 5.49 (br s, NH₂, 2H); 7.75-7.85 (m, ArH, 2H); and 7.98 (dd, ArH, 1H).

EXAMPLE 6 2-(Azidomethyl)-6-[((4,6-dimethoxypyrimidin-2-yl)aminocarbonyl)aminosulfonyl]benzoic acid, ethyl ester

To a suspension of 0.21 g of the compound from Example 5 and 0.23 g of 4,6-dimethoxy-2-pyrimidinylcarbamic acid, phenyl ester in 4.0 mL of dry acetonitrile was added 0.12 mL of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). After being stirred at room temperature for 2 hours, the resulting reaction mixture was diluted with 4.0 mL of water, acidified with 1N hydrochloric acid to pH 2 and the solids collected by vacuum filtration. The solids were further washed with ether and then air dried to give 0.21 g of a white solid, m.p. 158°-160° C.

¹ HNMR (200 MHz, CDCl₃): 1.41 (t, CH₃, 3H); 3.98 (s, OCH₃, 6H); 4.43 (q, CH₂, 2H); 4.44 (s, CH₂, 2H); 5.78 (s, Het-H, 1H); 7.22 (br s, NH, 1H); 7.60-7.80 (m, ArH, 2H); 8.36 (dd, ArH, 1H); and 12.52 (br s, NH, 1H).

EXAMPLE 7 3-Acetoxymethyl-2-carboethoxy-N-(1,1-dimethylethyl)benzenesulfonamide

A solution of 5.0 g of 3-bromomethyl-2-carboethoxy-N-(1,1-dimethylethyl)benzenesulfonamide and 1.5 g of potassium acetate in 50 mL of dimethylsulfoxide was stirred at room temperature for 6 hours. The resulting reaction mixture was poured onto ice and extracted with ethyl acetate. The organic phase was washed with a solution of saturated sodium chloride and then dried over magnesium sulfate. Removal of the drying agent by filtration and concentration provided a white solid. Chromatography on silica gel with 1:1 ethyl acetate/hexane provided 2.58 g of a white solid, m.p. 81°-82° C.

¹ HNMR (90 MHz, CDCl₃): 1.22 (s, CH₃, 9H); 1.40 (t, CH₃, 3H); 2.20 (s, CH₃, 3H); 4.48 (q, CH₂, 2H); 5.23 (br s, NH, CH₂, 3H); 7.53-7.70 (m, ArH, 2H); and 8.00-8.16 (m, ArH, 1H).

EXAMPLE 8 3-Acetoxymethyl-2-carboethoxybenzenesulfonamide

A solution of 2.58 g of 3-acetoxymethyl-2-carboethoxy-N-(1,1-dimethylethyl)benzenesulfonamide in 25 mL of trifluoroacetic acid was stirred at room temperature overnight. Removal of the solvent on the rotovap followed by trituration with n-butyl chloride provided 2.0 g of a white solid, m.p. 98°-100° C.

¹ HNMR (90 MHz, CDCl₃): 1.51 (t, CH₃, 3H); 2.20 (s, CH₃, 3H); 4.48 (q, CH₂, 2H); 5.23 (s, NH, CH₂, 2H); 5.35 (br s, NH₂, 2H); 7.50-7.70 (m, ArH, 2H); and 7.98-8.15 (m, ArH, 1H).

EXAMPLE 9 2-Acetoxymethyl-6-[((4,6-dimethoxypyrimidin-2-yl)aminocarbonyl)aminosulfonyl]benzoic acid, ethyl ester

To a suspension of 0.25 g of the compound from Example 8 and 0.23 g of 4,6-dimethoxy-2-pyrimidinylcarbamic acid, phenyl ester in 4.0 mL of dry acetonitrile was added 0.12 mL of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). After being stirred at room temperature for 2 hours, the reaction mixture was diluted with 4.0 mL of water and then acidified with 1N hydrochloric acid to pH 2. The solids were collected by vacuum filtration and washed with ether to yield 0.28 g of a white solid, m.p. 162°-163° C.

¹ HNMR (200 MHz, DMSO-d₆): 1.22 (t, CH₃, 3H); 2.00 (s, CH₃, 3H); 3.90 (s, OCH₃, 6H); 4.28 (q, CH₂, 2H); 5.08 (s, CH₂, 2H); 5.60 (s, Het-H, 1H); 7.70-7.90 (m, ArH, 2H); and 8.03-8.10 (m, ArH, 1H).

EXAMPLE 10 3-Bromomethyl-6-[((4,6-dimethoxypyrimidin-2-yl)aminocarbonyl)aminosulfonyl]benzoic acid, ethyl ester

To a suspension of 0.31 g of the compound from Example 4 and 0.28 g of 4,6-dimethoxy-2-pyrimidinylcarbamic acid, phenyl ester in 5.0 ml of dry acetonitrile was added 0.15 ml of DBU. After stirring at room temperature for three hours, the reaction mixture was diluted with 5.0 ml of water and then acidified with 1N hydrochloric acid to pH3. The solids were collected by vacuum filtration and washed with n-butylchloride to yield 0.38 g of a white solid; m.p. 195°-197° C.;

¹ HNMR (200 mhz, DMSO-d₆): 1.28 (t, CH₃, 3H); 3.90 (s, OCH₃, 6H); 4.35 (q, CH₂, 2H); 4.68 (s, CH₂, 2H); 6.00 (s, CH, 1H); 7.75 (d, d, ARH, 1H); 7.94 (d, ARH, 1H); 8.15 (d, ARH, 1H); 10.68 (br, s, N--H, 1H); and 12.65 (brs, N--H, 1H).

The invention is further exemplified, but not limited to the compounds in Tables I-VII. The com- pounds depicted in these tables may be prepared by methods described in Examples 1-10, or by modifications thereof apparent to those skilled in the art. ##STR27##

    TABLE I       General Formula I R.sub.1 R.sub.2 R.sub.X W R X Y Z m.p. (°C.)        F CH.sub.2 CN H O H OCH.sub.3 H CH  F CH.sub.2 CN H O CH.sub.3      OCH.sub.3 CH.sub.3 CH F CH.sub.2 CN H O H CH.sub.3 OCH.sub.3 N F      CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 CH F CH.sub.2 SCN H O H OCH.sub.3      CH.sub.2 CH.sub.3 CH F CH.sub.2 SCN H O H CH.sub.2 CH.sub.3 OCH.sub.3 N      F CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 CH.sub.2 OCH.sub.3 CH F      CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH F CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H OCH.sub.2 CH.sub.3 CH.sub.3 CH F CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 CH.sub.3 N Cl CH.sub.2 CN H O H      OCH.sub.3 CH.sub.2 CH.sub.2 OCH(CH.sub.3).sub.2 CH Cl CH.sub. 2 CN 6-Cl      O H Cl OCH.sub.3 CH Cl CH.sub.2 CN H O H OCH.sub.3 CH(CH.sub.3)(CH.sub.2      OCH.sub.3) CH Cl CH.sub.2 SCN H O H CH.sub.3 CH.sub.3 CH Cl CH.sub.2 SCN      H O H OCH.sub.3 CH.sub.3 N Cl CH.sub.2 SCN 6-Cl O H OCH.sub.3 CH.sub.3      CH Cl CH.sub.2 SCN H O H Cl OCH.sub.3 CH Cl CH.sub.2 SCN H O H OCH.sub.3      OCH.sub.3 N Cl CH.sub.2 SCN H O H OCH.sub.3 (CH.sub.2).sub.4 CH.sub.2      OCH.sub.2 CH.sub.3 CH Cl CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3      CH.sub.3 N Cl CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCF.sub.2 H CH.sub.3      CH Cl CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 NH.sub.2 CH Cl      CH.sub.2 P(O)(OCH.sub.2 CH.sub.3).sub.2 H O H OCH.sub.3 NHCH.sub.3 N Br      CH.sub.2 CN H O H CH.sub.3 NHCH.sub.2 CH.sub.3 CH Br CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH Br CH.sub.2 CN H S H OCH.sub.3 CH.sub.3 N Br      CH.sub.2 SCN H O H CH.sub.2 F OCH.sub.3 CH Br CH.sub.2 SCN H O H      OCH.sub.3 NHCH(CH.sub.3).sub.2 CH Br CH.sub.2 SCN H O H OCH.sub.3      CH.sub.3 N Br CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.2 CH.sub.2 F      OCH.sub.3 CH Br CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 N(CH.sub.3).sub.2 CH Br CH.sub.2      P(O)(SCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N NO.sub.2 CH.sub.2 CN H      O H OCH.sub.3 OCH.sub.3 CH NO.sub.2 CH.sub.2 CN H O H OCH.sub.3 CH.sub.3      CH NO.sub.2 CH.sub.2 CN H O H CH.sub.3 OCH.sub.3 CH NO.sub.2 CH.sub.2      SCN H O H OCH.sub.3 CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 N NO.sub.2      CH.sub.2 SCN H O H CH.sub.2 CH.sub.3 OCH.sub.3 CH NO.sub.2 CH.sub.2 SCN      H O H OCH.sub.3 OCH.sub.2 CH.sub.2 CH.sub.2 Cl CH NO.sub.2 CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub. 3 N NO.sub.2 CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H CH.sub.2 CH.sub.2 CH.sub.2       CH.sub.3 OCH.sub.3 CH NO.sub.2 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H      OCH.sub.3 SCH.sub.2 CH.sub.2 F CH NO.sub.2 CH.sub.2       P(O)(SCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N CH.sub.3 CH.sub.2 CN      H O H CH.sub.3 SCH.sub.3 CH CH.sub.3 CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 CH CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3 SCH(CH.sub.3).sub.2 N      CH.sub.3 CH.sub.2 SCN H O H OCH.sub.2 (CH.sub.3).sub.2 OCH.sub.3 CH      CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H Br OCH.sub.3 CH CH.sub.3      CH.sub.2 P(O)(N(CH.sub.3).sub.2).sub.2 H O H OCH.sub.3 OCH.sub.3 N      CH.sub.2 CH.sub.3 CH.sub.2 CN H O H CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2      CH.sub.3 OCH.sub.3 CH CH.sub.3 CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3      OCH.sub.2 CH.sub.2 OCH.sub.3 CH -n-C.sub.4 H.sub.9 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N CHCH.sub.2 CH.sub.2      CN H O H F OCH.sub.3 CH CHCHCH.sub.3 CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 CH CH.sub.2 CHCH.sub.2 CH.sub.2 SCN H O H CH.sub.3 OCH.sub.3 N      CClCCl.sub.2 CH.sub.2 SCN H O H OCH.sub.2 CH.sub.2 OCH(CH.sub.3).sub.2      OCH.sub.3 CH CCCH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H CH.sub.3      OCH.sub.3 CH CH.sub.2 CCH CH.sub.2 CN H O H OCH.sub.3 CH.sub.2 CH.sub.3      N CH.sub.2 Cl CH.sub.2 CN H O H N(CH.sub.2 CH.sub.3).sub.2 OCH.sub.3 CH      CH.sub.2 Cl CH.sub.2 SCN H O H Cl OCH.sub.3 CH CH.sub.2 Br CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N CH.sub.2 Br CH.sub.2      CN H O H CH.sub.3 OCH.sub.3 CH CF.sub.3 CH.sub.2 CN H O H OCH.sub. 3      CH.sub.3 N CF.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH CF.sub.3      CH.sub.2 SCN H O H Br OCH.sub.3 CH CF.sub.3 CH.sub.2 SCN H O H OCH.sub.3      CH.sub.2 CH.sub.3 N CF.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H      OCH.sub.3 OCH.sub.3 CH CF.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H      OCH.sub.2 CH.sub.3 CH.sub.3 CH CF.sub.3 CH.sub.2       NH.sub.2 H O H OCH.sub.3 H CH CH.sub.2 CHClCH.sub.2 Cl CH.sub.2 CN H O      H CH.sub.3 OCH.sub.3 N CH.sub.2 CF.sub.3 CH.sub.2 CN H O H I OCH.sub.3      CH OCH.sub.3 CH.sub.2 CN H O H OCH.sub.3 CH.sub.2 OCH.sub.3 CH OCH.sub.3      CH.sub.2 CN H O H CH.sub.3 OCH.sub.3 CH OCH.sub.3 CH.sub.2 CN H O H      CH.sub.3 OCH.sub.3 N OCH.sub.3 CH.sub.2 CN H O H OCH.sub.3 NHCH.sub.3 CH      OCH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N OCH.sub.3 CH.sub.2 CN      H O H OCH.sub.2 CF.sub.2 H OCH.sub.3 CH OCH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH OCH.sub.3 CH.sub.2 CN H O H CH.sub.3 CH.sub.3 N      OCH.sub.3 CH.sub.2 SCN H O H CH.sub.2 Br OCH.sub.3 CH 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     CH CH.sub.2 CN H O H OCH.sub.3 OCH.sub.2 CH.sub.2 CH.sub.2CH.sub.3 CH      OCH.sub.2 CCH CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N OCH.sub.2 CCH      CH.sub.2 SCN H O H CH.sub.3 CH.sub.2 SCH.sub.3 CH OCH.sub.2 CCH CH.sub.2      SCN H O H OCH.sub.3 OCH.sub.3 CH OCH.sub.2 CCH CH.sub.2 SCN H O H      CH.sub.3 OCH.sub.3 N OCH.sub.2 CCH CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H      OCH.sub.3 CH.sub.2 SCH.sub.2 CH.sub.2 CH.sub.2 CH OCH.sub.2 CCH CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 OCH.sub.3 CH OC(Cl)CHCl CH.sub.2 CN      H O H OCH.sub.3 CH.sub.2 CH.sub.2 F N OC(Cl)CHCl CH.sub.2 CN H O H I      OCH.sub.3 CH OC(Cl)CHCl CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.2 CCH CH      OC(Cl)CHCl CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 CCH N OC(Cl)CHCl CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3      CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH 191-193 CO.sub.2 CH.sub.3      CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 CH 194-195 CO.sub.2 CH CH.sub.2 CN      H O H CH.sub.3 CH.sub.3 CH 197(d) CO.sub.2 CH.sub.3 CH.sub.2 CN H O H      CH.sub.2 CH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub. 3 CH.sub.2 CN H O H      OCH.sub.3 CH.sub.3 N 173-176 CO.sub.2 CH.sub.3 CH.sub.2 CN H O H      CH.sub.2 CH.sub.2 OCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2 CN H O H Cl      OCH.sub.3 CH 202-204 CO.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 N 184-187 CO.sub.2 CH.sub.3 CH.sub.2 SCN H O H CH.sub.3      OCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2 SCN H O H Cl OCH.sub.3 CH      CO.sub.2 CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 N CO.sub.2      CH.sub.3 CH.sub.2 SCN H O H CH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.3      CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2 SCN      H O H OCH.sub.3 CH.sub.3 N CO.sub.2 CH.sub.3 CH.sub.2       SCN H O H NHCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2 SCN H O H      OCH.sub.3 CH(OCH.sub.3).sub.2 CH CO.sub.2 CH.sub.3 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.3  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O H      OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2 SeCH.sub.3 H O H      OCH.sub.3 CH.sub.3 N CO.sub.2 CH.sub.3 CH.sub.2 SeCH.sub.3 H O H Cl      OCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3 CH.sub.3      CH 175-178 CO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3      N 181-183 CO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H Cl OCH.sub.3 CH      176-177 CO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.2 CH.sub.3      NHCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3      CH.sub.3 N 164-165 CO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H CH.sub.3      CH.sub.3 CH 179-181 CO.sub.2 CH.sub. 3 CH.sub.2 N.sub.3 H O H OCH.sub.3      OCH.sub.3 CH 175-177 CO.sub.2 CH.sub.3 CH.sub.2 NO.sub.2 H O H CH.sub.3      OCH.sub.3 N CO.sub.2 CH.sub.3 CH.sub.2 NO.sub.2 H O H CH.sub.3 CH.sub.3      CH CO.sub.2 CH.sub.3 CH.sub.2 NO.sub.2 H O H CH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.3 CH.sub.2 NO.sub.2 H O H OCH.sub.3 OCH.sub.3 N CO.sub.2      CH.sub.3 CH.sub.2 NO.sub.2 H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2      CH.sub.3 CH.sub.2 NO.sub.2 H O H Cl OCH.sub.3 CH CO.sub.2 CH.sub.3      CH.sub.2 NC H O H OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.3 CH.sub.2 NC H      O H CH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH 201-204 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H      O H CH.sub.3 CH.sub.3 CH 191-193 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN      H O H CH.sub.3 OCH.sub.3 N 166-168 CO.sub.2 CH.sub. 2 CH.sub.3 CH.sub.2      CN H O H OCH.sub.3 N(OCH.sub.3)CH.sub.3 N CO.sub.2 CH.sub.2 CH.sub.3      CH.sub.2 SCN H O H CH.sub.3 OCH.sub.3 CH 188-190 CO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 CH 213-214 CO.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 CH 191-193      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H Cl OCH.sub.3 CH 192-195      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N      175-177 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H CH.sub.3 CH.sub.3      CH 184-186 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H Cl OCH.sub.3 CH      187-190 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2       SCN H O H OCH.sub.3 OCH.sub.3 N 158-164 CO.sub.2 CH.sub.2 CH.sub.3      CH.sub.2 SCN H O H CH.sub.3 OCH.sub.3 N 137-140 CO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 CH.sub.3 CH      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH      158-160 CO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.2 CH.sub.3      NHCH.sub.3 N >250 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H      OCH.sub.3 CH.sub.3 N 150-152 CO.sub.2 CH(CH.sub.3).sub.2 CH.sub.2 CN H O      H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH(CH.sub.3).sub.2 CH.sub.2 CN H O H      OCH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.2 CHCH.sub.2 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.2 CHCH.sub.2 CH.sub.2 SCN H O H      OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.2 CHCH.sub.2 CH.sub.2 SCN H O H      OCH.sub.3 CN CH CO.sub.2 CH.sub.2 C CH CH.sub.2 P(O)(OCH.sub.3).sub.2 H      O H OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.2 CH.sub.2 Cl CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.2      CH.sub.2 Cl CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.2      CH.sub.2 F CH.sub.2 CN H O H CH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.2      CH.sub.2 F CH.sub.2 SCN H O H CH.sub.3 CHO CH CO.sub.2 CH.sub.2 CF.sub.3      CH.sub.2 SCN H O H CH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.2      OCH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N      CO.sub.2 CH.sub.2 CH.sub.2 OCH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O      H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.2 SCH.sub.3 CH.sub.2      CN H O H OCH.sub.3 N.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.2 SCH.sub.3      CH.sub.2 SCN H O H OCH.sub.3 CH.sub.3 N C(O)NHCH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH C(O)NHCH.sub.3 CH.sub.2 SCN H O H OCH.sub.3      CH.sub.3 CH C(O)NHCH.sub.3 CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 CH      C(O)NHCH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3      N C(O)N(CH.sub.3).sub.2 CH.sub.2 CN H O H CH.sub.2 CH.sub.3 OCH.sub.3 CH      C(O)N(CH.sub.3).sub.2 CH.sub.2       CN H O H OCH.sub.3 CH.sub.3 CH C(O)N(CH.sub.3).sub.2 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 N C(O)N(CH.sub.3).sub.2 CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 CH C(O)N(CH.sub.3).sub.2 CH.sub.2 SCN H O H Cl OCH.sub.3 CH      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H CH.sub.3 CH.sub.3 CH      183-185 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3      CH.sub.3 CH 158-159 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H Cl      OCH.sub.3 CH 157-159 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H      OCH.sub.3 OCH.sub.3 N 165-168 C(O)N(CH.sub.3).sub.2 CH.sub.2 SCN H O H      OCH.sub.3 OCH.sub.3 N C(O)N(CH.sub.3).sub.2 CH.sub.2 SCN H O H CH.sub.3      OCH.sub.3 CH C(O)N(CH.sub.3).sub.2 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H      OCH.sub.3 OCH.sub.3 CH C(O)N(CH.sub.3).sub.2 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N C(O)N(CH.sub.3).sub.2      CH.sub.2 SeCH.sub.2 CH.sub.2 CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH      C(O)N(CH.sub.3).sub.2 CH.sub.2 N(CH.sub.3).sub.2 H O H OCH.sub.3      CH(OCH.sub.3).sub.2 CH SO.sub.2 NHCH.sub.3 CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 N SO.sub.2 NHCH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH      SO.sub.2 NHCH.sub.3 CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 CH SO.sub.2      NHCH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N SO.sub.2 NHCH.sub.3      CH.sub.2 SCN H O H OCH.sub.3 CH.sub.3 CH SO.sub.2 NHCH.sub.3 CH.sub.2      SCN H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2 NHCH.sub.3 CH.sub.2 SCN H O H      CH.sub.3 OCH.sub.3 N SO.sub.2 NHCH.sub.3 CH.sub.2 SCN H O H Cl OCH.sub.3      CH SO.sub.2 NHCH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H CH.sub.3      OCH.sub.3 CH SO.sub.2 NHCH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H      OCH.sub.3 OCH.sub.3 N SO.sub.2 NHCH.sub.2 CH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH SO.sub.2 NHCH.sub.2 CH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 CH.sub.3 CH SO.sub.2 NHCH.sub.2 CH.sub.3 CH.sub.2 SCN H O H      OCH.sub.3 OCH.sub.2 N SO.sub.2 NHCH.sub.2 CH.sub.3 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 OCH.sub.3 CH SO.sub.2       N(CH.sub.3)(CH.sub.2 CH.sub.3) CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH      SO.sub.2 NHCH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3      CH.sub.3 CH SO.sub.2 N(CH.sub.2 CH.sub.3).sub.2 CH.sub.2 SCN H O H Cl      OCH.sub.3 CH SO.sub.2 N(CH.sub.3)(CH(CH.sub.3).sub.2) CH.sub.2 SCN H O H      OCH.sub.3 OCH.sub.3N SO.sub.2 N(CH.sub.3)(OCH.sub.3) CH.sub.2       P(O)(OCH.sub.3) H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2       N(CH.sub.3)(OCH.sub.3) CH.sub.2 P(O)(OCH.sub.3) H O H OCH.sub.3      CH.sub.3 CH SO.sub.2 N(CH.sub.3)(OCH.sub.3) CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 CH SO.sub.2 N(CH.sub.3)(OCH.sub.3) CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 N SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 CH SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 CN H O H OCH.sub.3      CH.sub.3 CH SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 CN H O H CH.sub.3      OCH.sub.2 CHCH.sub.2 CH SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 CN H O H      OCH.sub.3 CH.sub.3 N SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 SCN H O H      CH.sub.2 CH.sub.3 OCH.sub.3 CH SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 SCN H      O H OCH.sub.3 N(CH.sub.3)(CH(CH.sub.3).sub.2) CH SO.sub.2       N(CH.sub.3).sub.2 CH.sub. 2 SCN H O H OCH.sub.3 OCH.sub.3 N SO.sub.2      N(CH.sub.3).sub.2 CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2      N(CH.sub.3).sub.2 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3      CH.sub.3 CH SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 P(O)(OCH.sub.3).sub.2 H      O H OCH.sub.3 OCH.sub.3 N SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 OCH.sub.2 C(CH.sub.3)CH.sub.2 CH      SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2       N(CH.sub.3).sub.2 CH.sub.2 NO.sub.2 H O H OCH.sub.3 CH.sub.2       S(CH.sub.2).sub.3 CH.sub.3 N SO.sub.2 CH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3      (CH.sub.2).sub.4 CH.sub.2 SCH.sub.2 CH.sub.3 CH SO.sub.2 CH.sub.3      CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N SO.sub.2 CH.sub.3 CH.sub.2 CN H      O H CH.sub. 3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2       SCN H O H OCH.sub.3 CH.sub.3 CH SO.sub.2 CH.sub.3 C(O)H H O H OCH.sub.3      OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2       N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 SCN H O      H OCH.sub.3 OCH.sub.3 N SO.sub.2 CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3      cylclopropyl CH SO.sub.2 CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3      CH SO.sub.2 CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H CH.sub.3      OCH.sub.3 N SO.sub.2 CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H      OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2      H O H CH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 N SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 2-methylcyclopropyl CH SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN      H O H OCH.sub.3 CH.sub.3 N SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H      CH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H      OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H      OCH.sub.3 CH.sub.3 CH SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H      CH.sub.3 CCH CH SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3      cyclopentyl N SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H CH.sub.2      CH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 CH.sub.3 CH SO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N      SO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2      CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 CH      SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H CH.sub.3 CH.sub.3      CH SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H Cl OCH.sub.3 CH      SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2       CN H O H OCH.sub.3 OCH.sub.3 N SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3      CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 N SO.sub.2 CH.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3 CH.sub.3 CH SO.sub.2      CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H CH.sub.3 CH.sub.3 CH      SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H Cl OCH.sub.3      CH SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3      OCH.sub.3 N SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H      OCH.sub.3 CH.sub.3 N SCH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH      SCH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N      S(O)CH.sub.2 CH.sub.3 CH.sub.2       SCN H O H CH.sub.3 OCH.sub.3 CH S(O)CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N OSO.sub.2 CH.sub.3      CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 N OSO.sub.2 CH.sub.3 CH.sub.2 CN H      O H CH.sub.3 OCH.sub.3 CH OSO.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3      CHO CH OSO.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N      OSO.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH OSO.sub.2      CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3 CCCH.sub.3 CH OSO.sub.2 CH.sub.3      CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 N OSO.sub.2 CH.sub.3 CH.sub. 2      SCN H O H OCH.sub.3 CH.sub.3 CH OSO.sub.2 CH.sub.3 CH.sub.2 SCN H O H      OCH.sub.3 OCH.sub.3 CH OSO.sub.2 CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2      H O H CH.sub.3 OCH.sub.3 N OSO.sub.2 CH.sub.3 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 COCH.sub.3 CH OSO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 CN H O H CH.sub.3 OCH.sub.3 CH OSO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N OSO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH OSO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 CH(OCH.sub.3).sub.2 CH OSO.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 N OSO.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H CH.sub.3 OCH.sub.3 CH OSO.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 CH OSO.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 SCN H O H OCH.sub.3 CH.sub.3 CH OSO.sub. 2      CH.sub.2 CH.sub.3 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 OCH.sub.3 CH OSO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 CH.sub.3 N      OSO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H      CH.sub.2 CH.sub.3 OCH.sub.3 CH OSO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3      CH.sub.2 CN H O H OCH.sub.3 CH(SCH.sub.3)(OCH.sub.2 CH.sub.3) CH      OSO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 N OSO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH OSO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN      H O H OCH.sub.3 CH.sub.3 CH CH.sub.2 OCH.sub.3 CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N CH.sub.2 SCH.sub.3      CH.sub.2       P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 C(CH.sub.3)(SCH.sub.3).sub.2 CH      CH.sub.2 CH.sub.3 OCH.sub.3 CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H      OCH.sub.3 OCH.sub.3 CH CH.sub.2 CH.sub.2 OCH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 N CH.sub.2 CH.sub.2 OCH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH CH.sub.2 CH.sub.2 SCH.sub.2 CH.sub.3 CH.sub.2 CN      H O H OCH.sub.3 1,3-dioxolan-2-yl CH CH.sub.2 CN CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 N C.sub.2 H.sub.5 CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 CH C.sub.2 H.sub.5 CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 CH      C.sub.2 H.sub.5 CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 N C.sub.2 H.sub.5      CH.sub.2 SCN H O H OCH.sub.3 2-methyl-1,3-oxathion-2-yl CH COCH.sub.3      CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 CH COCH.sub.2 CH.sub.3 CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 OCH.sub.3 N COCCCH.sub.3 CH.sub.2      CN H O H OCH.sub.3 CH.sub.3 CH COCH.sub.2 CH.sub.2 Cl CH.sub.2 CN H O H      CH.sub.3 OCH.sub.3 CH C(O)-cyclo-propyl CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 N C(O)-cyclo-propyl CH.sub.2 CN H O H CH.sub.3 OCH.sub.3 CH      C(O)-cyclo-propyl CH.sub.2       SCN H O H OCH.sub.3 CH.sub.3 CH CH(OCH.sub.3).sub.2 CH.sub.2 SCN H O H      OCH.sub.3 OCH.sub.3 N CH(OCH.sub.3).sub.2 CH.sub.2 SCN H O H CH.sub.3      OCH.sub.3 CH CH(OCH.sub.2 CH.sub.3).sub.2 CH.sub.2 P(O)(OCH.sub.3).sub.2      H O H OCH.sub.3 OCH.sub.3 CH CH(OCH.sub.2 CH.sub.3).sub.2 CH.sub.2      P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 CH.sub.3 CH 1,3-dioxyl-2-yl      CH.sub.2 CN H O H CH.sub.3 OCH.sub.3 CH 1,3-dioxyl-2-yl CH.sub.2 CN H O      H OCH.sub.3 CH.sub.3 N R.sub.1 -A CH.sub.2 CN H O H CH.sub.2 CH.sub.3      OCH.sub.3 CH R.sub.1 -A CH.sub.2 CN H O H OCH.sub.3 1,3-oxathion-2-yl CH      R.sub.1 -A CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -A CH.sub.2      CN H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -A CH.sub.2 CN H O H OCH.sub.3      CH.sub.3 CH R.sub.1 -A CH.sub. 2 SCN H O H OCH.sub.3 OCH.sub.3 N R.sub.1      -A CH.sub.2 SCN H O H CH.sub.3 2-methyl-1,3-dithian-2-yl CH R.sub.1 -A      CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -A      CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -A      CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -B      CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 CH R.sub.1 -B CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 N R.sub.1 -B CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3      CH R.sub.1 -B CH.sub.2 CN H O H OCH.sub.3 4-methyl-1,3-dioxolan-2-yl CH      R.sub.1 -B CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -B CH.sub.2      SCN H O H Cl OCH.sub.3 CH R.sub.1 -B CH.sub.2 SCN H O H OCH.sub.3      OCH.sub.3 CH R.sub.1 -B CH.sub.2 SCN H O H CH.sub.3 OCH.sub.3 N R.sub.1      -B CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1      -B CH.sub.2 P(O)(OCH.sub.3).sub.2 H O H CH.sub.3 OCH.sub.3 CH R.sub.1 -C      CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -C CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -C CH.sub.2       CN H O H OCH.sub.3 4-methyl-1,3-oxathiolan-2-yl CH R.sub.1 -C CH.sub.2      CN H O H OCH.sub.3 CH.sub.3 N R.sub.1 -C CH.sub.2 SCN H O H CH.sub.3      OCH.sub.3 CH R.sub.1 -C CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -C CH.sub.2 SCN H O H OCH.sub.3 CH.sub.3 CH R.sub.1 -C CH.sub.2      P(O)(OMe).sub.2 H O H CH.sub.3OCH.sub.3 CH R.sub.1 -C CH.sub.2       P(O)(OMe).sub.2 H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -C CH.sub.2      P(O)(OMe).sub.2 H O H CH.sub.2 CH.sub.3 OCH.sub.3 CH R.sub.1 -D CH.sub.2      P(O)(OMe).sub.2 H O H OCH.sub.3 2,4-dimethyl-1,3-dithiolan-2-yl CH      R.sub.1 -D CH.sub.2 P(O)(OMe).sub.2 H O H OCH.sub.3 OCH.sub.3 N R.sub.1      -E CH.sub.2 P(O)(OMe).sub.2 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -F      CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -G CH.sub.2 CN H O H      OCH.sub.3 N(OCH.sub.3)CH.sub.3 CH R.sub.1 -H CH.sub.2 CN H O H OCH.sub.3      OCH.sub.3 N R.sub.1 -I CH.sub.2 CN H O H CH.sub.3 CH.sub.3 CH R.sub.1 -J      CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -K CH.sub.2 SCN H O H      OCH.sub.3 OCH.sub.3 N R.sub.1 -L CH.sub.2 SCN H O H OCH.sub.3 OCH.sub.3      CH R.sub.1 -M CH.sub.2 SCN H O H OCH.sub.3 CH.sub.3 CH R.sub.1 -N      CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -O CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -P CH.sub.2 CN H O H Cl OCH.sub.3 CH      R.sub.1 -Q CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -R CH.sub.2      P(O)(OMe).sub.2 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -S CH.sub.2      P(O)(OMe).sub.2 H O H OCH.sub. 3 OCH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.3      CH.sub.2 N.sub.3 6-CHF.sub.2 0 H OCH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 N.sub.3 6-CHF.sub.2 O H CH.sub.3 CH.sub.3 CH CO.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-OCH.sub.3 O H Cl OCH.sub.3 CH      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-OCH.sub.3 O H OCH.sub.3      OCH.sub.3 N CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN 6-CHF.sub.2 O H Cl      OCH.sub.3 CH CO.sub.2 CH(CH.sub.3).sub.2 CH.sub.2       N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH 157-160 CO.sub.2       CH(CH.sub.3).sub.2 CH.sub.2 N.sub.3 H O H OCH.sub.3 CH.sub.3 CH 168-171      CO.sub.2 CH(CH.sub.3).sub.2 CH.sub.2 N.sub.3 H O H Cl OCH.sub.3 CH      165-167 CO.sub.2 CH(CH.sub.3).sub.2 CH.sub.2 N.sub.3 H O H CH.sub.3      CH.sub.3 CH 181-183 CO.sub.2 CH(CH.sub.3).sub.2 CH.sub.2 N.sub.3 H O H      OCH.sub.3 OCH.sub.3 N 183-185 CO.sub.2 CH(CH.sub.3).sub. 2 CH.sub.2      N.sub.3 H O H OCH.sub.3 CH.sub.3 N 157-158 CO.sub.2 CH(CH.sub.3).sub.2      CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH 208-211 CO.sub.2       CH(CH.sub.3).sub.2 CH.sub.2 CN H O H Cl OCH.sub.3 CH 207-208 CO.sub.2      CH(CH.sub.3).sub.2 CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 CH 204-205      CO.sub.2 CH(CH.sub.3).sub.2 CH.sub.2 CN H O H CH.sub.3 CH.sub.3 CH      196-198 CO.sub.2 CH(CH.sub.3).sub.2 CH.sub.2       CN H O H OCH.sub.3 OCH.sub.3 N 173-174 CO.sub.2 CH(CH.sub.3).sub.2      CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 N 192-193 Cl CH(CH.sub.3)CN H O H      OCH.sub.3 OCH.sub.3 CH OCH.sub.3 CHFCN H O H OCH.sub.3 CH.sub.3 CH      CO.sub.2 CH.sub.3 CH(CH.sub.2 CH.sub.3)SCN H O H CH.sub.3 CH.sub.3 CH      NO.sub.2 CH(CH.sub.3)P(O)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH      SO.sub.2 N(CH.sub.3).sub.2 CH(CH.sub.2 CH.sub.3)P(S)(CH.sub.3).sub.2 H O      H OCH.sub.3 CH.sub.3 N CO.sub.2       N(CH.sub.3).sub.2 CH(CH.sub.3)N(CH.sub.3).sub.2 H O H Cl OCH.sub.3 CH      OCH.sub.3 CH(OC(O)CH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N OCH.sub.3      CH(CH.sub.2       CH.sub.3)N.sub.3 H O H OCH.sub.3 CH.sub.3 CH Cl CH(CH.sub.3)SeCH.sub.3      H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.3 CH(CH.sub.2      CH.sub.3)N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH OCH.sub.2 CH.sub.3      CH(CH.sub.3)N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH OCH.sub.2 CH.sub.3      CH(CH.sub.3)N.sub.3 H O H OCH.sub.3 CH.sub.3 CH OCH.sub.2 CH.sub.3      CH(CH.sub.3)N.sub.3 H O H Cl OCH.sub.3 CH OCH.sub.2       CH.sub.3 CH(CH.sub.3)N.sub.3 H O H OCH.sub.3 OCH.sub.3 N OCH.sub.2      CH.sub.3 CH(CH.sub.3)N.sub.3 H O H OCH.sub.3 CH.sub.3 N OCH.sub.2      CH.sub.3 CH(CH.sub.3)CN H O H OCH.sub.3 OCH.sub.3 CH OCH.sub.2 CH.sub.3      CH(CH.sub.3)CN H O H OCH.sub.3 CH.sub.3 CH OCH.sub.2       CH.sub. 3 CH(CH.sub.3)CN H O H OCH.sub.3 CH.sub.3 N CO.sub.2 CH.sub.3      CH(CH.sub.2       CH.sub.3)NC H O H OCH.sub.3 OCH.sub.3 CH Cl CH(OCH.sub.3).sub.2 H O H      OCH.sub.3 OCH.sub.3 CH NO.sub.2 CH(OCH.sub.3).sub.2 H O H OCH.sub.3      OCH.sub.3 CH SO.sub.2 N(CH.sub.3).sub.2 CH(OCH.sub.3).sub.2 H O H      OCH.sub.3 OCH.sub.3 CH SO.sub.2 N(CH.sub.3).sub.2 CH(OCH.sub.3).sub.2 H      O H Cl OCH.sub.3 CH OCH.sub.3 CH(OCH.sub.3).sub.2 H O H OCH.sub.3      OCH.sub.3 N OCH.sub.3 CH(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH      OCH.sub.2 CH.sub.3 CH(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N      CO.sub.2 CH.sub.3 CH(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.3 CH(OCH.sub.3).sub.2 H O H OCH.sub.3 CH.sub.3 CH      CO.sub.2 CH.sub.3 CH(OCH.sub.3).sub.2 H O H OCH.sub.3 CH.sub.3 N      CO.sub.2 CH.sub.3 CH(OCH.sub.2 CH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3      CH CO.sub.2 CH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2 H O H OCH.sub.3      OCH.sub.3 CH CO.sub.2 CH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2 H O H      OCH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2 H O      H OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2 H      O H CH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2      H O H Cl OCH.sub.3 CH OCH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2 H O H      OCH.sub.3 OCH.sub.3 CH OCH.sub.2 CH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2 H      O H OCH.sub.3 OCH.sub.3 CH OCH.sub.2       CH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2 H O H OCH.sub.3 CH.sub.3 CH      OCH.sub.2       CH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 N      OCH.sub.2 CH.sub.3 C(CH.sub.3)(OCH.sub.3).sub.2 H O H CH.sub.3 CH.sub.3      CH CO.sub.2 CH.sub.3 C(CH.sub.2 CH.sub.3)(OCH.sub.3).sub.2 H O H      OCH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.3 CH(SCH.sub.3).sub.3 H O H      OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3 C(CH.sub.2       CH.sub.3)(SCH.sub.3).sub.2 H O H OCH.sub.3 OCH.sub.3 CH  CO.sub.2      CH.sub.3       H O H OCH.sub.3 OCH.sub.3 CH       OCH.sub.3      ##STR28##       H O H OCH.sub.3 OCH.sub.3 CH  CO.sub.2       CH.sub.3 CH(CN)(OSi(CH.sub.3).sub.3) H O H OCH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.3 CH(CN)(OSi(CH.sub.3).sub.3) H O H OCH.sub.3 CH.sub.3      CH CO.sub.2 CH.sub.3 C(CH.sub.3)(CN)OH H O H OCH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.3 C(CH.sub.2 CH.sub.3)(CN)OCH.sub.3 H O H OCH.sub.3      OCH.sub.3 CH CO.sub.2 CH.sub.3 1,-3-dithiolan-2-yl H O H OCH.sub.3      OCH.sub.3 N CO.sub.2 CH.sub.3 1,-3-dithiolan-2-yl H O H Cl OCH.sub.3 CH      Cl 1,-3-dithiolan-2-yl H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3      1,-3-dioxolan-2-yl H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3      1,-3-dioxolan-2-yl H O H OCH.sub.3 CH.sub.3 CH NO.sub.2 1,-3-dioxolan-2-y      l H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2       CH.sub.3 2-methyl-1,3-dioxolan-2-yl H O H OCH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.3 1,-3-dioxolan-2-yl H O H OCH.sub.3 OCH.sub.3 N      CO.sub.2 CH.sub.3 1,-3-dioxolan-2-yl H O H OCH.sub.3 CH.sub.3 CH      CO.sub.2 CH.sub.3 1,-3-dioxolan-2-yl H O H Cl OCH.sub.3 CH SO.sub.2      N(CH.sub.3).sub.2 1,3-dithian-2-yl H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2      CH.sub.3 2-methyl-1,3-dioxan-2-yl H O H OCH.sub.3 OCH.sub.3 CH C.sub.6      H.sub.5 CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 CH       Cl      ##STR29##       H O H OCH.sub.3 OCH.sub.3 CH       NO.sub.2      ##STR30##       H O H OCH.sub.3 OCH.sub.3 CH       OCH.sub.3      ##STR31##       H O H OCH.sub.3 OCH.sub.3 CH       OCH.sub.3      ##STR32##       H O H OCH.sub.3 CH.sub.3 CH       OCH.sub.3      ##STR33##       H O H OCH.sub.3 OCH.sub.3 CH  OCH.sub.2       CH.sub. 3      ##STR34##       H O H OCH.sub.3 OCH.sub.3 CH  OCH.sub.2       CH.sub.3      ##STR35##       H O H OCH.sub.3 OCH.sub.3 CH  OCH.sub.2       CH.sub.3      ##STR36##       H O H OCH.sub.3 CH.sub.3 N  OCH.sub.2       CH.sub.3      ##STR37##       H O H CH.sub.3 CH.sub.3 CH  OCH.sub.2       CH.sub.3      ##STR38##       H O H OCH.sub.3 CH.sub.3 CH  OCH.sub.2       CH.sub.3      ##STR39##       H O H Cl OCH.sub.3 CH  OCH.sub.2       CH.sub.3      ##STR40##       H O H OCH.sub.3 OCH.sub.3 N  OCH.sub.2       CH.sub.3      ##STR41##       H O H OCH.sub.3 OCH.sub.3 CH  OCH.sub.2       CH.sub.3      ##STR42##       H O H OCH.sub.3 OCH.sub.3 N  OCH.sub.2       CH.sub.3      ##STR43##       H O H Cl OCH.sub.3 CH   CO.sub.2       CH.sub.3      ##STR44##       H O H OCH.sub.3 OCH.sub.3 CH  CO.sub.2       CH.sub.3      ##STR45##       H O H OCH.sub.3 CH.sub.3 CH  CO.sub.2       CH.sub.3      ##STR46##       H O H Cl OCH.sub.3 CH  CO.sub.2       CH.sub.3      ##STR47##       H O H OCH.sub.3 OCH.sub.3 N  CO.sub.2       CH.sub.3      ##STR48##       H O H OCH.sub.3 CH.sub.3 N  CO.sub.2       CH.sub.3      ##STR49##       H O H CH.sub.3 CH.sub.3 CH  CO.sub.2       CH.sub.3      ##STR50##       H O H OCH.sub.3 OCH.sub.3 CH  CO.sub.2       CH.sub.3      ##STR51##       H O H OCH.sub.3 CH.sub.3 CH  CO.sub.2       CH.sub.3      ##STR52##       H O H OCH.sub.3 OCH.sub.3 N  CO.sub.2       CH.sub.3      ##STR53##       H O H OCH.sub.3 CH.sub.3 N  CO.sub.2 CH.sub.2       CH.sub.3      ##STR54##       H O H OCH.sub.3 OCH.sub.3 CH  CO.sub.2 CH.sub.2       CH.sub.3      ##STR55##       H O H OCH.sub.3 CH.sub.3 CH  CO.sub.2 CH.sub.2       CH.sub.3      ##STR56##       H O H Cl OCH.sub.3 CH  OSO.sub.2       CH.sub.3      ##STR57##       H O H OCH.sub.3 CH.sub.3 CH  SO.sub.2 CH.sub.2       CH.sub.3      ##STR58##       H O H OCH.sub.3 OCH.sub.2 CH.sub.3 CH  C(O)N(CH.sub.2 CH.sub.3).sub.2      Cl H O H CH.sub.3 CH.sub.3 CH Cl CH.sub.2 N.sub.3 H O H OCH.sub.3      OCH.sub.3 CH Cl CH.sub.2 N.sub.3 H O H OCH.sub.3 CH.sub.3 CH Cl CH.sub.2      N.sub.3 H O H CH.sub.3 CH.sub.3 CH Cl CH.sub.2       N.sub.3 H O H Cl OCH.sub.3 CH Cl CH.sub.2 N.sub.3 H O H OCH.sub.3      OCH.sub.3 N Cl CH.sub.2 N.sub.3 H O H OCH.sub.3 CH.sub.3 N  CO.sub.2      CH.sub.2       CH.sub.3      ##STR59##       H O H OCH.sub.3 OCH.sub.3 CH  CO.sub.2 CH.sub.2       CH.sub.3      ##STR60##       H O H CH.sub.3 CH.sub.3 CH  CO.sub.2 CH.sub.2       CH.sub.3      ##STR61##       H O H OCH.sub.3 OCH.sub.3 N  CO.sub.2 CH.sub.2       CH.sub.3      ##STR62##       H O H OCH.sub.3 CH.sub.3 N CO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2      N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3      CH.sub.2 N.sub.3 H O H OCH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 N.sub.3 H O H CH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H Cl OCH.sub.3 CH CO.sub.2      CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3 N      CO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O H OCH.sub.3      CH.sub.3 N CO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN H O H      OCH.sub.3 OCH.sub.3 CH CO.sub. 2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN      H O H OCH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2      CN H O H CH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3      CH.sub.2 CN H O H Cl OCH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3      CH.sub.2 CN H O H OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 CN H O H OCH.sub.3 CH.sub.3 N CO.sub.2 CH.sub.3      CHNOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3 CHNOCH.sub.3      H O H OCH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.3 CHNOCH.sub.3 H O H      CH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.3 CHNOCH.sub.3 H O H Cl OCH.sub.3      CH CO.sub.2 CH.sub.3 CHNOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 N CO.sub.2      CH.sub.3 CHNOCH.sub.3 H O H OCH.sub.3 CH.sub.3 N OCH.sub.2 CH.sub.3      C(CH.sub.3)NOH H O H OCH.sub.3 OCH.sub.3 CH OCH.sub.2 CH.sub.3 C(CH.sub.3      )NOH H O H OCH.sub.3 CH.sub.3 CH OCH.sub.2 CH.sub.3 C(CH.sub.3)NOH H O H      CH.sub.3 CH.sub.3 CH OCH.sub.2       CH.sub.3 C(CH.sub.3)NOH H O H Cl OCH.sub.3 CH OCH.sub.2 CH.sub.3      C(CH.sub.3)NOH H O H OCH.sub.3 OCH.sub.3 N OCH.sub.2                     N       CH.sub.3 C(CH.sub.3)OH H O H OCH.sub.3 CH.sub.3 N OCH.sub.2 CH.sub.3      C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH OCH.sub.2 CH.sub.3      C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 CH.sub.3 CH OCH.sub.2 CH.sub.3      C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 N OCH.sub.2 CH.sub.3      C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 CH.sub.3 N F CHNOH H O H OCH.sub.3      OCH.sub.3 CH F CHNOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH F C(CH.sub.3)NOH       H O H OCH.sub.3 OCH.sub.3 CH F C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3      OCH.sub.3 CH Cl CHNOH H O H OCH.sub.3 OCH.sub.3 CH Cl CHNOCH.sub.3 H O H      OCH.sub.3 OCH.sub.3 CH Cl C(CH.sub.3)NOH H O H OCH.sub.3 OCH.sub.3 CH Cl      C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH NO.sub.2 CHNOH H O H      OCH.sub.3 OCH.sub.3 CH NO.sub.2 CHNOCH.sub.3 H O H OCH.sub.3 OCH.sub.3      CH NO.sub.2 C(CH.sub.3)NOH H O H OCH.sub.3 OCH.sub.3 CH NO.sub.2      C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH CH.sub.3 CHNOH H O H      OCH.sub.3 OCH.sub.3 CH CH.sub.3 CHNOCH.sub.3 H O H OCH.sub.3 OCH.sub.3      CH CH.sub.3 C(CH.sub.3)NOH H O H OCH.sub.3 OCH.sub.3 CH CH.sub.3      C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH C(O)N(CH.sub.3).sub.2      CHNOH H O H OCH.sub.3 OCH.sub.3 CH C(O)N(CH.sub.3).sub.2 CHNOCH.sub.3 H      O H OCH.sub.3 OCH.sub.3 CH C(O)N(CH.sub.3).sub.2 C(CH.sub.3)NOH H O H      OCH.sub.3 OCH.sub.3 CH C(O)N(CH.sub.3 ).sub.2 C(CH.sub.3)NOCH.sub.3 H O      H OCH.sub.3 OCH.sub.3 CH SO.sub.2       N(CH.sub.3).sub.2 CHNOH H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2       N(CH.sub.3).sub.2 CHNOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2      N(CH.sub.3).sub.2 C(CH.sub.3)NOH H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2      N(CH.sub.3).sub.2 C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH      SO.sub.2 CH.sub.3 CHNOH H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3   N      CHOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2       CH.sub.3 C(CH.sub.3)NOH H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3      CH(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH OSO.sub.2 CH.sub.3   N      CHOH H O H OCH.sub.3 OCH.sub.3 CH OSO.sub.2 CH.sub.3 CHNOCH.sub.3 H O 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CH(OCH.sub.3).sub.2 CHNOCH.sub.3 H O H OCH.sub.3 OCH.sub.3      CH CH(OCH.sub.3).sub.2 C(CH.sub.3)NOH H O H OCH.sub.3 OCH.sub.3 CH      CH(OCH.sub.3).sub.2 C(CH.sub.3)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -A CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -B CHNOH H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -C CHNOH H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -D CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -E CHNOH H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -F CHNOH H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -G CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -H CHNOH H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -I CHNOH H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -J CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -K CHNOH H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -L CH NOH H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -M CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -N CHNOH H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -O CHNOH H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -P CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -Q CHNOH H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -R CHNOH H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -S CHNOH H O H OCH.sub.3 OCH.sub.3 CH NO.sub.2 CH.sub.2 CN 6-Cl      O H CH.sub.3 CH.sub.3 CH NO.sub.2 CH.sub.2       CN 6-Cl O H CH.sub.3 OCH.sub.3 CH NO.sub.2 CH.sub.2 CN 6-Cl O H      OCH.sub.3 OCH.sub.3 CH NO.sub.2 CH.sub.2 CN 6-Cl O H Cl OCH.sub.3 CH      NO.sub.2 CH.sub.2 CN 6-Cl O H OCH.sub.3 OCH.sub.3 N NO.sub.2 CH.sub.2 CN      6-Cl O H OCH.sub.3 CH.sub.3 N CF.sub.3 CH.sub.2 CN 6-Cl O H OCH.sub.3      OCH.sub.3 CH OCH.sub.3 CH.sub.2 CN 6-Cl O H OCH.sub.3 CH.sub.3 CH      OCH.sub.3 CH.sub.2 CN 6-F O H OCH.sub.3 CH.sub.3 CH OCH.sub.3 CH.sub.2      CN 6-F O H OCH.sub.3 OCH.sub.3 CH OCH.sub.3 CH.sub.2 CN 6-Cl O H      OCH.sub.3 OCH.sub.3 CH OCH.sub.3 CH.sub.2 O(CO)CH.sub.3 6-Cl O H      OCH.sub.3 OCH.sub.3 CH OCH.sub.3 CH.sub.2 O(CO)CH.sub.3 6-Cl O H      OCH.sub.3 CH.sub.3 CH OCH.sub.3 CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3      OCH.sub.3 CH OCH.sub.3 CH.sub.2 N.sub.3 6-F O H OCH.sub.3 OCH.sub.3 CH      OCH.sub.3 CH.sub.2 N.sub.3 6-F O H OCH.sub.3 CH.sub.3 CH OCH.sub.3      CH.sub.2 NO.sub.2 6-Cl O H OCH.sub.3 CH.sub.3 CH OCH.sub.3 CH.sub.2      NO.sub.2 6-Cl O H OCH.sub.3 OCH.sub.3 CH OCH.sub.2 CH.sub.2 Cl CH.sub.2      N.sub.3 6-OCH.sub.3 O H OCH.sub.3 CH.sub.3 CH OCH.sub.2 CH.sub.2 Cl      CH.sub.2 N.sub.3 6 OCH.sub.3 O H OCH.sub.3 OCH.sub.3 CH Cl CH.sub.2      O(CO)CH.sub.3 H O H CH.sub.3 OCH.sub.3 CH Cl CH.sub.2 O(CO)CH.sub.3 H O      H OCH.sub.3 OCH.sub. 3 CH Cl CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3      CH.sub.3 N Cl CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 N      OCH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H CH.sub.3 CH.sub.3 CH OCH.sub.3      CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 CH.sub.3 CH OCH.sub.3 CH.sub.2      O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH OCH.sub.3 CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 N OCH.sub.2 CH.sub.2 Cl      CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 CH.sub.3 CH OCH.sub.2 CH.sub.2 Cl      CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH C(O)N(CH.sub.3).sub.2      CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH C(O)N(CH.sub.3).sub.2      CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 N C(O)N(CH.sub.3).sub.2      CH.sub.2 O(CO)CH.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 CH SO.sub.2       N(CH.sub.3).sub.2 CH.sub.2 O(CO)CH.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 N      SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3      OCH.sub. 3 CH SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 OSO.sub.2 CH.sub.3 H O      H OCH.sub.3 OCH.sub.3 CH SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 OSO.sub.2      CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 CN 6-Cl      O H OCH.sub.3 CH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 CN 6-Cl O H      OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H      OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H      OCH.sub.3 OCH.sub.3 N SO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-Cl O H      OCH.sub.3 CH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-Cl O H      OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 OSO.sub.2 CH.sub.3 H O      H CH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 OSO.sub.2 CH.sub.3 H      O H OCH.sub.3 OCH.sub.3 N SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2      N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 N SO.sub.2 CH.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3 CH.sub.3 CH SO.sub.2      CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3      CH SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H      CH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2      O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 NSO.sub.2 CH.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 O(CO)CH.sub.3HOH OCH.sub.3 OCH.sub.3 N SO.sub.2      CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 OSO.sub.2 CH.sub.3 H O H OCH.sub.3      OCH.sub.3 CH SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 OSO.sub.2      CH.sub.3 H O H OCH.sub.3 OCH.sub.3 N 1,3-dioxyl-2-yl CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH 1,3-dioxyl-2-yl CH.sub.2      O(C0)CH.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -A CH.sub.2      O(CO)CH.sub.3 H O H OCH.sub.3 CH.sub.3 CH R.sub.1 -A CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -A CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -A CH.sub.2       O(CO)CH.sub.3 6-Cl O H OCH.sub.3 OCH.sub. 3 CH R.sub.1 -A CH.sub.2      N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2      O(CO)CH.sub.3 H O H CH.sub.3 OCH.sub.3 CH 180-181 CO.sub.2 CH.sub.3      CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH 182-184 CO.sub.2      CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H Cl OCH.sub.3 CH 188-190 CO.sub.2      CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 CH.sub.3 N 172-173      CO.sub.2 CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 N      181-183 CO.sub.2 CH.sub.3 CH.sub.2 CN 6-Cl O H OCH.sub.3 CH.sub.3 CH      CO.sub.2 CH.sub.3 CH.sub.2 CN 6-Cl O H OCH.sub.3 OCH.sub.3 CH CO.sub.2      CH.sub.3 CH.sub.2 CN 6-Cl O H OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.3      CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3      CH.sub.2 O(CO)CH.sub.3 H O H CH.sub.3 CH.sub.3 CH 179-180 CO.sub.2      CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.2 CH.sub.3 NHCH.sub.3 N      >250 CO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-F O H OCH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-OCF.sub.2 H O H OCH.sub.3 OCH.sub.3      CH CO.sub.2 CH.sub.3 CH.sub.2 SCN 6-Cl O H OCH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.3 CH.sub.2 SCN 6-Cl O H OCH.sub.3 OCH.sub.3 CH CO.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3 CH.sub.3      CH CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3      OCH.sub.3 N CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H      CH.sub.3 CH.sub.3 CH 172-173 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2      O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH 162-163 CO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H CH.sub.3 OCH.sub.3 CH 160-162      CO.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 O(CO)CH.sub. 3 H O H Cl OCH.sub.3 CH      166-168 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 CH.sub.3 N 175-176 CO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 N 180-182      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 CN 6-Cl O H OCH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 NO.sub.2 H O H CH.sub.3 OCH.sub.3 CH      148-150 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 NO.sub.2 H O H OCH.sub.3      OCH.sub.3 CH 156-159 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 NO.sub.2 H O H      OCH.sub.3 OCH.sub.3 N 152-153 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2      NO.sub.2 H O H OCH.sub.3 CH.sub.3 N 138-140 CO.sub.2 CH.sub.2 CH.sub.3      CH.sub.2 NO.sub.2 H O H Cl OCH.sub.3 CH 155-157 CO.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 NO.sub.2 6-Cl O H OCH.sub.3 OCH.sub.3 CH CO.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 NO.sub.2 6-Cl O H OCH.sub.3 OCH.sub.3 N      R.sub.1 -B CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 N R.sub.1 -B      CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -B CH.sub.2      OSO.sub.2 CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -B CH.sub.2      OSO.sub.2 CH.sub.3 H O H OCH.sub.3 CH.sub.3 CH R.sub.1 -C CH.sub.2      O(CO)CH.sub.3 H O H OCH.sub.3 CH.sub.3 CH R.sub.1 -C CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -D CH.sub.2 N.sub.3      6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -O CH.sub.2 N.sub.3 6-Cl O H      OCH.sub.3 CH.sub.3 CH R.sub.1 -X CH.sub.2 N.sub.3 H O H CH.sub.3      OCH.sub.3 CH R.sub.1 -X CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -X CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -Y      CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3 N R.sub.1 -Y CH.sub.2 N.sub.3      H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -X CH.sub.2 O(CO)CH.sub. 3 H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -X CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3      CH.sub.3 CH R.sub.1 -Y CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3      CH R.sub.1 -Y CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 CH.sub.3 CH R.sub.1      -X CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -Y CH.sub.2      N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -X CH.sub.2 N.sub.3 6-Cl      O CH.sub.3 OCH.sub.3 OCH.sub.3 CH R.sub.1 -X CH.sub.2 N.sub.3 6-Cl O      CH.sub.3 OCH.sub.3 CH.sub.3 CH R.sub.1 -Z CH.sub.2 O(CO)CH.sub.3 H O H      OCH.sub.3 CH.sub.3 CH R.sub.1 -Z CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3      OCH.sub.3 CH R.sub.1 -Z CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -AA CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AA      CH.sub.2 NO.sub.2 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AA CH.sub.2      NO.sub.2 H O H OCH.sub.3 CH.sub.3 CH R.sub.1 -AB CH.sub.2 N.sub.3 H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -AB CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 CH.sub.3 CH R.sub.1 -AB CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AC CH.sub.2      O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AC CH.sub.2       O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AC CH.sub.2      O(CO)CH.sub.3 H O H OCH.sub.3 CH.sub.3 CH R.sub.1 -AC CH.sub.2 N.sub.3 H      O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AC CH.sub.2 N.sub.3 6-Cl O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -AD CH.sub.2 N.sub.3 H O H OCH.sub.3      OCH.sub.3 CH R.sub.1 -AD CH.sub.2 N.sub.3 H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -AD CH.sub.2 O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH CO.sub.2      CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O CH.sub.3 OCH.sub.3 OCH.sub.3 CH      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O CH.sub.3 OCH.sub.3      OCH.sub.3 CH CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 O(CO)CH.sub.3 H O      CH.sub.3 OCH.sub.3 CH.sub.3 N OCH.sub.2 CH.sub.3 CH(CH.sub.3)N.sub.3 H O      CH.sub.3 OCH.sub.3 CH.sub.3 N OCH.sub.2 CH.sub.3 CH(CH.sub.3)N.sub.3      6-Cl O H CH.sub.3 OCH.sub.3 CH NO.sub.2 CH.sub.2 O(O)CH.sub.3 6-Cl O H      OCH.sub.3 OCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2 O(O)CH.sub.3 H O      CH.sub.3 OCH.sub.3 CH.sub.3 N CO.sub.2       CH.sub.3 CH(CH.sub.3)O(CO)CH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH      NO.sub.2       ##STR63##       6-Cl O H OCH.sub.3 OCH.sub.3 CH       OCH.sub.3      ##STR64##       6-Cl O H OCH.sub.3 OCH.sub.3 CH       OCH.sub.3      ##STR65##       H O CH.sub.3 OCH.sub.3 CH.sub.3 N  SO.sub.2 CH.sub.2       CH.sub.3      ##STR66##       6-Cl 0 CH.sub.3 OCH.sub.3 CH.sub.3 N  SO.sub.2 CH.sub.2 CH.sub.3       ##STR67##       6-CF.sub. 2 H O H OCH.sub.3 OCH.sub.3 CH  CO.sub.2 CH.sub.2 CH.sub.2      CH.sub.3 CH.sub.2 N.sub.3 6-Cl O H OCH.sub.3 OCH.sub.3 CH CO.sub.2      CH.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 N.sub.3 H O CH.sub.3 OCH.sub.3      CH.sub.3 N CO.sub.2 CH.sub.3 CHNOCH.sub.3 6-Cl O CH.sub.3 OCH.sub.3      OCH.sub.3 CH F CHNOH 6-Cl O H OCH.sub.3 OCH.sub.3 CH F CHNOH 6-F O H      OCH.sub.3 OCH.sub.3 CH NO.sub.2 CHNOCH.sub.3 H O CH.sub.3 OCH.sub.3      CH.sub.3 N CH.sub.2 OCH.sub.3 CHNOH 6-Cl O H OCH.sub.3 OCH.sub.3 CH      CH.sub.2 OCH.sub.3 CHNOH H O CH.sub.3 OCH.sub.3 CH.sub.3 N R.sub.1 -A      CH4NOH 6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -A CHNOH H O CH.sub.3      OCH.sub.3 CH.sub.3 N R.sub.1 -B CHNOH 6-Cl O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -C CHNOH 6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -D CHNOH 6-Cl O      H OCH.sub.3 OCH.sub.3 CH R.sub.1 -E CHNOH 6-Cl O H OCH.sub.3 OCH.sub.3      CH R.sub.1 -O CHNOH 6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -O CHNOH H O      CH.sub.3 OCH.sub.3 CH.sub.3 N R.sub.1 -W CHNOH 6-CCl O H OCH.sub.3      OCH.sub.3 CH R.sub.1 -W CHNOH H O CH.sub.3 OCH.sub.3 CH.sub.3 N R.sub.1      -X CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -X CHNOCH.sub.3 H O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -X CHNOCH.sub.3 6-Cl O H OCH.sub.3      OCH.sub.3 CH R.sub.1 -Y CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -Y      CHNOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -Z CHNOH 6-Cl O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -Z CHNOH H O CH.sub.3 OCH.sub.3 CH.sub.3      N R.sub.1 -AA CHNOH 6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AA CHNOH H      O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AA CHNOH H O CH.sub.3 OCH.sub.3      CH.sub.3 N R.sub.1 -AB CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AB      CHNOH 6-Cl O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AC CHNOH 6-Cl O H      OCH.sub.3 OCH.sub.3 CH R.sub.1 -AC CHNOH H O H OCH.sub.3 OCH.sub.3 CH      R.sub.1 -AD CHNOH H O H OCH.sub.3 OCH.sub.3 CH R.sub.1 -AD CHNOH 6-F O H      OCH.sub.3 OCH.sub.3 CH F CH.sub.2 Br H O H OCH.sub.3 CH.sub.3 CH F      CH.sub.2 Br H O H OCH.sub.3 OCH.sub.3 CH F CH.sub.2 Br H O H OCH.sub.3      OCH.sub.3 N F CH.sub.2 Cl H O H OCH.sub.3 OCH.sub.3 N F CH.sub.2 Cl H O      H OCH.sub.3 CH.sub.3 CH Cl CH.sub.2 Br H O H OCH.sub.3 CH.sub.3 CH Cl      CH.sub.2 Br H O H OCH.sub.3 OCH.sub.3 CH Cl CH.sub.2 Cl H O H OCH.sub.3      CH.sub.3 N Cl CH.sub.2 Cl H O H OCH.sub.3 OCH.sub.3 N Br CH.sub.2 Br H O      H OCH.sub.3 CH.sub.3 CH Br CH.sub.2 Br H O H OCH.sub.3 CH.sub.3 N Br      CH.sub.2 Cl H O H OCH.sub.3 OCH.sub.3 N Br CH.sub.2 Cl H O H OCH.sub.3      OCH.sub.3 CH NO.sub.2 CH.sub.2 Br H O H CH.sub.3 CH.sub.3 CH 191-194 (D)      NO.sub.2 CH.sub.2 Br H O H OCH.sub.3 CH.sub.3 CH 200-201 NO.sub.2      CH.sub.2 Br H O H OCH.sub.3 OCH.sub.3 CH 194-195 NO.sub.2 CH.sub.2 Br H      O H Cl OCH.sub.3 CH 184-186 NO.sub.2 CH.sub.2 Br H O H OCH.sub.3      CH.sub.3 N 180-183 NO.sub.2 CH.sub.2 Br H O H OCH.sub.3 OCH.sub.3 N      154-157 NO.sub.2 CH.sub.2 Cl H O H OCH.sub.3 OCH.sub.3 CH NO.sub.2      CH.sub.2 Cl H O H OCH.sub.3 OCH.sub.3 N NO.sub.2 CH.sub.2 Cl H O H      OCH.sub.3 CH.sub.3 CH CO.sub.2 CH.sub.3 C(Cl)NOCH.sub.3 H O H OCH.sub.3      OCH.sub.3 CH CO.sub.2 CH.sub.3 C(Cl)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3      N  CO.sub.2 CH.sub.2 CH.sub.3 C(Cl)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3      CH CO.sub.2 CH.sub.3 C(CN)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 N      CO.sub.2 CH.sub.3 C(CN)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH Br      C(Cl)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH Br C(Cl)NOCH.sub.3 H O H      OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.2 CH.sub.3 C(CN)NOCH.sub.3 H O H      OCH.sub.3 OCH.sub.3 CH NO.sub.2 C(Cl)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3       CH NO.sub.2 C(CN)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 N NO.sub.2      C(CN)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH OCH.sub.3 C(CN)NOCH.sub.3 H      O H OCH.sub.3 OCH.sub.3 CH OCH.sub.3 C(Cl)NOCH.sub.3 H O H OCH.sub.3      OCH.sub.3 CH SO.sub.2 CH.sub.3 C(Cl)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3      CH SO.sub.2 CH.sub.3 C(CN)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH      SO.sub.2 CH.sub.3 C(SCH.sub.3 )NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 N F      C(Cl)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 CH F C(Cl)NOCH.sub.3 H O H      OCH.sub.3 OCH.sub.3 CH CF.sub.3 C(CN)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3       CH CF.sub.3 C(CN)NOCH.sub.3 H O H OCH.sub.3 OCH.sub.3 N CF.sub.3      C(CN)NOCH.sub.3 H O H OCH.sub.3 CH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2      Br H O H OCH.sub.3 OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 Br H O H      OCH.sub.3 OCH.sub.3 N SO.sub.2 CH.sub.3 CH.sub.2 Cl H O H OCH.sub.3      OCH.sub.3 CH SO.sub.2 CH.sub.3 CH.sub.2 Cl H O H OCH.sub.3 OCH.sub.3 N      SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 Br H O H OCH.sub.3 OCH.sub.3 CH+      SO.sub.2 N(CH.sub.3).sub.2 CH.sub.2 Cl H O H OCH.sub.3 OCH.sub.3 CH      OSO.sub.2 CH.sub.3 CH.sub.2 Br H O H OCH.sub.3 OCH.sub.3 CH OSO.sub.2      CH.sub.3 CH.sub.2 Cl H O H OCH.sub.3 OCH.sub.3 CH CO.sub. 2 CH.sub.3      CH.sub.2 Br H O H CH.sub.3 CH.sub.3 CH 176-178 CO.sub.2 CH.sub.3      CH.sub.2 Br H O H OCH.sub.3 CH.sub.3 CH 174-176 CO.sub.2 CH.sub.3      CH.sub.2 Br H O H OCH.sub.3 OCH.sub.3 CH 173-176 CO.sub.2 CH.sub.3      CH.sub.2 Br H O H Cl OCH.sub.3 CH 190-191 CO.sub.2 CH.sub.3 CH.sub.2 Br      H O H OCH.sub.3 CH.sub.3 N 171-173 CO.sub.2 CH.sub.3 CH.sub.2 Br H O H      OCH.sub.3 OCH.sub.3 N 180-182 CO.sub.2 CH.sub.3 CH.sub.2 Cl H O H      OCH.sub.3 OCH.sub.3 N CO.sub.2 CH.sub.3 CH.sub.2 Cl H O H OCH.sub.3      OCH.sub.3 CH CO.sub.2 CH.sub.3 CH.sub.2 Cl H O H OCH.sub.3 CH.sub.3 CH      CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 Br H O H CH.sub.3 CH.sub.3 CH      203-204 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 Br H O H OCH.sub.3 CH.sub.3      CH 181-182 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 Br H O H OCH.sub.3      OCH.sub.3 CH 195-197 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 Br H O H Cl      OCH.sub.3 CH 177-178 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 Br H O H      OCH.sub.3 CH.sub.3 N 157-159 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 Br H O      H OCH.sub.3 OCH.sub.3 N 179-181 CO.sub.2 CH.sub.2 CH.sub.3 CH.sub.2 Br H      O H OCH.sub.2 CH.sub.3 NHCH.sub.3 N 190-195 C(O)N(CH.sub.3).sub.2      CH.sub.2 Br H O H CH.sub.3 CH.sub.3 CH 193-194 C(O)N(CH.sub.3).sub.2      CH.sub.2 Br H O H OCH.sub.3 CH.sub.3 CH 177-178 C(O)N(CH.sub.3).sub.2      CH.sub.2 Br H O H OCH.sub.3 OCH.sub.3 CH 184 C(O)C(CH.sub.3).sub.2      CH.sub.2 Br H O H Cl OCH.sub.3 CH 188 C(O)N(CH.sub.3).sub.2 CH.sub.2 Br      H O H OCH.sub.3 CH.sub.3 N 209-210 C(O)N(CH.sub.3).sub.2 CH.sub.2 Br H O      H OCH.sub.3 OCH.sub.3 N 146-148 NO.sub.2 CH.sub.2 N H O H CH.sub.3      CH.sub.3 CH 190 NO.sub.2 CH.sub.2       N H O H OCH.sub.3 CH.sub.3 CH 182-183

                                      TABLE II                                     __________________________________________________________________________     General Formula II                                                             R.sub.1  R.sub.2     R.sub.x                                                                           X.sub.1                                                                             Y.sub.1                                                                           m.p. (°C.)                              __________________________________________________________________________     F        CH.sub.2 CN H  CH.sub.3                                                                            O                                                 Cl       CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                           O                                                 CF.sub.3 CH.sub.2 P(O)(OCH.sub.2 CH.sub.3).sub.2                                                    H  OCH.sub.3                                                                           CH.sub.2                                          NO.sub.2 CH.sub.2 CN H  OCH.sub.3                                                                           O                                                 OCH.sub.3                                                                               CH.sub.2 CN H  OCH.sub.3                                                                           O                                                 OCH.sub.3                                                                               CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                           CH.sub.2                                          OCH.sub.2 CH.sub.3                                                                      CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                           O                                                 OCH.sub.2 CH.sub.3                                                                      CH.sub.2 CN H  OCH.sub.3                                                                           CH.sub.2                                          CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN H  OCF.sub.2 H                                                                         O                                                 CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN H  OCH.sub.3                                                                           CH.sub.2                                          CO.sub.2 CH.sub.3                                                                       CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                           O                                                 CO.sub.2 CH.sub.3                                                                       CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                           O                                                 CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                           O                                                 CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 CN H  OCH.sub.3                                                                           CH.sub.3                                          CO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub.2 CN H  CH.sub.3                                                                            O                                                 SO.sub.2 NHCH.sub.3                                                                     CH.sub.2 CN H  OCH.sub.3                                                                           O                                                 SO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub.2 CN H  OCH.sub.3                                                                           CH.sub.2                                          SO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                           O                                                 SO.sub.2 CH.sub.3                                                                       CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                           O                                                 SO.sub.2 CH.sub.3                                                                       CH.sub.2 CN H  OCF.sub.2 H                                                                         CH.sub.2                                          SO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 CN H  OCH.sub.3                                                                           O                                                 SO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                           O                                                 OSO.sub.2 CH.sub.3                                                                      CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                           CH.sub.2                                          OSO.sub.2 CH.sub.3                                                                      CH.sub.2 CN H  OCH.sub.2 C                                                                         O                                                 OSO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                           O                                                 R.sub.1 -A                                                                              CH.sub.2 CN H  CH.sub.3                                                                            O                                                 R.sub.1 -A                                                                              CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                           CH.sub.2                                          R.sub.1 -B                                                                              CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                           O                                                 R.sub.1 -C                                                                              CH.sub.2 CN H  OCH.sub.3                                                                           O                                                 F        CH═NOH  H  CH.sub.3                                                                            O                                                 OCH.sub.3                                                                               CH═NOH.sub.3                                                                           H  OCH.sub.3                                                                           O                                                 COOCH.sub.3                                                                             C(CH.sub.3)═NOH                                                                        H  OCF.sub.2 H                                                                         CH.sub.2                                          CO.sub.2 N(CH.sub.3).sub.2                                                              C(CH.sub.3)═NOCH.sub.3                                                                 H  CH.sub.3                                                                            O                                                 SO.sub.2 N(CH.sub.3).sub.2                                                              CH═NOH  H  OCH.sub.3                                                                           O                                                 SO.sub.2 CH.sub.3                                                                       CH═NOCH.sub.3                                                                          H  OCH.sub.3                                                                           CH.sub.2                                          OSO.sub.2 CH.sub.2 CH.sub.3                                                             C(CH.sub.3)═NOH                                                                        H  OCF.sub.2 H                                                                         O                                                 R.sub.1 -A                                                                              C(CH.sub.3)═NOCH.sub.3                                                                 H  CH.sub.3                                                                            O                                                 R.sub.1 -B                                                                              CH═NOH  H  CH.sub.3                                                                            CH.sub.2                                          R.sub.1 -C                                                                              CH═NOCH.sub.3                                                                          H  OCH.sub.3                                                                           O                                                 F        CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 F        CH.sub.2 CN 6-Cl                                                                              OCH.sub.3                                                                           O                                                 F        CH.sub.2 OSO.sub.2 CH.sub.3                                                                H  OCH.sub.3                                                                           O                                                 CF.sub.3 CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 OCH.sub.3                                                                               CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 OCH.sub.3                                                                               CH.sub.2 CN 6-Cl                                                                              OCH.sub.3                                                                           O                                                 OCH.sub.3                                                                               CH.sub.2 N.sub.3                                                                           6-Cl                                                                              OCH.sub.3                                                                           O                                                 CO.sub.2 CH.sub.3                                                                       CH.sub.2 OSO.sub.2 CH.sub.3                                                                H  OCH.sub.3                                                                           O                                                 CO.sub.2 CH.sub.3                                                                       CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 CO.sub.2 CH.sub.3                                                                       CH.sub.2 O(CO)CH.sub. 3                                                                    H  OCH.sub.3                                                                           CH.sub.2                                          CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub.3                                                                           H  OCH.sub.3                                                                           O                                                 CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 OSO.sub.2 CH.sub.3                                                                H  OCH.sub.3                                                                           O                                                 SO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 R.sub.1 -A                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 R.sub.1 -A                                                                              CH.sub.2 OSO.sub.2 CH.sub.3                                                                H  OCH.sub.3                                                                           O                                                 R.sub.1 -W                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 R.sub.1 -X                                                                              CH.sub.2 N.sub.3                                                                           H  OCH.sub.3                                                                           O                                                 R.sub.1 -X                                                                              CH.sub.2 NO.sub.2                                                                          H  OCH.sub.3                                                                           CH.sub.2                                          R.sub.1 -X                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           CH.sub.2                                          R.sub.1 -Y                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 R.sub.1 -Y                                                                              CH.sub.2 N.sub.3                                                                           H  OCH.sub.3                                                                           O                                                 R.sub.1 -AB                                                                             CH.sub.2 N.sub.3                                                                           H  OCH.sub.3                                                                           CH.sub.2                                          R.sub.1 -AB                                                                             CH.sub.2 N.sub.3                                                                           6-Cl                                                                              OCH.sub.3                                                                           O                                                 R.sub.1 -AC                                                                             CH.sub.2 N.sub.3                                                                           H  OCH.sub.3                                                                           O                                                 R.sub.1 -AC                                                                             CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                           O                                                 F        CH Br       H  OCH.sub.3                                                                           O                                                 NO.sub.2 CH.sub.2 Br H  OCH.sub.3                                                                           O                                                 CH.sub.2 CH.sub.3                                                                       CH.sub.2 Br H  OCH.sub.3                                                                           O                                                 CO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub.2 Br H  OCH.sub.3                                                                           O                                                 SO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub.2 Br H  OCH.sub.3                                                                           O                                                 OCH.sub.3                                                                               CH.sub.2 Br H  OCH.sub.3                                                                           O                                                 CO.sub.2 CH.sub.3                                                                       C(CN)═NOCH.sub.3                                                                       H  OCH.sub.3                                                                           O                                                 NO.sub.2 C(Cl)═NOCH.sub.3                                                                       H  OCH.sub.3                                                                           O                                                 __________________________________________________________________________

                                      TABLE III                                    __________________________________________________________________________     General Formula III                                                            R.sub.1  R.sub.2     R.sub.x                                                                             X.sub.1                                                                              m.p. (°C.)                              __________________________________________________________________________     F        CH.sub.2 CN H    CH.sub.3                                             Cl       CH.sub.2 SCN                                                                               H    OCH.sub.3                                            CF.sub.3 CH.sub.2 P(O)(OCH.sub.2 CH.sub.3).sub.2                                                    H    OCH.sub.3                                            NO.sub.2 CH.sub.2 CN H    OCH.sub.3                                            OCH.sub.3                                                                               CH.sub.2 CN H    OCH.sub.3                                            OCH.sub.3                                                                               CH.sub.2 SCN                                                                               H    OCH.sub.3                                            OCH.sub.2 CH.sub.3                                                                      CH.sub.2 SCN                                                                               H    OCH.sub.3                                            OCH.sub.2 CH.sub.3                                                                      CH.sub.2 CN H    OCH.sub.3                                            CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN H    OCF.sub.2 H                                          CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN H    OCH.sub.3                                            CO.sub.2 CH.sub.3                                                                       CH.sub.2 SCN                                                                               H    OCH.sub.3                                            CO.sub.2 CH.sub.3                                                                       CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H    OCH.sub.3                                            CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H    OCH.sub.3                                            CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 CN H    OCH.sub.3                                            CO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub.2 CN H    CH.sub.3                                             SO.sub.2 NHCH.sub.3                                                                     CH.sub.2 CN H    OCH.sub.3                                            SO.sub. 2 N(CH.sub.3).sub.2                                                             CH.sub.2 CN H    OCH.sub.3                                            SO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub.2 SCN                                                                               H    OCH.sub.3                                            SO.sub.2 CH.sub.3                                                                       CH.sub.2 SCN                                                                               H    OCH.sub.3                                            SO.sub.2 CH.sub.3                                                                       CH.sub.2 CN H    OCF.sub.2 H                                          SO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 CN H    OCH.sub.3                                            SO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H    OCH.sub.3                                            OSO.sub.2 CH.sub.3                                                                      CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H    OCH.sub.3                                            OSO.sub.2 CH.sub.3                                                                      CH.sub.2 CN H    OCH.sub.2 CH.sub.3                                   OSO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 SCN                                                                               H    OCH.sub.3                                            R.sub.1 -A                                                                              CH.sub.2 CN H    CH.sub.3                                             R.sub.1 -A                                                                              CH.sub.2 SCN                                                                               H    OCH.sub.3                                            R.sub.1 -B                                                                              CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H    OCH.sub.3                                            R.sub.1 -C                                                                              CH.sub.2 CN H    OCH.sub.3                                            F        CH═NOH  H    CH.sub.3                                             OCH.sub.3                                                                               CH═NOCH.sub.3                                                                          H    OCH.sub.3                                            COOCH.sub.3                                                                             C(CH.sub.3)═NOH                                                                        H    OCH.sub.3                                            CO.sub.2 N(CH.sub.3).sub.2                                                              C(CH.sub.3)═NOCH.sub.3                                                                 H    OCF.sub.2 H                                          SO.sub.2 N(CH.sub.3).sub.2                                                              CH═NOH  H    CH.sub.3                                             SO.sub.2 CH.sub.3                                                                       CH═NOCH.sub.3                                                                          H    OCH.sub.3                                            OSO.sub.2 CH.sub.2 CH.sub.3                                                             C(CH.sub.3)═NOH                                                                        H    CH.sub.3                                             R.sub.1 -A                                                                              C(CH.sub.3)═NOCH.sub.3                                                                 H    OCH.sub.3                                            R.sub.1 -B                                                                              CH═NOH  H    OCF.sub.2 H                                          R.sub.1 -C                                                                              CH═NOCH.sub.3                                                                          H    OCH.sub.3                                            F        CH.sub.2 CN 6-Cl CH.sub.3                                             F        CH.sub.2 O(CO)CH.sub.3                                                                     H    OCH.sub.3                                            CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub.3                                                                           H    OCH.sub.3                                            CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub.3                                                                           6-Cl OCH.sub.3                                            CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H    OCH.sub.3                                            CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 OSO.sub.2 CH.sub.3                                                                H    OCH.sub.3                                            SO.sub.2 NHCH.sub.3                                                                     CH.sub.2 CN 6-Cl OCH.sub.3                                            SO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H    OCH.sub.3                                            R.sub.1 -A                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H    OCH.sub.3                                            R.sub.1 -A                                                                              CH.sub.2 CN 6-Cl OCH.sub.3                                            R.sub.1 -C                                                                              CH.sub.2 CN 6-OCHF.sub.2                                                                        OCH.sub.3                                            R.sub.1 -X                                                                              CH.sub.2 N.sub.3                                                                           H    OCH.sub.3                                            R.sub.1 -X                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H    OCH.sub.3                                            R.sub.1 -Y                                                                              CH.sub.2 N.sub.3                                                                           H    OCH.sub.3                                            R.sub.1 -Y                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H    OCH.sub.3                                            R.sub.1 -Z                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H    OCH.sub.3                                            R.sub.1 -Z                                                                              CH.sub.2 N.sub.3                                                                           H    OCH.sub.3                                            R.sub.1 -Z                                                                              CH(CH.sub.3)N.sub.3                                                                        H    OCH.sub.3                                            R.sub.1 -AB                                                                             CH.sub.2 N.sub.3                                                                           H    OCH.sub.3                                            R.sub.1 -AC                                                                             CH.sub.2 O(CO)CH.sub.3                                                                     H    OCH.sub.3                                            F        CH.sub.2 ═NOH                                                                          6-Cl OCH.sub.3                                            R.sub.1 -X                                                                              CH═NOH  H    OCH.sub.3                                            F        CH.sub.2 Br H    OCH.sub.3                                            F        CH.sub.2 Cl H    OCH.sub.3                                            F        C(CN)═NOCH.sub.3                                                                       H    OCH.sub.3                                            NO.sub.2 CH.sub.2 Br H    OCH.sub.3                                            OCH.sub.3                                                                               CH.sub.2 Br H    OCH.sub.3                                            CO.sub.2 CH.sub.3                                                                       CH.sub.2 Br H    OCH.sub.3                                            CO.sub.2 CH.sub.3                                                                       CH.sub.2 Cl H    OCH.sub.3                                            CO.sub.2 CH.sub.3                                                                       C(CN)═NOCH.sub.3                                                                       H    OCH.sub.3                                            SO.sub.2 CH.sub.3                                                                       CH.sub.2 Br H    OCH.sub.3                                            SO.sub.2 CH.sub.3                                                                       CH.sub.2 Cl H    OCH.sub.3                                            __________________________________________________________________________

                                      TABLE IV                                     __________________________________________________________________________     General Formula IV                                                             R.sub.1  R.sub.2     R.sub.x                                                                           X.sub.1                                                                              Y.sub.3                                                                           m.p. (°C.)                             __________________________________________________________________________     F        CH.sub.2 CN H  CH.sub.3                                                                             H                                                Cl       CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                            H                                                CF.sub.3 CH.sub.2 P(O)(OCH.sub.2 CH.sub.3).sub.2                                                    H  OCH.sub.3                                                                            CH.sub.3                                         NO.sub.2 CH.sub.2 CN H  OCH.sub.3                                                                            H                                                OCH.sub.3                                                                               CH.sub.2 CN H  OCH.sub.3                                                                            H                                                OCH.sub.3                                                                               CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                            CH.sub.3                                         OCH.sub.2 CH.sub.3                                                                      CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                            H                                                OCH.sub.2 CH.sub.3                                                                      CH.sub.2 CN H  OCH.sub.3                                                                            CH.sub.3                                         CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN H  OCF.sub.2 H                                                                          H                                                CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN H  OCH.sub.3                                                                            CH.sub.3                                         CO.sub.2 CH.sub.3                                                                       CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.3                                                                       CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 CN H  OCH.sub.3                                                                            CH.sub.3                                         CO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub. 2 CN                                                                               H  CH.sub.3                                                                             H                                                SO.sub.2 NHCH.sub.3                                                                     CH.sub.2 CN H  OCH.sub.3                                                                            H                                                SO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub.2 CN H  OCH.sub.3                                                                            H                                                SO.sub.2 N(CH.sub.3).sub.2                                                              CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                            H                                                SO.sub.2 CH.sub.3                                                                       CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                            H                                                SO.sub.2 CH.sub.3                                                                       CH.sub.2 CN H  OCF.sub.2 H                                                                          CH.sub.3                                         SO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 CN H  OCH.sub.3                                                                            H                                                SO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                            H                                                OSO.sub.2 CH.sub.3                                                                      CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                            CH.sub.3                                         OSO.sub.2 CH.sub.3                                                                      CH.sub.2 CN H  OCH.sub.2 CH.sub.3                                                                   H                                                OSO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                            H                                                R.sub.1 -A                                                                              CH.sub.2 CN H  CH.sub.3                                                                             H                                                R.sub.1 -A                                                                              CH.sub.2 SCN                                                                               H  OCH.sub.3                                                                            CH.sub.3                                         R.sub.1 -B                                                                              CH.sub.2 P(O)(OCH.sub.3).sub.2                                                             H  OCH.sub.3                                                                            H                                                R.sub.1 -C                                                                              CH.sub.2 CN H  OCH.sub.3                                                                            H                                                F        CH═NOH  H  CH.sub.3                                                                             H                                                OCH.sub.3                                                                               CH═NOH.sub.3                                                                           H  CH.sub.3                                                                             CH.sub.3                                         COOCH.sub.3                                                                             C(CH.sub.3)═NOH                                                                        H  OCH.sub.3                                                                            H                                                CO.sub.2 N(CH.sub.3).sub.2                                                              C(CH.sub.3)═NOCH.sub.3                                                                 H  OCH.sub.3                                                                            H                                                SO.sub.2 N(CH.sub.3).sub.2                                                              CH═NOH  H  CH.sub.3                                                                             H                                                SO.sub.2 CH.sub.3                                                                       CH═NOCH.sub.3                                                                          H  CH.sub.3                                                                             CH.sub.3                                         OSO.sub.2 CH.sub.2 CH.sub.3                                                             C(CH.sub.3)═NOH                                                                        H  CH.sub.3                                                                             H                                                R.sub.1 -A                                                                              C(CH.sub.3)═NOCH.sub.3                                                                 H  OCH.sub.3                                                                            H                                                R.sub.1 -B                                                                              CH═NOH  H  CH.sub.3                                                                             CH.sub.3                                         R.sub.1 -C                                                                              CH═NOCH.sub.3                                                                          H  OCH.sub.3                                                                            H                                                F        CH.sub.2 CN 6-Cl                                                                              OCH.sub.3                                                                            H                                                F        CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                            H                                                F        CH.sub.2 OSO.sub.2 CH.sub.3                                                                H  OCH.sub.3                                                                            H                                                NO.sub.2 CH.sub.2 CN 6-Cl                                                                              OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.3                                                                       CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 CN 6-Cl                                                                              OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 N.sub.3                                                                           6-F                                                                               OCH.sub.3                                                                            H                                                SO.sub.2 CH.sub.3                                                                       CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                            H                                                SO.sub. 2 CH.sub.2 CH.sub.3                                                             CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                            H                                                SO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 N.sub.3                                                                           6-Cl                                                                              OCH.sub.3                                                                            H                                                R.sub.1 -A                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                            H                                                R.sub.1 -A                                                                              CH.sub.2 CN 6-Cl                                                                              OCH.sub.3                                                                            CH.sub.3                                         R.sub.1 -B                                                                              CH.sub.2 CN 6-Cl                                                                              OCH.sub.3                                                                            H                                                R.sub.1 -X                                                                              CH.sub.2 N.sub.3                                                                           H  OCH.sub.3                                                                            H                                                R.sub.1 -Y                                                                              CH.sub.2 N.sub.3                                                                           H  OCH.sub.3                                                                            H                                                R.sub.1 -Z                                                                              CH.sub.2 O(CO)CH.sub.3                                                                     H  OCH.sub.3                                                                            H                                                R.sub.1 -AC                                                                             CH.sub.2 N.sub.3                                                                           H  OCH.sub.3                                                                            H                                                R.sub.1 -AD                                                                             CH.sub.2 N.sub.3                                                                           H  OCH.sub.3                                                                            H                                                OCH.sub.3                                                                               CH═NOH  6-Cl                                                                              OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.3                                                                       CH═NOH  6-Cl                                                                              OCH.sub.3                                                                            H                                                F        CH.sub.2 Br H  OCH.sub.3                                                                            H                                                F        CH.sub.2 Cl H  OCH.sub.3                                                                            H                                                CF.sub.3 CH.sub.2 Br H  OCH.sub.3                                                                            H                                                CF.sub.3 CH.sub.2 Cl H  OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.3                                                                       CH.sub.2 Br H  OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.3                                                                       CH.sub.2 Cl H  OCH.sub.3                                                                            H                                                CO.sub.2 CH.sub.3                                                                       C(CN)═ NOCH.sub.3                                                                      H  OCH.sub.3                                                                            H                                                SO.sub.2 CH.sub.3                                                                       CH.sub.2 Br H  OCH.sub.3                                                                            H                                                SO.sub.2 CH.sub.3                                                                       CH.sub.2 Cl H  OCH.sub.3                                                                            H                                                R.sub.1 -A                                                                              CH.sub.2 Br H  OCH.sub.3                                                                            H                                                R.sub.1 -B                                                                              CH.sub.2 Cl H  OCH.sub.3                                                                            H                                                OCH.sub.3                                                                               CH.sub.2 Br H  OCH.sub.3                                                                            H                                                NO.sub.2 CH.sub.2 Br H  OCH.sub.3                                                                            H                                                NO.sub.2 C(CN)═NOCH.sub.3                                                                       H  OCH.sub.3                                                                            H                                                __________________________________________________________________________

                                      TABLE V                                      __________________________________________________________________________     General Formula V                                                                                                 m.p.                                        R.sub.1 R.sub.2    R.sub.X                                                                             X.sub.2                                                                             Y.sub.2                                                                              (°C.)                                __________________________________________________________________________     F       CH.sub.2 CN                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         Cl      CH.sub.2 SCN                                                                              H    CH.sub.3                                                                            OCH.sub.2 CH.sub.3                                CF.sub.3                                                                               CH.sub.2 P(O)(OCH.sub.2 CH.sub.3).sub.2                                                   H    CH.sub.3                                                                            OCH.sub.3                                         NO.sub.2                                                                               CH.sub.2 CN                                                                               H    CH.sub.3                                                                            SCH.sub.3                                         OCH.sub.3                                                                              CH.sub.2 CN                                                                               H    CH.sub.2 CH.sub.3                                                                   OCH.sub.3                                         OCH.sub.3                                                                              CH.sub.2 SCN                                                                              H    CH.sub.3                                                                            SCH.sub.2 CH.sub.3                                OCH.sub.2 CH.sub.3                                                                     CH.sub.2 SCN                                                                              H    CH.sub.3                                                                            OCH.sub.3                                         OCH.sub.2 CH.sub.3                                                                     CH.sub.2 CN                                                                               H    CH.sub.2 CF.sub.3                                                                   OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 CN                                                                               H    CH.sub.3                                                                            CH.sub.3                                          CO.sub.2 CH.sub.3                                                                      CH.sub.2 CN                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 SCN                                                                              H    CH.sub.3                                                                            CH.sub.2 CH.sub.3                                 CO.sub.2 CH.sub.3                                                                      CH.sub.2 P(O)(OCH.sub.3).sub.2                                                            H    CH.sub.2 CH.sub.3                                                                   OCH.sub.3                                         CO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 P(O)(OCH.sub.3).sub.2                                                            H    CH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CN                                                                               H    CH.sub.3                                                                            OCH.sub.2 CH.sub.3                                CO.sub.2 N(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                               H    CH.sub.2 CF.sub.3                                                                   OCH.sub.3                                         SO.sub.2 NHCH.sub.3                                                                    CH.sub.2 CN                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 N(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                               H    CH.sub.3                                                                            SCH.sub.3                                         SO.sub.2 N(CH.sub.3).sub.2                                                             CH.sub.2 SCN                                                                              H    CH.sub.2 CH.sub.3                                                                   OCH.sub.3                                         SO.sub.2 CH.sub.3                                                                      CH.sub.2 SCN                                                                              H    CH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 CH.sub.3                                                                      CH.sub.2 CN                                                                               H    CH.sub.3                                                                            SCH.sub.2 CH.sub.3                                SO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CN                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 P(O)(OCH.sub.3).sub.2                                                            H    CH.sub.2 CF.sub.3                                                                   OCH.sub.3                                         OSO.sub.2 CH                                                                           CH.sub.2 P(O)(OCH.sub.3).sub.2                                                            H    CH.sub.3                                                                            CH.sub.3                                          OSO.sub.2 CH.sub.3                                                                     CH.sub.2 CN                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         OSO.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.2 SCN                                                                              H    CH.sub.2 CH.sub.3                                                                   OCH.sub.3                                         R.sub.1 -A                                                                             CH.sub.2 CN                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -A                                                                             CH.sub.2 SCN                                                                              H    CH.sub.3                                                                            CH.sub. 2 CH.sub.3                                R.sub.1 -B                                                                             CH.sub.2 P(O)(OCH.sub.3).sub.2                                                            H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -C                                                                             CH.sub.2 CN                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         F       CH═NOH H    CH.sub.3                                                                            OCH.sub.3                                         OCH.sub.3                                                                              CH═NOHCH.sub.3                                                                        H    CH.sub.3                                                                            CH.sub.3                                          COOCH.sub.3                                                                            C(CH.sub.3)═NOH                                                                       H    CH.sub.2 CH.sub.3                                                                   OCH.sub.3                                         CO.sub.2 N(CH.sub.3).sub.2                                                             C(CH.sub.3)═NOCH.sub.3                                                                H    CH.sub.2 CF.sub.3                                                                   CH.sub.3                                          SO.sub.2 N(CH.sub.3).sub.2                                                             CH═NOH H    CH.sub.3                                                                            OCH.sub.2 CH.sub.3                                SO.sub.2 CH.sub.3                                                                      CH═NOCH.sub.3                                                                         H    CH.sub.3                                                                            OCH.sub.3                                         OSO.sub.2 CH.sub.2 CH.sub.3                                                            C(CH.sub.3)═NOH                                                                       H    CH.sub.2 CF.sub.3                                                                   OCH.sub.3                                         R.sub.1 -A                                                                             C(CH.sub.3)═NOCH.sub.3                                                                H    CH.sub.2 CH.sub.3                                                                   CH.sub.3                                          R.sub.1 -B                                                                             CH═NOH H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -C                                                                             CH═NOCH.sub.3                                                                         H    CH.sub.3                                                                            CH.sub.3                                          F       CH.sub.2 CN                                                                               6-Cl CH.sub.3                                                                            OCH                                               F       CH.sub.2 O(CO)CH.sub.3                                                                    H    CH.sub.3                                                                            OCH.sub.3                                         NO.sub.2                                                                               CH.sub.2 O(CO)CH.sub.3                                                                    H    CH.sub.3                                                                            OCH.sub.3                                         NO.sub.2                                                                               CH.sub.2 N.sub.3                                                                          H    CH.sub.3                                                                            OCH.sub.3                                         OCH.sub.2 CH.sub.3                                                                     CH.sub.2 O(CO)CH.sub.3                                                                    H    CH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 N.sub.3                                                                          H    CH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 CN                                                                               6-Cl CH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 O(CO)CH.sub.3                                                                    H    CH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CN                                                                               6-Cl CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -A                                                                             CH.sub.2 O(CO)CH.sub.3                                                                    H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -B                                                                             CH.sub.2 O(CO)CH.sub.3                                                                    H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -X                                                                             CH.sub.2 N.sub.3                                                                          H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -X                                                                             CH.sub.2 O(CO)CH.sub.3                                                                    H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -AC                                                                            CH.sub.2 O(CO)CH.sub.3                                                                    H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -AC                                                                            CH.sub.2 N.sub.3                                                                          H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -AD                                                                            CH.sub.2 CN                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -AD                                                                            CH.sub.2 N.sub.3                                                                          H    CH.sub.3                                                                            OCH.sub.3                                         F       CH═NOH 6-Cl CH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH═NOH 6-OCF.sub.2 H                                                                       CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -X                                                                             CH═NOH H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -Y                                                                             CH═NOH H    CH.sub.3                                                                            OCH.sub.3                                         F       CH.sub.2 Br                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         CF.sub.3                                                                               CH.sub.2 Br                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         NO.sub.2                                                                               CH.sub.2 Br                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         NO.sub.2                                                                               CH.sub.2 Cl                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 Br                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 Cl                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      C(CN)═NOCH.sub.3                                                                      H    CH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 N(CH.sub.3).sub.2                                                             CH.sub.2 Br                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 N(CH.sub.3).sub.2                                                             CH.sub.2 Cl                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -A                                                                             CH.sub.2 Br                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -A                                                                             CH.sub.2 Cl                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -AD                                                                            CH.sub.2 Br                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -B                                                                             CH.sub.2 Br                                                                               H    CH.sub.3                                                                            OCH.sub.3                                         __________________________________________________________________________

                  TABLE VI                                                         ______________________________________                                         General Formula VII                                                                                                    m.p.                                   R.sub.1   R.sub.2        R.sub.X  X.sub.3                                                                              (°C.)                           ______________________________________                                         F         CH.sub.2 CN    H        OCH.sub.3                                    Cl        CH.sub.2 SCN   H        OCH.sub.3                                    CF.sub.3  CH.sub.2 P(O)(OCH.sub.2 CH.sub.3).sub.2                                                       H        OCH.sub.3                                    NO.sub.2  CH.sub.2 CN    H        CH.sub.3                                     OCH.sub.3 CH.sub.2 CN    H        OCH.sub.3                                    OCH.sub.3 CH.sub.2 SCN   H        CH.sub.3                                     OCH.sub.2 CH.sub.3                                                                       CH.sub.2 SCN   H        OCH.sub.3                                    OCH.sub.2 CH.sub.3                                                                       CH.sub.2 CN    H        CH.sub.3                                     CO.sub.2 CH.sub.3                                                                        CH.sub.2 CN    H        OCH.sub.3                                    CO.sub.2 CH.sub.3                                                                        CH.sub.2 CN    H        CH.sub.3                                     CO.sub.2 CH.sub.3                                                                        CH.sub.2 SCN   H        OCH.sub.3                                    CO.sub.2 CH.sub.3                                                                        CH.sub.2 P(O)(OCH.sub.3).sub.2                                                                H        CH.sub.3                                     CO.sub.2 CH.sub.2 CH.sub.3                                                               CH.sub.2 P(O)(OCH.sub.3).sub.2                                                                H        OCH.sub.3                                    CO.sub.2 CH.sub.2 CH.sub.3                                                               CH.sub.2 CN    H        CH.sub.3                                     CO.sub.2 N(CH.sub.3).sub.2                                                               CH.sub.2 CN    H        OCH.sub.3                                    SO.sub.2 NHCH.sub.3                                                                      CH.sub.2 CN    H        CH.sub.3                                     SO.sub.2 N(CH.sub.3 ).sub.2                                                              CH.sub.2 CN    H        OCH.sub.3                                    SO.sub.2 N(CH.sub.3).sub.2                                                               CH.sub.2 SCN   H        CH.sub.3                                     SO.sub.2 CH.sub.3                                                                        CH.sub.2 SCN   H        OCH.sub.3                                    SO.sub.2 CH.sub.3                                                                        CH.sub.2 CN    H        OCH.sub.3                                    SO.sub.2 CH.sub.2 CH.sub.3                                                               CH.sub.2 CN    H        CH.sub.3                                     SO.sub.2 CH.sub.2 CH.sub.3                                                               CH.sub.2 P(O)(OCH).sub.2                                                                      H        CH.sub.3                                     OSO.sub.2 CH.sub.3                                                                       CH.sub.2 P(O)(OCH.sub.3).sub.2                                                                H        CH.sub.3                                     OSO.sub.2 CH.sub.3                                                                       CH.sub.2 CN    H        OCH.sub.3                                    OSO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 SCN   H        OCH.sub.3                                    R.sub.1 -A                                                                               CH.sub.2 CN    H        CH.sub.3                                     R.sub.1 -A                                                                               CH.sub.2 SCN   H        OCH.sub.3                                    R.sub.1 -B                                                                               CH.sub.2 P(O)(OCH.sub.3).sub.2                                                                H        CH.sub.3                                     R.sub.1 -C                                                                               CH.sub.2 CN    H        OCH.sub.3                                    F         CH═NOH     H        OCH.sub.3                                    OCH.sub.3 CH═NOCH.sub.3                                                                             H        OCH.sub.3                                    COOCH.sub.3                                                                              C(CH.sub.3)═NOH                                                                           H        CH.sub.3                                     CO.sub.2 N(CH.sub.3).sub.2                                                               C(CH.sub.3)═NOCH.sub.3                                                                    H        CH.sub.3                                     SO.sub.2 CH.sub.3                                                                        CH═NOH     H        OCH.sub.3                                    OSO.sub.2 CH.sub.2 CH.sub.3                                                              C(CH.sub.3)═NOCH.sub.3                                                                    H        OCH.sub.3                                    R.sub.1 -A                                                                               C(CH.sub.3)═NOH                                                                           H        OCH.sub.3                                    R.sub.1 -B                                                                               C(CH.sub.3)═NOCH                                                                          H        CH.sub.3                                     R.sub.1 -C                                                                               CH═NOH     H        OCH.sub.3                                    F         CH.sub.2 CN    6-OCF.sub.2 H                                                                           OCH.sub.3                                    F         CH.sub.2 O(CO)CH.sub.3                                                                        H        OCH.sub.3                                    NO.sub.2  CH.sub.2 CN    6-Cl     OCH.sub.3                                    NO.sub.2  CH.sub.2 O(CO)CH.sub.3                                                                        H        OCH.sub.3                                    CO.sub.2 CH.sub.3                                                                        CH.sub.2 O(CO)CH.sub.3                                                                        H        OCH.sub.3                                    CO.sub.2 CH.sub.3                                                                        CH.sub.2 OSO.sub.2 CH.sub.3                                                                   H        OCH.sub.3                                    CO.sub.2 CH.sub.2 CH.sub.3                                                               CH.sub.2 OSO.sub.2 CH.sub.3                                                                   H        OCH.sub.3                                    CO.sub.2 CH.sub.2 CH.sub.3                                                               CH.sub.2 O(CO)CH.sub.3                                                                        H        OCH.sub.3                                    SO.sub.2 CH.sub.2 CH.sub.3                                                               CH.sub.2 O(CO)CH.sub.3                                                                        H        OCH.sub.3                                    SO.sub.2 CH.sub.2 CH.sub.3                                                               CH.sub.2 CN    6-Cl     OCH.sub.3                                    R.sub.1 -A                                                                               CH.sub.2 O(CO)CH.sub.3                                                                        H        OCH.sub.3                                    R.sub.1 -A                                                                               CH.sub.2 OSO.sub.2 CH.sub.3                                                                   H        OCH.sub.3                                    R.sub.1 -A                                                                               CH.sub.2 CN    6-Cl     OCH.sub.3                                    R.sub.1 -X                                                                               CH.sub.2 CN    H        OCH.sub.3                                    R.sub.1 -X                                                                               CH.sub.2 O(CO)CH.sub.3                                                                        H        OCH.sub.3                                    R.sub.1 -Y                                                                               CH.sub.2 CN    H        OCH.sub.3                                    R.sub.1 -Y                                                                               CH.sub. 2 N.sub.3                                                                             H        OCH.sub.3                                    R.sub.1 -AC                                                                              CH.sub.2 N.sub.3                                                                              H        OCH.sub.3                                    R.sub.1 -AC                                                                              CH.sub.2 CN    H        OCH.sub.3                                    F         CH═NOH     6-Cl     OCH.sub.3                                    CO.sub.2 CH.sub.3                                                                        CH═NOCH.sub.3                                                                             6-Cl     OCH.sub.3                                    R.sub.1 -A                                                                               CH═NOH     6-Cl     OCH.sub.3                                    R.sub.1 -X                                                                               CH═NOCH.sub.3                                                                             H        OCH.sub.3                                    R.sub.1 -Y                                                                               CH═NOCH.sub.3                                                                             H        OCH.sub.3                                    F         CH.sub.2 Br    H        OCH.sub.3                                    F         C(Cl)═NOCH.sub.3                                                                          H        OCH.sub.3                                    NO.sub.2  CH.sub.2 Br    H        OCH.sub.3                                    NO.sub.2  CH.sub.2 Cl    H        OCH.sub.3                                    CO.sub.2 CH.sub.3                                                                        CH.sub.2 Br    H        OCH.sub.3                                    CO.sub.2 CH.sub.3                                                                        CH.sub.2 Cl    H        OCH.sub.3                                    CO.sub.2 CH.sub.3                                                                        C(CN)═NOCH.sub.3                                                                          H        OCH.sub.3                                    SO.sub.2 CH.sub.3                                                                        CH.sub.2 Br    H        OCH.sub.3                                    SO.sub.2 CH.sub.3                                                                        C(CN)═NOCH.sub.3                                                                          H        OCH.sub.3                                    SO.sub.2 N(CH.sub.3).sub.2                                                               CH.sub.2 Br    H        OCH.sub.3                                    SO.sub.2 N(CH.sub.3).sub.2                                                               CH.sub.2 Cl    H        OCH.sub.3                                    R.sub.1 -A                                                                               CH.sub.2 (CN)═NOCH.sub.3                                                                  H        OCH.sub.3                                    OCH.sub.3 C(CN)═NOCH.sub.3                                                                          H        OCH.sub.3                                    ______________________________________                                    

                                      TABLE VII                                    __________________________________________________________________________     General Formula VII                                                                                               m.p.                                        R.sub.1 R.sub.2    R.sub.X                                                                            X.sub.4                                                                              Y.sub.4                                                                              (°C.)                                __________________________________________________________________________     F       CH.sub.2 CN                                                                               H   CH.sub.3                                                                             OCH.sub.3                                         Cl      CH.sub.2 SCN                                                                              H   OCH.sub.3                                                                            CH.sub.3                                          CF.sub.3                                                                               CH.sub.2 P(O)(OCH.sub.2 CH.sub.3).sub.2                                                   H   OCH.sub.2 CH.sub.3                                                                   OCH.sub.3                                         NO.sub.2                                                                               CH.sub.2 CN                                                                               H   CH.sub.2 OCH.sub.3                                                                   OCH.sub.3                                         OCH.sub.3                                                                              CH.sub.2 CN                                                                               H   Cl    OCH.sub.3                                         OCH.sub.3                                                                              CH.sub.2 SCN                                                                              H   CH.sub.3                                                                             OCH.sub.2 CH.sub.3                                OCH.sub.2 CH.sub.3                                                                     CH.sub.2 SCN                                                                              H   OCH.sub.3                                                                            OCH.sub.3                                         OCH.sub.2 CH.sub.3                                                                     CH.sub.2 CN                                                                               H   CH.sub.3                                                                             Cl                                                CO.sub.2 CH.sub.3                                                                      CH.sub.2 CN                                                                               H   CH.sub.3                                                                             OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 CN                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 SCN                                                                              H   OCH.sub.3                                                                            CH.sub.3                                          CO.sub.2 CH.sub.3                                                                      CH.sub.2 P(O)(OCH.sub.3).sub.2                                                            H   OCH.sub.2 CH.sub.3                                                                   OCH.sub.3                                         CO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 P(O)(OCH.sub.3).sub.2                                                            H   OCH.sub.3                                                                            OCH.sub.3                                         CO.sub. 2 CH.sub.2 CH.sub.3                                                            CH.sub.2 CN                                                                               H   OCH.sub.3                                                                            OCH.sub.2 CH.sub.3                                CO.sub.2 N(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                               H   CH.sub.2 OCH.sub.3                                                                   OCH.sub.3                                         SO.sub.2 NHCH.sub.3                                                                    CH.sub.2 CN                                                                               H   OCH.sub.3                                                                            CH.sub.3                                          SO.sub.2 N(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 N(CH.sub.3).sub.2                                                             CH.sub.2 SCN                                                                              H   Cl    OCH.sub.3                                         SO.sub.2 CH.sub.3                                                                      CH.sub.2 SCN                                                                              H   OCH.sub.3                                                                            CH.sub.3                                          SO.sub.2 CH.sub.3                                                                      CH.sub.2 CN                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CN                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 P(O)(OCH.sub.3).sub.2                                                            H   CH.sub.3                                                                             OCH.sub.3                                         OSO.sub.2 CH.sub.3                                                                     CH.sub.2 P(O)(OCH.sub.3).sub.2                                                            H   OCH.sub.3                                                                            OCH.sub.2 CH.sub.3                                OSO.sub.2 CH.sub.3                                                                     CH.sub.2 CN                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         OSO.sub.2 CH.sub.2 CH.sub.3                                                            CH.sub.2 SCN                                                                              H   OCH.sub.2 CH.sub.3                                                                   OCH.sub.3                                         R.sub.1 -A                                                                             CH.sub.2 CN                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -A                                                                             CH.sub.2 SCN                                                                              H   OCH.sub.3                                                                            CH.sub.3                                          R.sub.1 -B                                                                             CH.sub.2 P(O)(OCH.sub.3).sub. 2                                                           H   CH.sub.2 OCH.sub.3                                                                   OCH.sub.3                                         R.sub.1 -C                                                                             CH.sub.2 CN                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         F       CH═NOH H   CH.sub.3                                                                             OCH.sub.3                                         OCH.sub.3                                                                              CH═NOCH.sub.3                                                                         H   OCH.sub.3                                                                            CH.sub.3                                          COOCH.sub.3                                                                            C(CH.sub.3)═NOH                                                                       H   OCH.sub.2 CH.sub.3                                                                   OCH.sub.3                                         CO.sub.2 N(CH.sub.3).sub.2                                                             C(CH.sub.3)═NOCH.sub.3                                                                H   CH.sub.2 OCH.sub.3                                                                   OCH.sub.3                                         SO.sub.2 CH.sub.3                                                                      CH═NOH.sub.3                                                                          H   Cl    OCH.sub.3                                         OSO.sub.2 CH.sub.2 CH.sub.3                                                            C(CH.sub.3)═NOCH.sub.3                                                                H   CH.sub.3                                                                             OCH.sub.2 CH.sub.3                                R.sub.1 -A                                                                             C(CH.sub.3)═NOH                                                                       H   OCH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -B                                                                             CH(CH.sub.3)═NOCH.sub.3                                                               H   OCH.sub.3                                                                            Cl                                                R.sub.1 -C                                                                             CH═NOH H   CH.sub.3                                                                             OCH.sub.3                                         F       CH.sub.2 CN                                                                               6-Cl                                                                               CH.sub.3                                                                             OCH.sub.3                                         F       CH.sub.2 O(CO)CH.sub.3                                                                    H   OCH.sub.3                                                                            OCH.sub.3                                         NO.sub.2                                                                               CH.sub.2 O(CO)CH.sub.3                                                                    H   OCH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 O(CO)CH.sub.3                                                                    H   OCH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 O(CO)CH.sub.3                                                                    6-Cl                                                                               CH.sub.3                                                                             OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 OSO.sub.2 CH.sub.3                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 OSO.sub.2 CH.sub.3                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 N.sub.3                                                                          H   OCH.sub.3                                                                            OCH.sub.3                                         CO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 CN                                                                               6-Cl                                                                               OCH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 O(CO)CH.sub.3                                                                    H   CH.sub.3                                                                             OCH.sub.3                                         SO.sub.2 CH.sub.2 CH.sub.3                                                             CH.sub.2 OSO.sub.2 CH.sub.3                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -A                                                                             CH.sub.2 CN                                                                               6-Cl                                                                               OCH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -A                                                                             CH.sub.2 O(CO)CH.sub.3                                                                    H   OCH.sub.3                                                                            CH.sub.3                                          R.sub.1 -B                                                                             CH.sub.2 O(CO)CH.sub.3                                                                    H   OCH.sub.3                                                                            CH.sub.3                                          R.sub.1 -C                                                                             CH.sub.2 N.sub.3                                                                          H   OCH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -X                                                                             CH.sub.2 O(CO)CH.sub.3                                                                    H   OCH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -Y                                                                             CH.sub.2 O(CO)CH.sub.3                                                                    H   OCH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -AC                                                                            CH.sub.2 N.sub.3                                                                          H   OCH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -AD                                                                            CH.sub.2 O(CO)CH.sub.3                                                                    H   OCH.sub.3                                                                            OCH.sub.3                                         R.sub.1 -AD                                                                            CH.sub.2 OSO.sub.2 CH.sub.3                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         F       CH.sub.2 Br                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         F       CH.sub. 2 Cl                                                                              H   CH.sub.3                                                                             OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 Br                                                                               H   CH.sub.3                                                                             OCH.sub.3                                         CO.sub.2 CH.sub.3                                                                      CH.sub.2 Cl                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 CH.sub.3                                                                      CH.sub.2 Br                                                                               H   OCH.sub.3                                                                            OCH.sub.3                                         SO.sub.2 N(CH.sub.3).sub.2                                                             CH.sub.2 Br                                                                               H   CH.sub.3                                                                             OCH.sub.3                                         F       C(CN)═NOCH.sub.3                                                                      H   OCH.sub.3                                                                            OCH.sub.3                                         __________________________________________________________________________

Formulations

Useful formulations of the compounds of Formula I can be prepared in conventional ways. They include dusts, granules, pellets, solutions, suspensions, emulsions, wettable powders, emulsifiable concentrates and the like. Many of these may be applied directly. Sprayable formulations can be extended in suitable media and used at spray volumes of from a few liters to several hundred liters per hectare. High strength compositions are primarily used as intermediates for further formulation. The formulations, broadly, contain about 0.1% to 99% by weight of active ingredient(s) and at least one of (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99.9% solid or liquid inert diluent(s). More specifically, they will contain these ingredients in the following approximate proportions:

    ______________________________________                                                     Weight Percent*                                                                Active                                                                         Ingredient                                                                             Diluent(s)                                                                               Surfactant(s)                                    ______________________________________                                         Wettable Powders                                                                             20-90      0-74     1-10                                         Oil Suspensions,                                                                              3-50     40-95     0-15                                         Emulsions, Solutions,                                                          (including Emulsifiable                                                        Concentrates)                                                                  Aqueous Suspension                                                                           10-50     40-84     1-20                                         Dusts          1-25     70-99     0-5                                          Granules and Pellets                                                                         0.1-95      5-99.9  0-15                                         High Strength 90-99      0-10     0-2                                          Compositions                                                                   ______________________________________                                          *Active ingredient plus at least one of a Surfactant or a Diluent equals       100 weight percent.                                                      

Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are sometimes desirable, and are achieved by incorporation into the formulation or by tank mixing.

Typical solid diluents are described in Watkins, et al., "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books, Caldwell, N.J., but other solids, either mined or manufactured, may be used. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts. Typical liquid diluents and solvents are described in Marsden, "Solvents Guide," 2nd Ed., Interscience, New York, 1950. Solubility under 0.1% is preferred for suspension concentrates: solution concentrates are preferably stable against phase separation at 0° C. "McCutcheon's Detergents and Emulsifiers Annual", MC Publishing Corp., Ridgewood, N.J., as well as Sisely and Wood, "Encyclopedia of Surface Active Agents", Chemical Publishing Co., Inc., New York, 1964, list surfactants and recommended uses. All formulations can contain minor amounts of additives to reduce foaming, caking, corrosion, microbiological growth, etc.

The methods of making such compositions are well known. Solutions are prepared by simply mixing the ingredients. Fine solid compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granular carriers or by agglomeration techniques. See J. E. Browning, "Agglomeration", Chemical Engineering, Dec. 4, 1967, pp. 147ff. and "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York, 1963, pp. 8-57ff.

For further information regarding the art of formulation, see for example:

H. M. Loux, U.S. Pat. No. 3,235,361, Feb. 15, 1966, Col. 6, line 16 through Col. 7, line 19 and Examples 10 through 41;

R. W. Luckenbaugh, U.S. Pat. No. 3,309,192, Mar. 14, 1967, Col. 5, line 43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58, 132, 138-140, 162-164, 166, 167 and 169-182;

H. Gysin and E. Knusli, U.S. Pat. No. 2,891,855, Jun. 23, 1959, Col. 3, line 66 through Col. 5, line 17 and Examples 1-4;

G. C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961, pp. 81-96; and

J. D. Fryer and S. A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pp. 101-103.

In the following examples, all parts are by weight unless otherwise indicated.

EXAMPLE 11 High Strength Concentrate

    ______________________________________                                         2-(cyanomethyl)-6-[[(4,6-dimethoxypyrimidin-2-yl)-                                                          99%                                               aminocarbonyl]aminosulfonyl]benzoic acid, ethyl                                ester                                                                          trimethylnonyl polyethylene glycol ether                                                                     1%                                               ______________________________________                                    

The surfactant is sprayed upon the active ingredient in a blender and the mixture sifted through a U.S. Ser. No. 40 sieve (0.42 mm openings) prior to packaging. The concentrate may be formulated further for practical use.

EXAMPLE 12 Wettable Powder

    ______________________________________                                         2-(acetoxymethyl)-6-[[(4-methoxy-6-methyl-1,3,5-                                                            65%                                               triazin-2-yl)aminocarbonyl]aminosulfonyl]benzoic                               acid, ethyl ester                                                              dodecylphenol polyethylene glycol ether                                                                      2%                                               sodium ligninsulfonate        4%                                               sodium silicoaluminate        6%                                               montmorillonite (calcined)   23%                                               ______________________________________                                    

The ingredients are thoroughly blended. The liquid surfactant is added by spraying upon the solid ingredients in the blender. After grinding in a hammer mill to produce particles essentially all below 100 microns, the material is reblended and sifted through a U.S. Ser. No. 50 sieve (0.3 mm opening) and packaged.

EXAMPLE 13 Aqueous Suspension

    ______________________________________                                         2-(cyanomethyl)-6-[[(4,6-dimethoxypyrimidin-2-yl)-                                                         50.0%                                              aminocarbonyl]aminosulfonyl]benzoic acid, ethyl                                ester                                                                          polyacrylic acid thickener  0.3%                                               dodecylphenol polyethylene glycol ether                                                                    0.5%                                               disodium phosphate          1%                                                 monosodium phosphate        0.5%                                               polyvinyl alcohol           1.0%                                               water                       56.7%                                              ______________________________________                                    

The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size.

EXAMPLE 14 Oil Suspension

    ______________________________________                                         2-(acetoxymethyl)-6-[[(4-methoxy-6-methyl-1,3,5-                                                          35%                                                 triazin-2-yl)aminocarbonyl]aminosulfonyl]benzoic                               acid, ethyl ester                                                              blend of polyalcohol carboxylic esters                                                                     6%                                                 and oil soluble petroleum sulfonates                                           xylene                     59%                                                 ______________________________________                                    

The ingredients are combined and ground together in a sand mill to produce particles essentially all below 3 microns. The product can be used directly, extended with oils, or emulsified in water.

EXAMPLE 15 Oil Suspension

    ______________________________________                                         2-(cyanomethyl)-6-[[(4,6-dimethoxypyrimidin-2-yl)-                                                           25%                                              aminocarbonyl]aminosulfonyl]benzoic acid, ethyl                                ester                                                                          polyoxyethylene sorbitol hexaoleate                                                                           5%                                              highly aliphatic hydrocarbon oil                                                                             70%                                              ______________________________________                                    

The ingredients are ground together in a sand mill until the solid particles have been reduced to under about 5 microns. The resulting thick suspension may be applied directly, but preferably after being extended with oils or emulsified in water.

EXAMPLE 16 Aqueous Suspension

    ______________________________________                                         2-(acetoxymethyl)-6-[[(4-methoxy-6-methyl-1,3,5-                                                            25%                                               triazin-2-yl)aminocarbonyl]aminosulfonyl]benzoic                               acid, ethyl ester                                                              hydrated attapulgite         3%                                                crude calcium ligninsulfonate                                                                               10%                                               sodium dihydrogen phosphate  0.5%                                              water                        61.5%                                             ______________________________________                                    

The ingredients are ground together in a ball or roller mill until the solid particles have been reduced to diameters under 10 microns.

EXAMPLE 17 Wettable Powder

    ______________________________________                                         2-(cyanomethyl)-6-[[(4,6-dimethoxypyrimidin-2-yl)-                                                          40%                                               aminocarbonyl]aminosulfonyl]benzoic acid, ethyl                                ester                                                                          dioctyl sodium sulfonsuccinate                                                                              1.5%                                              sodium ligninsulfonate       3%                                                low viscosity methyl cellulose                                                                              1.5%                                              attapulgite                  54%                                               ______________________________________                                    

The ingredients are thoroughly blended, passed through an air mill, to produce an average particle size under 15 microns, reblended, and sifted through a U.S. Ser. No. 50 sieve (0.3 mm opening) before packaging.

All compounds of the invention may be formulated in the same manner.

EXAMPLE 18 Granule

    ______________________________________                                         wettable powder of Example 17                                                                            15%                                                  gypsum                    69%                                                  potassium sulfate         16%                                                  ______________________________________                                    

The ingredients are blended in a rotating mixer and water sprayed on to accomplish granulation. When most of the material has reached the desired range of 1.0 to 0.42 cm (U.S. Ser. No. 18 to 40 sieves), the granules are removed, dried, and screened. Oversized material is crushed to produce additional material in the desired range. These granules contain % active ingredient.

EXAMPLE 19 Wettable Powder

    ______________________________________                                         2-(acetoxymethyl)-6-[[(4-methoxy-6-methyl-1,3,5-                                                            50%                                               triazin-2-yl)aminocarbonyl]aminosulfonyl]benzoic                               acid, ethyl ester                                                              sodium alkylnaphthalenesulfonate                                                                             2%                                               low viscosity methyl cellulose                                                                               2%                                               diatomaceous earth           46%                                               ______________________________________                                    

The ingredients are blended, coarsely hammer-milled and the air milled to produce particles of active essentially all below 10 microns in diameter. The product is reblended before packaging.

EXAMPLE 20 Extruded Pellet

    ______________________________________                                         2-(cyanomethyl)-6-[[(4,6-dimethoxypyrimidin-2-yl)-                                                          40%                                               aminocarbonyl]aminosulfonyl]benzoic acid, ethyl                                ester                                                                          anhydrous sodium sulfate     10%                                               crude calcium ligninsulfonate                                                                                5%                                               sodium alkylnaphthalenesulfonate                                                                             1%                                               calcium/magnesium bentonite  59%                                               ______________________________________                                    

The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S. Ser. No. 20 sieve (0.84 mm openings). The granules held on a U.S. Ser. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled.

EXAMPLE 21 Wettable Powder

    ______________________________________                                         2-(acetoxymethyl)-6-[[(4-methoxy-6-methyl-1,3,5-                                                            80%                                               triazin-2-yl)aminocarbonyl]aminosulfonyl]benzoic                               acid, ethyl ester                                                              sodium alkylnaphthalenesulfonate                                                                             2%                                               sodium ligninsulfonate        2%                                               synthetic amorphous silica    3%                                               kaolinite                    13%                                               ______________________________________                                    

The ingredients are blended and then ground in a hammer-mill to produce particles with an average particle size less than 25 microns in diameter. The material is reblended and sifted through a U.S. Ser. No. 50 sieve (0.3 mm opening) before being packaged.

EXAMPLE 22 High Strength Concentrate

    ______________________________________                                         2-(cyanomethyl)-6-[[(4,6-dimethoxypyrimidin-2-yl)-                                                          98.5%                                             aminocarbonyl]aminosulfonyl]benzoic acid, ethyl                                ester                                                                          silica aerogel                0.5%                                             synthetic amorphous fine silica                                                                              1.0%                                             ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produce a high strength concentrate essentially all passing a U.S. Ser. No. 50 sieve (0.3 mm openings). This material may then be formulated in a variety of ways.

Utility

Test results indicate that the compounds of the present invention are highly active preemergent or postemergent herbicides or plant growth regulants. Many of them have utility for broad-spectrum pre- and/or post-emergence weed control in areas where complete control of all vegetation is desired, such as around fuel storage tanks, industrial storage areas, parking lots, drive-in theaters, around billboards, highway and railroad structures. Some of the compounds have utility for selective weed control in crops such as wheat barley, corn, soybeans, sugarbeets and cotton. Alternatively, the subject compounds are useful to modify plant growth.

The rates of application for the compounds of the invention are determined by a number of factors, including their use as plant growth modifiers or as herbicides, the crop species involved, the types of weeds to be controlled, weather and climate, formulations selected, mode of application, amount of foliage present, etc. In general terms, the subject compounds should be applied at levels of around 0.010 to 20 kg/ha, the lower rates being suggested for use on lighter soils and/or those having a low organic matter content, for plant growth modification or for situations where only short-term persistence is required such as herbicide for fallow land.

The compounds of the invention may be used in combination with any other commercial herbicide; non-limiting examples of which are those of the sulfonylurea, triazine, triazole, uracil, urea, amide, diphenyl ether, carbamate and imidazolinone, cineole and bipyridylium types.

The herbicidal properties of the subject compounds were discovered in a number of greenhouse tests. The test procedures and results follow.

    __________________________________________________________________________     Compounds                                                                       ##STR68##                                                                     Compound                                                                              R.sub.1  R.sub.2  X     Y    Z                                          __________________________________________________________________________     1      COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 CN                                                                             CH.sub.3                                                                             CH.sub.3                                                                            CH                                         2      COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 CN                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         3      COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 CN                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         4      COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 CN                                                                             Cl    OCH.sub.3                                                                           CH                                         5      COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 CN                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           N                                          6      COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 CN                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          7      COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 SCN                                                                            CH.sub.3                                                                             CH.sub.3                                                                            CH                                         8      COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 SCN                                                                            CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         9      COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 SCN                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         10     COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 SCN                                                                            Cl    OCH.sub.3                                                                           CH                                         11     COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 SCN                                                                            CH.sub.3                                                                             OCH.sub.3                                                                           N                                          12     COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 SCN                                                                            OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          13     COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 OC(O)CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                            CH                                         14     COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 OC(O)CH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         15     COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 OC(O)CH.sub.3                                                                  OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         16     COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 OC(O)CH.sub.3                                                                  Cl    OCH.sub.3                                                                           CH                                         17     COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 OC(O)CH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                                                           N                                          18     COOCH.sub.2 CH.sub.3                                                                    CH.sub.2 OC(O)CH.sub.3                                                                  OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          19     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             CH.sub.3                                                                            CH                                         20     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         21     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 N.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         22     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 N.sub.3                                                                        Cl    OCH.sub.3                                                                           CH                                         23     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3                                                                           N                                          24     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 N.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          25     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 NO.sub.2                                                                       CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         26     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 NO.sub.2                                                                       OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         27     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 NO.sub.2                                                                       Cl    OCH.sub.3                                                                           CH                                         28     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 NO.sub.2                                                                       CH.sub.3                                                                             OCH.sub.3                                                                           N                                          29     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 NO.sub.2                                                                       OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          30     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                             CH.sub.3                                                                             CH.sub.3                                                                            CH                                         31     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         32     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         33     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                             Cl    OCH.sub.3                                                                           CH                                         34     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           N                                          35     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 CN                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          36     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             CH.sub.3                                                                            CH                                         37     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         38     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 N.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         39     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 N.sub.3                                                                        Cl    OCH.sub.3                                                                           CH                                         40     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3                                                                           N                                          41     CO.sub.2 CH(CH.sub.3).sub.2                                                             CH.sub.2 N.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          42     CO.sub.2 CH.sub.3                                                                       CH.sub.2 OC(O)CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                            CH                                         43     CO.sub.2 CH.sub.3                                                                       CH.sub.2 OC(O)CH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         44     CO.sub.2 CH.sub.3                                                                       CH.sub.2 OC(O)CH.sub.3                                                                  OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         45     CO.sub.2 CH.sub.3                                                                       CH.sub.2 OC(O)CH.sub.3                                                                  Cl    OCH.sub.3                                                                           CH                                         46     CO.sub.2 CH.sub.3                                                                       CH.sub.2 OC(O)CH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                                                           N                                          47     CO.sub.2 CH.sub.3                                                                       CH.sub.2 OC(O)CH.sub.3                                                                  OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          48     CO.sub.2 CH.sub.3                                                                       CH.sub.2 OC(O)CH.sub.3                                                                  NHCH.sub.3                                                                           OC.sub.2 H.sub.5                                                                    N                                          49     CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             CH.sub.3                                                                            CH                                         50     CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub. 3                                                                       CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         51     CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         52     CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub.3                                                                        Cl    OCH.sub.3                                                                           CH                                         53     CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3                                                                           N                                          54     CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          55     CO.sub.2 CH.sub.3                                                                       CH.sub.2 N.sub.3                                                                        NHCH.sub.3                                                                           OC.sub.2 H.sub.5                                                                    N                                          56     CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN                                                                             CH.sub.3                                                                             CH.sub.3                                                                            CH                                         57     CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         58     CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         59     CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN                                                                             Cl    OCH.sub.3                                                                           CH                                         60     CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           N                                          61     CO.sub.2 CH.sub.3                                                                       CH.sub.2 CN                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          62     CO.sub.2 CH.sub.3                                                                       CH.sub.2 Br                                                                             CH.sub.3                                                                             CH.sub.3                                                                            CH                                         63     CO.sub.2 CH.sub.3                                                                       CH.sub.2 Br                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         64     CO.sub.2 CH.sub.3                                                                       CH.sub.2 Br                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         65     CO.sub.2 CH.sub.3                                                                       CH.sub.2 Br                                                                             Cl    OCH.sub.3                                                                           CH                                         66     CO.sub.2 CH.sub.3                                                                       CH.sub.2 Br                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           N                                          67     CO.sub.2 CH.sub.3                                                                       CH.sub.2 Br                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          68     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 Br                                                                             CH.sub.3                                                                             CH.sub.3                                                                            CH                                         69     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 Br                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         70     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 Br                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         71     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 Br                                                                             Cl    OCH.sub.3                                                                           CH                                         72     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 Br                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           N                                          73     CO.sub.2 CH.sub.2 CH.sub.3                                                              CH.sub.2 Br                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          74     C(O)N(CH.sub.3).sub.2                                                                   CH.sub.2 Br                                                                             CH.sub.3                                                                             CH.sub.3                                                                            CH                                         75     C(O)N(CH.sub.3).sub.2                                                                   CH.sub.2 Br                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         76     C(O)N(CH.sub.3).sub.2                                                                   CH.sub.2 Br                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         77     C(O)N(CH.sub.3).sub.2                                                                   CH.sub.2 Br                                                                             Cl    OCH.sub.3                                                                           CH                                         78     C(O)N(CH.sub.3).sub.2                                                                   CH.sub.2 Br                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           N                                          79     C(O)N(CH.sub.3).sub.2                                                                   CH.sub.2 Br                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          80     NO.sub.2 CH.sub.2 Br                                                                             CH.sub.3                                                                             CH.sub.3                                                                            CH                                         81     NO.sub.2 CH.sub.2 Br                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         82     NO.sub.2 CH.sub.2 Br                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         83     NO.sub.2 CH.sub.2 Br                                                                             Cl    OCH.sub.3                                                                           CH                                         84     NO.sub.2 CH.sub.2 Br                                                                             CH.sub.3                                                                             OCH.sub.3                                                                           N                                          85     NO.sub.2 CH.sub.2 Br                                                                             OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          86     NO.sub.2 CH.sub.2 OC(O)CH.sub.3                                                                  CH.sub.3                                                                             CH.sub.3                                                                            CH                                         87     NO.sub.2 CH.sub.2 OC(O)CH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         88     NO.sub.2 CH.sub.2 OC(O)CH.sub.3                                                                  OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         89     NO.sub.2 CH.sub.2 OC(O)CH.sub.3                                                                  Cl    OCH.sub.3                                                                           CH                                         90     NO.sub.2 CH.sub.2 OC(O)CH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                                                           N                                          91     NO.sub.2 CH.sub.2 OC(O)CH.sub.3                                                                  OCH.sub.3                                                                            OCH.sub.3                                                                           N                                          92     NO.sub.2 CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             CH.sub.3                                                                            CH                                         93     NO.sub.2 CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3                                                                           CH                                         94     NO.sub.2 CH.sub.2 N.sub.3                                                                        OCH.sub.3                                                                            OCH.sub.3                                                                           CH                                         95     NO.sub.2 CH.sub.2 N.sub.3                                                                        Cl    OCH.sub.3                                                                           CH                                         96     NO.sub.2 CH.sub.2 N.sub.3                                                                        CH.sub.3                                                                             OCH.sub.3                                                                           N                                          97     NO.sub.2 CH.sub.2 N.sub.3                                                                        OCH.sub. 3                                                                           OCH.sub.3                                                                           N                                          __________________________________________________________________________

TEST A

Seeds of crabgrass (Digitaria spp.), barnyard-grass (Echinochloa crusqualli), cheatgrass (Bromus Secalinus), giant foxtail (Setaria faberii), wild oats (Avena fatua), velvetleaf (Abutilon theophrasti), morningglory (Ipomoea spp., cocklebur (Xanthium pensylvanicum), sorghum, corn, barley, soybean, sugar-beet, cotton, rice, wheat and purple nutsedge (Cyperus rotundus) tubers were planted and treated preemergence with the test chemicals dissolved in a non-phytotoxic solvent. At the same time, these crop and weed species were treated with a soil/foliage application. At the time of treatment, the plants ranged in height from 2 to 18 cm. Treated plants and controls were maintained in a greenhouse for sixteen days, after which all species were compared to controls and visually rated for response to treatment. The ratings, summarized in Table A, are based on a numerical scale extending from 0=no injury, to 10=complete kill. The accompanying descriptive symbols have the following meanings:

B=burn;

C=chlorosis/necrosis;

D=defoliation;

E=emergence inhibition;

G=growth retardation;

H=formative effect;

U=unusual pigmentation;

X=axillary stimulation;

S=albinism; and

6Y=abscised buds or flowers.

    __________________________________________________________________________     (TEST A)                                                                       __________________________________________________________________________                  CMPD 1  CMPD 2  CMPD 3  CMPD 4  CMPD 5   CMPD 6                   RATE RATE = KG/HA                                                                           0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01 0.05                                                                               0.01                 __________________________________________________________________________     POSTEMERGENCE                                                                  COTTON       9C  9G  9C  3C,8G                                                                              10C 9C  9C  7H  3C,9G                                                                              3C,8H                                                                               3C,9G                                                                              2C,5G                MORNING GLORY                                                                               3C,9G                                                                              7G  10C 5C,9G                                                                              10C 10C 8G  7G  4C,8H                                                                              6G   3C,8H                                                                              5G                   COCKLEBUR    10C 7G  10C 3C,9H                                                                              10C 10C 10C 10C 10C 4G   4C,8H                                                                              3H                   NUTSEDGE     3C,9G                                                                              2C,8G                                                                              5C,9G                                                                              9G  10C 10C 10C 2C,9G                                                                              3C,8G                                                                              0    3C,8G                                                                              3G                   CRABGRASS    3C,9H                                                                              3C,6G                                                                              5C,9H                                                                              3G  2C,8G                                                                              2C,7G                                                                              7G  0   4C,9G                                                                              2C,9G                                                                               3C,9G                                                                              6G                   BARNYARD GRASS                                                                              9C  9H  10C 9H  10C 9C  10C 9C  10C 6C,9G                                                                               4C,9H                                                                              3C,8G                WILD OATS    3C,7G                                                                              3G  3C,9G                                                                              2G  2C,9G                                                                              3C,6G                                                                              3C,4G                                                                              0   2C,5G                                                                              2C,4G                                                                               2C,6G                                                                              0                    WHEAT        10C 9G  2C,9G                                                                              4C,9G                                                                              2C,9G                                                                              2C,9G                                                                              2C,6G                                                                              3G  2C,9G                                                                              9C   2C,9G                                                                              2G                   CORN         10C 9C  10C 9C  6U,9C                                                                              10C 6U,9C                                                                              4U,9G                                                                              4U,9C                                                                              6U,9C                                                                               9C  3C,8G                SOYBEAN      6C,9G                                                                              4C,9G                                                                              9C  5C,9G                                                                              9C  6C,9G                                                                              2C,7H                                                                              7H  5C,9G                                                                              3C,7H                                                                               5C,9G                                                                              3C,7H                RICE         9C  9C  9C  5C,9G                                                                              9C  9C  4C,9G                                                                              3C,9G                                                                              4C,9G                                                                              4C,9G                                                                               5C,9G                                                                              3C,9G                SORGHUM      9G  3C,9G                                                                              9C  3C,9G                                                                              9C  6C,9G                                                                              4C,9G                                                                              2C,9G                                                                              9C  3C,9G                                                                               6C,9G                                                                              1C,9G                CHEATGRASS   9G  5G  8G  5G  2C,8G                                                                              6G  2C,6G                                                                              2G  2C,7G                                                                              5G   6G  2G                   SUGAR BEETS  10C 9C  10C 9C  10C 10C 10C 6G  9C  2G   2C,4G                                                                              0                    VELVETLEAF   3C,7H                                                                              4G  9C  7G  10C 10C 2C,9G                                                                              7G  6C,9G                                                                              3C,6H                                                                               4C,8H                                                                              2C,6G                GIANT FOXTAIL                                                                               6C,9H                                                                              3C,7G                                                                              9C  5C,9G                                                                              10C 9C  3C,8G                                                                              7G  9C  3C,7G                                                                               3C,9G                                                                              2C,7G                BARLEY       9G  3C,9G                                                                              5C,9G                                                                              2C,9G                                                                              6C,9G                                                                              5C,9G                                                                              6C,9G                                                                              2C,7G                                                                              2C,9G                                                                              2C,6G                                                                               2C,6G                                                                              2C,4G                PREEMERGENCE                                                                   COTTON       2G  0   5G  0   2C,8G                                                                              3G  7H  0   4G  0    0   0                    MORNING GLORY                                                                               0   0   7H  0   9G  2G  7H  5G  2G  0    0   0                    COCKLEBUR    --  0   8H  1C  3C,8G                                                                              3C,7H                                                                              7H  --  --  3G   --  0                    NUTSEDGE     7G  0   9G  0   9G  4G  3C,9G                                                                              0   2G  0    0   0                    CRABGRASS    0   3G  6G  0   2C,5G                                                                              4G  2G  0   2G  2G   0   0                    BARNYARD GRASS                                                                              2G  0   9H  0   2C,9H                                                                              2G  3C,9H                                                                              0   3C,9H                                                                              0    5G  0                    WILD OATS    5G  0   3G  0   2C,7G                                                                              3G  2C,5G                                                                              0   0   0    2G  0                    WHEAT        9G  7G  9H  5G  1C,8G                                                                              2C,7G                                                                              2C,7G                                                                              0   2C,8G                                                                              2G   2C,5G                                                                              0                    CORN         9G  2C,8G                                                                              9H  9H  9H  2C,8H                                                                              9H  7G  3C,9G                                                                              3C,6G                                                                               3C,7G                                                                              3C,5G                SOYBEAN      2C,6G                                                                              3G  9H  3C,5G                                                                              3C,8H                                                                              5G  2C,6H                                                                              2C,6H                                                                              2C,6G                                                                              4G   2C,4G                                                                              4G                   RICE         9H  0   9H  0   2C,9H                                                                              3G  2C,9H                                                                              2C,7G                                                                              3C,9H                                                                              2G   2C,8H                                                                              0                    SORGHUM      9H  3C,5G                                                                              9H  3C,3G                                                                              3C,9H                                                                              2C,7H                                                                              3C,9H                                                                              2C,7H                                                                              3C,8H                                                                              3C,8G                                                                               3C,8H                                                                              3C,7G                CHEATGRASS   7G  0   4G  0   8H  5G  6G  0   4G  0    7G  0                    SUGAR BEETS  8H  2H  8H  3G  2C,9G                                                                              2C,5H                                                                              6G  3G  3H  2H   0   2H                   VELVETLEAF   0   0   2H  5G  5H  2H  3H  0   3H  2G   0   0                    GIANT FOXTAIL                                                                               0   0   7G  0   2C,8H                                                                              5G  7G  0   3G  3G   0   0                    BARLEY       9G  8G  9H  7G  2C,8G                                                                              2C,9G                                                                              9G  7G  9G  8G   8G  2C,7G                __________________________________________________________________________                  CMPD 7  CMPD 8  CMPD 9  CMPD 10 CMPD 11  CMPD 12                  RATE RATE = KG/HA                                                                           0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01 0.05                                                                               0.01                 __________________________________________________________________________     POSTEMERGENCE                                                                  COTTON       1C,7G                                                                              4G  3C,8G                                                                              6G  10C 7G  10C 5G  2C,8G                                                                              6G   7G  6G                   MORNING GLORY                                                                               2C,9G                                                                              7G  10C 3C,9G                                                                              10C 2C,9G                                                                              2C,7G                                                                              4G  9C  3C,8G                                                                               4C,8H                                                                              7G                   COCKLEBUR    10C 7G  3C,9H                                                                              2C,8H                                                                              10C 10C 10C --  10C 10C  3C,9G                                                                              3G                   NUTSEDGE     3C,9G                                                                              2G  9C  2C,6G                                                                              3C,7G                                                                              2C,5G                                                                              7G  0   0   0    2G  0                    CRABGRASS    2C,8G                                                                              0   7G  0   2C,7G                                                                              0   4G  0   2C,8G                                                                              0    0   0                    BARNYARD GRASS                                                                              2C,8H                                                                              2C,6G                                                                              9C  2C,8H                                                                              6C,9G                                                                              2C,8H                                                                              4C,8G                                                                              2C,7H                                                                              3C,9G                                                                              2C,6H                                                                               2C,7H                                                                              2G                   WILD OATS    2C,6G                                                                              0   3C,8G                                                                              0   2C,7G                                                                              0   2C,5G                                                                              0   0   0    0   0                    WHEAT        9C  0   2C,9G                                                                              2C,9G                                                                              2C,9G                                                                              4G  4G  3G  8G  0    0   0                    CORN         3C,8G                                                                              2C,8G                                                                              10C 3U,8G                                                                              3C,8G                                                                              3C,8G                                                                              2C,8G                                                                              2C,7H                                                                              3U,9G                                                                              3C,6H                                                                               2C,8G                                                                              3C,4G                SOYBEAN      3C,7G                                                                              2C,6G                                                                              3C,9G                                                                              2C,7H                                                                              5C,9G                                                                              4C,9G                                                                              3C,7H                                                                              2C,6G                                                                              6C,9G                                                                              5C,9G                                                                               3C,9G                                                                              3C,9H                RICE         6C,9G                                                                              2C,9G                                                                              5C,9G                                                                              3C,8G                                                                              4C,9G                                                                              3C,8G                                                                              2C,9G                                                                              2C,8G                                                                              4C,9G                                                                              3C,8G                                                                               3C,9G                                                                              3G                   SORGHUM      3C,8G                                                                              2C,6G                                                                              2C,9G                                                                              3C,8G                                                                              2C,8H                                                                              2H,4G                                                                              2C,9G                                                                              3G  2C,9G                                                                              2C,6G                                                                               3C,8G                                                                              2G                   CHEATGRASS   9G  0   2C,8G                                                                              2G  2C,7G                                                                              3G  5G  0   4G  0    0   0                    SUGAR BEETS  3C,8G                                                                              4G  3C,9G                                                                              2C,8G                                                                              10C 7G  2C,7G                                                                              2C,7G                                                                              3C,9G                                                                              2C,7G                                                                               2G  0                    VELVETLEAF   3C,9H                                                                              1C,7G                                                                              3C,9G                                                                              3C,9G                                                                              4C,9G                                                                              4C,9G                                                                              4C,9G                                                                              8G  4C,9H                                                                              2C,7H                                                                               4C,9H                                                                              2C,7H                GIANT FOXTAIL                                                                               2C,8G                                                                              0   3C,9G                                                                              7G  6C,9G                                                                              6G  7G  3G  7G  0    4G  2G                   BARLEY       2C,5G                                                                              5G  2C,7G                                                                              5G  3C,9G                                                                              3C,6G                                                                              3C,7G                                                                              2C,5G                                                                              4G  0    3G  4C,5G                PREEMERGENCE                                                                   COTTON       1C,7G                                                                              4G  8G  7G  8G  7G  7G  6G  7G  6G   7G  3G                   MORNING GLORY                                                                               9H  3G  2C,9H                                                                              7G  9G  7G  9G  6G  9G  7G   9G  0                    COCKLEBUR    2C,3H                                                                              0   7H  0   3C,7H                                                                              3G  0   --  --  0    0   0                    NUTSEDGE     3C,9G                                                                              0   9G  0   8G  0   7G  0   0   0    0   0                    CRABGRASS    5G  0   3C,9G                                                                              0   2C,6G                                                                              0   2C  0   3C,5G                                                                              0    2C,7G                                                                              0                    BARNYARD GRASS                                                                              0   0   2C,9H                                                                              0   7H  0   7H  0   2C,9H                                                                              0    0   0                    WILD OATS    2C,7G                                                                              3C,5G                                                                              4C,8G                                                                              3C,5G                                                                              3C,6G                                                                              2C,3G                                                                              3C,6G                                                                              0   2C,5G                                                                              0    0   0                    WHEAT        7H  8G  2C,9G                                                                              7G  7G  2C,5G                                                                              2C,8G                                                                              3G  9G  0    2C,7G                                                                              0                    CORN         7G  2G  1C,8G                                                                              2C,7H                                                                              2C,7G                                                                              2C  7G  0   2C,7G                                                                              2G   2C,7G                                                                              0                    SOYBEAN      2C,7H                                                                              5G  4C,8H                                                                              2C,6H                                                                              4C,8H                                                                              2C,6G                                                                              2C,7G                                                                              2C,6G                                                                              2C,7G                                                                              4G   6G  2G                   RICE         3C,9H                                                                              3C,9H                                                                              4C,9H                                                                              3C,9H                                                                              3C,9H                                                                              2C,7G                                                                              10H 2C,9H                                                                              2C,9H                                                                              3C,9H                                                                               2C,8G                                                                              7G                   SORGHUM      1C,8H                                                                              2C,6H                                                                              2C,8G                                                                              2C,8H                                                                              8G  2C,6G                                                                              2C,8G                                                                              7G  3C,8G                                                                              2C,8G                                                                               3C,8G                                                                              6G                   CHEATGRASS   9G  9G  2C,9H                                                                              8G  8G  7G  8G  4G  3C,9H                                                                              0    2G  0                    SUGAR BEETS  7G  2G  9G  7G  2C,7G                                                                              2C,6H                                                                              3C,9G                                                                              2G  9C  2C,9G                                                                               2G  0                    VELVETLEAF   7H  0   7H  6G  1C,8G                                                                              2G  7G  0   2C,7G                                                                              5H   7G  0                    GIANT FOXTAIL                                                                               2C,7G                                                                              0   3C,9G                                                                              0   9H  2G  2C,6G                                                                              0   2G  0    2G  0                    BARLEY       3G  0   8G  5G  4G  2G  5G  0   8G  5G   7G  0                    __________________________________________________________________________                  CMPD 13 CMPD 14 CMPD 15 CMPD 16 CMPD 17  CMPD 18                  RATE RATE = KG/HA                                                                           0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01 0.05                                                                               0.01                 __________________________________________________________________________     POSTEMERGENCE                                                                  COTTON       10C 3C,8G                                                                              10C 10C 9C  10C 9C  4C,9H                                                                              9C  4C,9H                                                                               4C,9G                                                                              5C,9G                MORNING GLORY                                                                               10C 10C 10C 9C  10C 10C 10C 9C  9C  5C,9G                                                                               6C,9G                                                                              5C,9G                COCKLEBUR    10C 10C 10C 10C 9C  10C 10C 10C 10C 10C  10C 10C                  NUTSEDGE     10C 8C  9C  5C,9G                                                                              10C 9C  10C 9C  5C,9G                                                                              5G   9C  7G                   CRABGRASS    10C 6C,9G                                                                              9C  3C,7G                                                                              10C 5G  3C,8G                                                                              4G  10C 5C,9G                                                                               5C,9G                                                                              4C,8G                BARNYARD GRASS                                                                              9C  9C  9C  9C  9C  9C  10C 9C  9C  9C   10C 4C,9H                WILD OATS    9C  2C,7G                                                                              5C,9G                                                                              4C,9G                                                                              5C,9G                                                                              4C,9G                                                                              3C,5G                                                                              2G  5C,9G                                                                              2G   3C,9G                                                                              3C                   WHEAT        10C 10C 10C 9C  5C,9G                                                                              3C,9G                                                                              4C,9G                                                                              2G  10C 5C,9G                                                                               9G  9C                   CORN         10C 10C 9C  10C 10C 9C  6C,9G                                                                              5C,9G                                                                              10C 10C  9C  5C,9G                SOYBEAN      4C,9G                                                                              3C,8H                                                                              5C,9G                                                                              5C,9G                                                                              9C  9C  5C,9G                                                                              8G  9C  5C,9G                                                                               4C,9G                                                                              5C,9G                RICE         9C  6C,9G                                                                              9C  9C  9C  9C  9C  5C,9G                                                                              9C  9C   9C  6C,9G                SORGHUM      6C,9G                                                                              5C,9G                                                                              9C  5C,9G                                                                              9C  5C,9G                                                                              9C  3C,9G                                                                              10C 9C   5C,9G                                                                              3C,9G                CHEATGRASS   9C  2C,7G                                                                              9C  5C,9G                                                                              9C  9C  3C,7G                                                                              3C,5G                                                                              5C,9G                                                                              6G   6G  3G                   SUGAR BEETS  10C 10C 10C 10C 10C 10C 10C 5C,9G                                                                              10C 10C  10C 2G                   VELVETLEAF   10C 4C,8H                                                                              9C  10C 10C 10C 9C  6C,9G                                                                              10C 9C   9C  4C,8G                GIANT FOXTAIL                                                                               10C 4C,9G                                                                              10C 9C  10C 10C 10C 4C,8H                                                                              10C 5C,9G                                                                               9C  4C,9G                BARLEY       3C,9G                                                                              2C,6G                                                                              5C,9G                                                                              5G  9C  6C,9G                                                                              9G  2G  3C,8G                                                                              6G   5G  0                    PREEMERGENCE                                                                   COTTON       2C,8G                                                                              7G  2C,9G                                                                              8G  9G  8G  9G  7G  9G  7G   8G  5G                   MORNING GLORY                                                                               9H  8G  9G  6G  9H  7G  9G  9G  9G  9G   9G  8G                   COCKLEBUR    2C,8H                                                                              2G  9H  7G  9G  3G  8H  0   9G  --   2G  2G                   NUTSEDGE     10E 5G  10E 9G  9G  9G  10C 3G  4C,8G                                                                              0    9G  0                    CRABGRASS    3C,8G                                                                              3C,9G                                                                              4C,9G                                                                              3C,9G                                                                              7G  5G  3C,7G                                                                              2G  4C,9G                                                                              5C,9G                                                                               4C,8G                                                                              2C                   BARNYARD GRASS                                                                              2C,9H                                                                              3C,8H                                                                              4C,9H                                                                              8H  9H  5H  9H  9H  9H  5C,9H                                                                               9H  4H                   WILD OATS    3C,8G                                                                              3C,7G                                                                              5C,8G                                                                              3C,9G                                                                              3C,8G                                                                              8G  3C,7G                                                                              3C,4G                                                                              4C,9G                                                                              3C,7G                                                                               4C,9H                                                                              3C,6G                WHEAT        2C,9G                                                                              2C,8G                                                                              4C,9G                                                                              9G  9H  8G  9G  7G  4C,9H                                                                              3C,9H                                                                               3C,8H                                                                              3G                   CORN         3C,9G                                                                              4C,8H                                                                              5C,9G                                                                              9G  4C,9H                                                                              8H  3C,9G                                                                              3C,7H                                                                              4U,9G                                                                              3C,9G                                                                               3C,9G                                                                              4G                   SOYBEAN      2C,8H                                                                              2C,7G                                                                              4C,9H                                                                              3C,7G                                                                              9H  3C,7H                                                                              3C,8G                                                                              2C,3G                                                                              4C,9H                                                                              5G   3C,7H                                                                              3G                   RICE         10E 2C,9H                                                                              5C,9H                                                                              3C,9H                                                                              9H  9H  10E 9H  10E 10E  10E 9H                   SORGHUM      10H 3C,9H                                                                              4C,9H                                                                              2C,9H                                                                              4C,9H                                                                              9H  6C,9H                                                                              9H  10H 5C,9H                                                                               9H  9H                   CHEATGRASS   2C,9h                                                                              2C,9H                                                                              9H  3C,9G                                                                              3C,9G                                                                              8G  9G  5G  4C,9H                                                                              9H   7G  3G                   SUGAR BEETS  2C,9G                                                                              2C,5G                                                                              9C  9G  9C  3C,9H                                                                              9C  9G  9C  9C   7G  0                    VELVETLEAF   3C,9H                                                                              6H  3C,9G                                                                              7G  5C,9G                                                                              3G  4C,9G                                                                              7G  4C,9G                                                                              4H   4C,8G                                                                              3H                   GIANT FOXTAIL                                                                               2C,9H                                                                              3G  4C,9H                                                                              3C,9G                                                                              3C,9H                                                                              8H  9H  2H  9H  3H   9H  2C,5G                BARLEY       8G  9G  3C,9G                                                                              7G  8G  7G  8G  4G  9H  9G   9H  5G                   __________________________________________________________________________                  CMPD 19 CMPD 20 CMPD 21 CMPD 22 CMPD 23  CMPD 24                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05  0.01                                                                              0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       3C,8G                                                                              3C,9G                                                                              4C,9G                                                                              10C 3C,9G                                                                              9C  4C,8G                                                                              9C  4C,9H                                                                              3C,9G                                                                               4C,8H                                                                              4C,9H                MORNING GLORY                                                                               3C,8H                                                                              3C,8H                                                                              10C 10C 10C 10C 3C,8H                                                                              5C,9G                                                                              5C,9G                                                                              10C  5C,9G                                                                              10C                  COCKLEBUR    10C 10C 10C 10C 10C 10C     10C 10C 10C  10C 10C                  NUTSEDGE     2C,7G                                                                              2C,7G                                                                              4C,9G                                                                              9C  3C,8G                                                                              10C 2C,8G                                                                              5C,9G                                                                              9G  9C   8G  5C,9G                CRABGRASS    5G  3C,8G                                                                              5G  2C,8G                                                                              7G  4C,9G                                                                              2G  2C,4G                                                                              3C,7G                                                                              9C   2C,5G                                                                              6C,9G                BARNYARD GRASS                                                                              4C,9H                                                                              9C  9C  9C  9C  10C 4C,9H                                                                              9C  9C  9C   3C,9H                                                                              9C                   WILD OATS    4G  9G  2C,6G                                                                              3C,9G                                                                              2C,5G                                                                              4C,9G                                                                              0   2G  2G  3C,8G                                                                               0   2C,5G                WHEAT        8G  9G  4C,9G                                                                              4C,9G                                                                              8G  4C,9G                                                                              0   5G  8G  5C,9G                                                                               0   7G                   CORN         9C  9C  9C  10C 10C 10C 9C  5C,9G                                                                              10C 10C  10C 5C,9G                SOYBEAN      4C,8H                                                                              5C,9G                                                                              4C,9G                                                                              9C  9C  9C  2C,4H                                                                              4C,9G                                                                              4C,9G                                                                              9C   4C,9G                                                                              5C,9G                RICE         4C,9G                                                                              9C  9C  9C  9C  9C  4C,9G                                                                              5C,9G                                                                              9C  9C   9C  9C                   SORGHUM      9G  3C,9G                                                                              9C  9C  9C  10C 3C,9G                                                                              3C,9G                                                                              9C  9C   3C,9H                                                                              9C                   CHEATGRASS   7G  5C,9G                                                                              3C,8G                                                                              9C  3C,9G                                                                              9C  4G  3C,8G                                                                              3C,6G                                                                              5C,9G                                                                               0   3C,5G                SUGAR BEETS  9C  9C  5C,9G                                                                              10C 5C,9G                                                                              10C 2C,5G                                                                              10C 9C  10C  9C  9C                   VELVETLEAF   3C,8G                                                                              9C  9C  10C 9C  10C 4C,8G                                                                              10C 9C  10C  3C,7H                                                                              9C                   GIANT FOXTAIL                                                                               9G  5C,9G                                                                              5C,9G                                                                              9C  9C  10C 3C,6G                                                                              5C,9G                                                                              9C  10C  3C,8G                                                                              9C                   BARLEY       8G  9G  2C,9G                                                                              5C,9G                                                                              5C,9G                                                                              9C  2C,2G                                                                              8G  2G  2C,8G                                                                               0   2C,6G                PRSOL                                                                          COTTON       4G  8G  0   7G  5G  6G  2G  6G  1C  8G       2G                   MORNING GLORY                                                                               0   0   2G  3G  0   5G  0   5G  2C  9H   0   8H                   COCKLEBUR    0           8H  3G  9H  2H  6H  2G  9H   0   9H                   NUTSEDGE     0   8G  0   10E 2G  9G  0   8G  2G  9G   0   10E                  CRABGRASS    2G  9H  0   3C,6G                                                                              2G  2C,5G                                                                              2G  2G  2G  3C,6G                                                                               0   3C,8G                BARNYARD GRASS                                                                              3G  4C,9H                                                                              5G  3C,9H                                                                              2C,8H                                                                              9H  7G  9H  3C,8H                                                                              9H   0   3C,8H                WILD OATS    0   0   2G  3C,6G                                                                              2G  2C,2G                                                                              0   4G  1C  3G   0   0                    WHEAT        3G  5G  2G  8G  2G  3G  0   0   4G  9H   0   2G                   CORN         0   9G  2C,5G                                                                              3C,9G                                                                              2C,3G                                                                              3C,8H                                                                              3C,5G                                                                              3C,9H                                                                              4C,8H                                                                              3C,9H                                                                               2C,5G                                                                              4C,8G                SOYBEAN      0   0   2G  3C,7H                                                                              0   3G  0   2C,2G                                                                              3C,3H                                                                              4C,7G                                                                               2H  3C,6G                RICE         2C,8H                                                                              3C,9H                                                                              3G  3C,9H                                                                              2G  9H  4G  8G  3C,5G                                                                              9G   3C,6G                                                                              9H                   SORGHUM      2C,7H                                                                              3C,9H                                                                              3C,9H                                                                              3C,9H                                                                              9G  9H  8G  9G  2C,9G                                                                              5C,9G                                                                               2C,8G                                                                              4C,9H                CHEATGRASS   3G  3C,7G                                                                              4G  8G  5G  9G  0   7G  0   8G   0   5G                   SUGAR BEETS  8G  4G  5H  4C,8G                                                                              4G  6G  0   5G  5H  4C,9G                                                                               3C,5H                                                                              4C,9G                VELVETLEAF   0   0   2G  3C,8G                                                                              2G  8G  2H  4G  0   6H   0   1H                   GIANT FOXTAIL                                                                               3G  7G  5G  4C,9H                                                                              2C,7G                                                                              9H  5G  7G  2C,5G                                                                              9H   0   3C,8H                BARLEY       0   6G  4G  8G  2G  3C,8G                                                                              2G  6G  3C,8G                                                                              8G   0   2D,8G                __________________________________________________________________________                  CMPD 25 CMPD 26 CMPD 27 CMPD 28 CMPD 29  CMPD 30                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       5G  3C,9G                                                                              7G  5C,9G                                                                              3G  9H  2G  4C,9G                                                                              0   2C,8G                                                                               0   0                    MORNING GLORY                                                                               9C  10C 10C 10C 2C,5H                                                                              9C  4C,8G                                                                              5C,9G                                                                              4C,9G                                                                              9C   2H  4H                   COCKLEBUR    4C,9G                                                                              10C 10C 10C 3C,8G                                                                              10C 10C 10C 4C,9H                                                                              10C  2C  3C,8H                NUTSEDGE     3C,8G                                                                              5C,9G                                                                              10C 9C  5C,9G                                                                              5C,9G                                                                              3C,7G                                                                              4C,8G                                                                              3C,5G                                                                              4C,8G                                                                               5G  3C,9G                CRABGRASS    2C,5G                                                                              6C,9G                                                                              3C,6G                                                                              5C,9G                                                                              0   2C,8G                                                                              7G  5C,9G                                                                              7G  5C,9G                                                                               0   0                    BARNYARD GRASS                                                                              3C,9H                                                                              9C  9C  9C  5C,9H                                                                              9C  9C  9C  3C,7H                                                                              5C,9H                                                                               8H  3C,9H                WILD OATS    5G  4C,8G                                                                              2C,4G                                                                              4C,8G                                                                              0   2G  0   3G  0   0    0   1C                   WHEAT        9G  4C,9G                                                                              3C,8G                                                                              2C,9G                                                                              3G  2G  9G  9C  0   5G   0   2G                   CORN         9C  10C 10C 10C 3C,9G                                                                              5U,9G                                                                              9C  10C 3C,9G                                                                              10C  3C,9G                                                                              9C                   SOYBEAN      9C  5C,9G                                                                              4C,9G                                                                              9C  2C,5H                                                                              3C,8G                                                                              4C,9G                                                                              5C,9G                                                                              3C,8H                                                                              4C,9G                                                                               3C,7H                                                                              2C,7G                RICE         9C  9C  9C  9C  4C,9G                                                                              5C,9G                                                                              5C,9G                                                                              9C  3C,9G                                                                              5C,9G                                                                               8G  2C,9G                SORGHUM      4C,9G                                                                              10C 5C,9G                                                                              10C 3C,9G                                                                              9C  5C,9G                                                                              10C 5C,9H                                                                              4C,9G                                                                               1C,4G                                                                              2C,5G                CHEATGRASS   6G  6C,9G                                                                              3C,6G                                                                              9C  2G  7G  3G  6G  0   2G   0   3G                   SUGAR BEETS  4C,8G                                                                              9C  9C  10C 3G  9C  6C,9G                                                                              9C  3C,5G                                                                              5C,9G                                                                               1C,2G                                                                              3C,8G                VELVETLEAF   8G  9C  10C 10C 7G  4C,9G                                                                              3C,8H                                                                              5C,9G                                                                              3C,4H                                                                              4C,9G                                                                               0   1C,4G                GIANT FOXTAIL                                                                               4C,9G                                                                              9C  9C  10C 3C,5G                                                                              4C,9G                                                                              3C,8G                                                                              9C  3C,7G                                                                              5C,9H                                                                               4G  7G                   BARLEY       2C,5G                                                                              4C,9G                                                                              3C,7H                                                                              5C,9G                                                                              0   6G  2G  5G  0   2G   3G  8G                   PRSOL                                                                          COTTON       4G  8G  5G  7G  5G  8G  0   8G  0   5G   0   0                    MORNING GLORY                                                                               7G  9G  8G  9G  7G  9G  0   9G  0   8H   0   0                    COCKLEBUR    0   3C,3H                                                                              0   8G  5G  4H  8H      0   5H   0   0                    NUTSEDGE     0   9G  7G  10E 0   9G  0   10E 0   0    0   8G                   CRABGRASS    5G  3C,7G                                                                              2G  3C,9G                                                                              0   5G  0   3C,8G                                                                              0   2G   0   10E                  BARNYARD GRASS                                                                              4G  9H  0   9H  5G  9H  0   3C,9H                                                                              0   3G   0   3G                   WILD OATS    2G  3C,6G                                                                              2G  3C,5G                                                                              0   4G  0   2C,4G                                                                              0   3G   0   0                    WHEAT        2G  8G  2G  7G  0   5G  0   3C,9H                                                                              0   0    0   0                    CORN         2C,8H                                                                              3C,9H                                                                              0   8G  3C,5H                                                                              3C,9G                                                                              3C,5H                                                                              3C,9G                                                                              0   3C,3G                                                                               2C,3G                                                                              2C,7G                SOYBEAN      2C,2H                                                                              3C,7H                                                                              2H  3C,7G                                                                              2C  2C,3H                                                                              1C,1H                                                                              3C,8G                                                                              0   3C,5G                                                                               0   2C,7H                RICE         9C  10H 3C,5G                                                                              3C,9G                                                                              9H  9H  3C,9G                                                                              10H 6G  9H   0   6G                   SORGHUM      3C,9H                                                                              5C,9H                                                                              3C,7G                                                                              3C,9G                                                                              9G  9H  4C,9G                                                                              4C,9H                                                                              2G  9H   0   6G                   CHEATGRASS   2G  4C,9G                                                                              5G  3C,9G                                                                              0   4G  0   3C,9H                                                                              0   3G   0   2G                   SUGAR BEETS  2H  3G  5G  8G  4G  8G  7G  4C,9G                                                                              2G  8G   0   6G                   VELVETLEAF   2G  8H  5G  8G  3G  4C,9H                                                                              1H  2C,8G                                                                              0   2H   0   2G                   GIANT FOXTAIL                                                                               3G  9H  2H  9H  0   8G  0   3C,7G                                                                              0   2G   0   9G                   BARLEY       2C,7G                                                                              3C,9G                                                                              0   8G  2C  2C,9G                                                                              4G  3C,8G                                                                              0   2C,6G                                                                               0   7G                   __________________________________________________________________________                  CMPD 31 CMPD 32 CMPD 33 CMPD 34 CMPD 35  CMPD 36                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       1C,5G                                                                              4C,8G                                                                              2C,8H                                                                              3C,9G                                                                              0   3C,8G                                                                              0   2C,9H                                                                              0   3C,8H                                                                               3C,8G                                                                              3C,8G                MORNING GLORY                                                                               1C,5H                                                                              3C,9H                                                                              5G  3C,8G                                                                              0   1C,2G                                                                              1C  3C,8H                                                                              2C  3C,7H                                                                               2C,8G                                                                              3C,8H                COCKLEBUR    4C,9H                                                                              4C,9H                                                                              10C 9C  3C,9H                                                                              9C  2C,3G                                                                              4C,9H                                                                              1C  4C,9H                                                                               3C,8H                                                                              4C,9H                NUTSEDGE     8G  8G  6G  8G  3G  3C,9G                                                                              0   3C,8G                                                                              0   4G   5G  3C,9G                CRABGRASS    0   3G  2G  6G  0   2G  2G  5G  0   3G   0   2G                   BARNYARDGRASS                                                                               8H  2C,9H                                                                              9H  4C,9G                                                                              6G  2C,9H                                                                              3C,8H                                                                              5C,9H                                                                              0   3C,8H                                                                               8H  9G                   WILD OATS    0   0   0   5G  0   0   0   0   0   0    5G  2C,9G                WHEAT        0   4G  0   5G  0   0   0   0   0   0    5G  9G                   CORN         9C  6U,9C                                                                              4C,9G                                                                              5C,9G                                                                              9G  3C,9G                                                                              2C,8H                                                                              6U,9C                                                                              9G  3C,9G                                                                               4C,9G                                                                              4C,9G                SOYBEAN      3C,8H                                                                              4C,9H                                                                              3C,9H                                                                              3C,9H                                                                              1H  4H  2C,8G                                                                              2C,9G                                                                              2C,6H                                                                              3C,8G                                                                               3C,9G                                                                              3C,8G                RICE         7G  2C,9G                                                                              9G  9G  5G  9G  0   3C,9G                                                                              3G  2C,7G                                                                               9G  9C                   SORGHUM      1C,5G                                                                              3C,8H                                                                              6G  2C,8H                                                                              4G  7G  2G  6G  3G  3C,9H                                                                               2C,7H                                                                              2C,9G                CHEATGRASS   6G  6G  5G  6G  3G  5G  0   3G  0   5G   6G  9G                   SUGAR BEETS  2C,6G                                                                              4C,9G                                                                              3C,7H                                                                              3C,8G                                                                              0   10C 2C,7H                                                                              9G  2C,5G                                                                              3C,8H                                                                               2C,6G                                                                              3C,8G                VELVETLEAF   2C,7G                                                                              3C,8G                                                                              9G  10C 0   8G  4G  4C,9H                                                                              1C,4G                                                                              7G   3C,8H                                                                              4C,9H                GIANT FOXTAIL                                                                               6G  8G  7G  4C,9G                                                                              2G  7G  7G  2C,9G                                                                              6G  8G   5G  8G                   BARLEY       3G  9G  9G  9G  3G  7G  0   0   0   0    5G  9G                   PRSOL                                                                          COTTON       0   0   2G  2G  0   0   0   2G  0   2G   0   0                    MORNING GLORY                                                                               0   3C  0   1C  0   2G  0   2G  0   0    2G  3G                   COCKLEBUR        2C  2C  8H  3G  3C,6H                                                                              0   2C  0   0    6H  7G                   NUTSEDGE     2G  0   0   9G  0   6G  0   2G  0   0    0   8G                   CRABGRASS    0   10E 3G  4G  0   0   2G  4G  0   0    0   2G                   BARNYARD GRASS                                                                              6G  8H  6G  8H  5G  5G  4G  5G  0   4G   4G  6H                   WILD OATS    0   2G  0   0   0   0   0   0   0   0    2G  6G                   WHEAT        0   2G  0   2G  0   0   0   0   0   0    0   6G                   CORN         2C,4G                                                                              3C,7G                                                                              0   1C,3G                                                                              2C,3G                                                                              2C,7G                                                                              2C,5G                                                                              2C,8G                                                                              0   8G   2C  8G                   SOYBEAN      1C  2C,3G                                                                              0   1C,2G                                                                              0   0   3G  2C,4G                                                                              0   0    4G  2C,4G                RICE         0   4G  0   3G  0   2G  0   0   0   2C,6G                                                                               2G  8H                   SORGHUM      1C,4G                                                                              2C,7G                                                                              1C,6G                                                                              2C,7H                                                                              5G  2C,6H                                                                              2G  3C,9H                                                                              0   3C,9H                                                                               6G  9G                   CHEATGRASS   2G  0   2G  5G  0   0   2G  0   0   0    3G  7G                   SUGAR BEETS  7G  2C,8G                                                                              7G  2C,6G                                                                              0   3G  3G  2C,4G                                                                              0   6G   6G  6G                   VELVETLEAF   0   2C,6G                                                                              0   3G  2G  3G  0   2C,4G                                                                              0   0    0   6G                   GIANT FOXTAIL                                                                               3G  9H  4G  4G  3G  4G  3G  4G  0   0    3G  5G                   BARLEY       5G  6G  4G  7G  6G  7G  3G  7G  0   7G   2G  7G                   __________________________________________________________________________                  CMPD 37 CMPD 38 CMPD 39 CMPD 40 CMPD 41  CMPD 42                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       5C,9G                                                                              9C  9C  9C  7G  4C,9G                                                                              3C,9G                                                                              10C 2C,8G                                                                              2C,9H                                                                               4C,9G                                                                              10C                  MORNING GLORY                                                                               3C,8H                                                                              10C 10C 10C 2C,8G                                                                              10C 3C,9G                                                                              10C 3C,8G                                                                              10C  10C 10C                  COCKLEBUR    3C,9G                                                                              10C 10C 10C 8H  10C 10C 10C 9C  10C  10C 10C                  NUTSEDGE     2C,8G                                                                              9G  8G  2C,9G                                                                              3G  2C,8G                                                                              8G  8G  3C,7G                                                                              2C,8G                                                                               9C  10C                  CRABGRASS    0   2G  2G  5G  0   2G  0   4G  0   5G   4C,9G                                                                              9C                   BARNYARD GRASS                                                                              3C,9H                                                                              9C  2C,9H                                                                              9C  2C,5H                                                                              3C,9H                                                                              3C,7H                                                                              9C  3H  3C,7H                                                                               6C,9G                                                                              9C                   WILD OATS    3G  2C,8G                                                                              2G  2C,8G                                                                              0   2G  0   6G  0   2G   9G  3C,9G                WHEAT        3G  9G  5G  9G  0   0   2G  5G  0   0    3C,9G                                                                              4C,9G                CORN         9C  10C 5C,9G                                                                              10C 9G  9C  3C,9G                                                                              9C  8H  5C,9G                                                                               9C  6U,9C                SOYBEAN      4C,9G                                                                              3C,9G                                                                              4C,9G                                                                              5C,9G                                                                              2H  2C,7G                                                                              3C,9G                                                                              5C,9G                                                                              4C,9G                                                                              9C   5C,9G                                                                              9C                   RICE         3C,9G                                                                              9C  4C,9G                                                                              9C  3C,9G                                                                              5C,9G                                                                              7G  5C,9G                                                                              2C,5G                                                                              5C,9G                                                                               9C  9C                   SORGHUM      2C,7G                                                                              3C,9G                                                                              2C,9H                                                                              3C,9G                                                                              3G  2C,9G                                                                              2C,9G                                                                              3C,9G                                                                              3C,9H                                                                              2C,9G                                                                               3C,9G                                                                              10C                  CHEATGRASS   7G  2C,8G                                                                              7G  4C,9G                                                                              0   5G  0   3G  0   3G   9G  9C                   SUGAR BEETS  3C,8G                                                                              5C,9G                                                                              4C,9G                                                                              5C,9G                                                                              1H  2C,5G                                                                              9C  9C  5C,9H                                                                              10C  5C,9G                                                                              5C,9H                VELVETLEAF   3C,8G                                                                              9C  9C  10C 7G  2C,9G                                                                              9C  10C 2G  6H   10C 10C                  GIANT FOXTAIL                                                                               5G  8G  6G  4C,9G                                                                              2G  4G  3G  6G  2G  3C,7G                                                                               4C,9G                                                                              10C                  BARLEY       3G  2C,9G                                                                              7G  2C,9G                                                                              0   3G  0   3G  0   0    9G  6C,9G                PRSOL                                                                          COTTON       2G  7G  2G  2G  0   0   0   4G  5G  4G   9G  9G                   MORNING GLORY                                                                               2G  6G  0   0   2G  6G  2C,2H                                                                              8G  7H  7H   8G  9G                   COCKLEBUR    2C,3H                                                                              2C,5H                                                                              1C  8G  1C  2C,3H                                                                              3C,3G   7G  6G   7G  9H                   NUTSEDGE     0   8G  4G  9G  0   8G  7G  8G  0   8G   9C  10E                  CRABGRASS    0   5G      2G      0   0   0   0   0    7H  5C,9H                BARNYARD GRASS                                                                              2C,8H                                                                              9H  5G  7H  0   6H  0   4G  0   0    7G  9H                   WILD OATS    3G  2C,7G                                                                              0   3G  2G  3G  0   2G  0   0    3G  2C,7G                WHEAT        2G  8G  0   0   0   0   0   0   0   0    8H  9H                   CORN         3C,6G                                                                              9G  1C,2G                                                                              2C,4G                                                                              0   3C,5G                                                                              2C,4G                                                                              2C,8G                                                                              2C,5G                                                                              2C,5G                                                                               2C,8H                                                                              2C,9H                SOYBEAN      2H  2C,5G                                                                              0   0   0   2G  2C,2H                                                                              3C,8H                                                                              0   2G   3C,7H                                                                              9H                   RICE         7G  8G  4G  8G  0   8G  2G  8G  3G  6G   5C,9H                                                                              10E                  SORGHUM      2C,9H                                                                              2C,9G                                                                              2C,8G                                                                              2C,9G                                                                              3G  4C,9G                                                                              3C,7G                                                                              9H  2C,6G                                                                              2C,8G                                                                               9H  10E                  CHEATGRASS   7G  7G  7G  8G  2G  6G  0   5G  0   0    8G  9H                   SUGAR BEETS  3H  8G  2G  7G  2C,8G                                                                              0   5G  8G  7G  4C,9G                                                                               3C,8G                                                                              3C,8G                VELVETLEAF   2G  6G  0   3H  0   2H  2C,5G                                                                              5G  0   0    6G  3C,8G                GIANT FOXTAIL                                                                               2G  7G  0   3H  0   0   0   2G  0   0    5G  9H                   BARLEY       3G  7G  0   0   1C  3G  0   5G  0   2G   8G  8G                   __________________________________________________________________________                  CMPD 43 CMPD 44 CMPD 45 CMPD 46 CMPD 47  CMPD 48                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       9C  10C 10C 10C 9C  10C 9C  9C  3C,8H                                                                              10C  3C,3G                                                                              3C,8G                MORNING GLORY                                                                               10C 10C 10C 10C 10C 10C 10C 10C 9C  10C  3C,7G                                                                              3C,8G                COCKLEBUR    10C 10C 10C 10C 10C 10C 10C 10C 10C 10C  3G  2H                   NUTSEDGE     3C,9G                                                                              10C 9C  10C 3C,9G                                                                              10C 2C,5G                                                                              5C,9G                                                                              8G  2C,8G                                                                               0                        CRABGRASS    5C,9G                                                                              9C  9G  9C  8G  5C,9G                                                                              9C  9C  5C,9G                                                                              9C   2C,8G                                                                              3C,8G                BARNYARD GRASS                                                                              5C,9G                                                                              10C 10C 10C 10C 10C 9C  9C  3C,9G                                                                              9C   1H  3G                   WILD OATS    3C,9G                                                                              4C,9G                                                                              3C,9G                                                                              4C,9G                                                                              5G  8G  2C,7G                                                                              9G  2C,7G                                                                              3C,9G                                                                               6G  9G                   WHEAT        9G  3C,9G                                                                              3C,9G                                                                              5C,9G                                                                              5G  8G  9G  9C  9G  2C,9G                                                                               3G  3G                   CORN         5C,9G                                                                              9C  9C  9C  4C,9G                                                                              9C  9C  5U,9C                                                                              9G  6U,9G                                                                               9H  3C,9H                SOYBEAN      6C,9G                                                                              9C  5C,9G                                                                              9C  3C,9H                                                                              3C,9G                                                                              4C,9G                                                                              9C  5C,9G                                                                              9C   3G  2C,5G                RICE         9C  9C  9C  10C 9C  9C  9C  9C  9C  9C   3C,5G                                                                              3C,7G                SORGHUN      9C  9C  10C 10C 9C  10C 9C  10C 9G  9C   3G  2C,5G                CHEATGRASS   5C,9G                                                                              9C  10C 10C 6G  9G  2C,7G                                                                              4C,9G                                                                              5G  8G   0   2G                   SUGAR BEETS  9C  10C 10C 10C 9C  9C  10C 9C  7G  6C,9G                                                                               0   0                    VELVETLEAF   10C 10C 10C 10C 10C 10C 5C,9G                                                                              5C,9G                                                                              5C,9G                                                                              10C  3C,7G                                                                              3C,9H                GIANT FOXTAIL                                                                               9C  10C 10C 10C 3C,9G                                                                              10C 5C,9G                                                                              9C  4C,9G                                                                              10C  3C,8G                                                                              3C,9G                BARLEY       3C,9G                                                                              9C  6C,9G                                                                              6C,9G                                                                              4C,8H                                                                              7G  2C,6G                                                                              2C,8G                                                                              3G  6G   2G  0                    PRSOL                                                                          COTTON       9G  9G  9G  9G  8G  9G  9G  9G  7G  7G   0   2G                   MORNING GLORY                                                                               9G  9G  9H  9H  8G  9H  9G  9G  8G  9G   0   5G                   COCKLEBUR    4G              7G  4G  6G  9H  0   2G   0   5G                   NUTSEDGE     9G  10E 9G  9G  9G  10E 6G  8G  0   5G   0   0                    CRABGRASS    3C,9H                                                                              4C,9H                                                                              7G  2C,8G                                                                              7G  2C,8H                                                                              8G  9H  5G       0   8G                   BARNYARD GRASS                                                                              7G  6H  6G  9H  8G  9H  9H  9H  3G  9H   0   4G                   WILD OATS    2C,6G                                                                              6G  4G  5G  0   3G  3G  2C,6G                                                                              0   2C,5G                                                                               0   2C,5G                WHEAT        2C,8H                                                                              3C,8H                                                                              2G  4G  0   5G  8G  9H  0   2C,8H                                                                               0   0                    CORN         8G  3C,9H                                                                              3C,7G                                                                              3C,9H                                                                              9G  9H  2U,9G                                                                              9H  3C,5G                                                                              3C,8H                                                                               0   3C,6G                SOYBEAN      4C,6H                                                                              9H  8H  3C,8H                                                                              2G  2C,8H                                                                              2C,7H                                                                              9H  2C,2G                                                                              3C,7H                                                                               0   2H                   RICE         10H 10H 5G  10H 10E 10H 9H  10E 8G  10E  0   5G                   SORGHUM      10H 10H 6G  9H  9H  10H 9H  10H 2C,8H                                                                              9H   0   2C,5G                CHEATGRASS   9H  10H 5G  9H  3G  4G  6G  9H  0   8G   0   2G                   SUGAR BEETS  2C,5G                                                                              5C,9G                                                                              8G  3C,8G                                                                              8G  3C,9H                                                                              8G  2C,9G                                                                              8G  9G   0   5G                   VELVETLEAF   7G  8H  8G  5C,9H                                                                              7G  3C,8G                                                                              7G  3C,9G                                                                              0   7H   0   2C,5G                GIANT FOXTAIL                                                                               8G  4C,9H                                                                              6G  9H  4G  3C,7H                                                                              3G  2C,5G                                                                              0   7G   0   3C,8G                BARLEY       8G  8G  4G  8G  7G  8G  9G  2C,9H                                                                              2C,2G                                                                              2C,8G                                                                               0   5G                   __________________________________________________________________________                  CMPD 49 CMPD 50 CMPD 51 CMPD 52 CMPD 53  CMPD 54                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       3C,8G                                                                              9C  9C  9C  10C 9C  9C  10C 4C,9G                                                                              10C  4C,8H                                                                              10C                  MORNING GLORY                                                                               9C  10C 10C 10C 10C 10C 10C 10C 5C,9G                                                                              10C  9C  10C                  COCKLEBUR    7H  10C 10C 10C 10C 10C 10C 10C 10C 10C  7H  10C                  NUTSEDGE     5G  8G  9G  4C,9G                                                                              5C,9G                                                                              9C  7G  9G  3G  8G   6G  8G                   CRABGRASS    8G  6C,9G                                                                              4C,9G                                                                              9C  8G  5C,9G                                                                              5G  8G  6C,9G                                                                              9C   8G  9C                   BARNYARD GRASS                                                                              3C,8H                                                                              2C,9H                                                                              9H  9C  9C  9C  9C  9C  9C  10C  3C,8H                                                                              9C                   WILD OATS    8G  3C,9G                                                                              9G  6C,9G                                                                              5C,9G                                                                              5C,9G                                                                              2G  2C,8G                                                                              2C,5G                                                                              4C,9G                                                                               8G  9G                   WHEAT        3C,9G                                                                              2C,9G                                                                              4C,9G                                                                              4C,9G                                                                              2C,9G                                                                              9C  4G  3C,9G                                                                              4C,9G                                                                              9C   7G  5C,9G                CORN         5U,9C                                                                              3U,9G                                                                              9C  4U,9C                                                                              10C 10C 10C 5U,9G                                                                              5U,9C                                                                              10C  9C  9C                   SOYBEAN      3C,8H                                                                              4C,9G                                                                              5C,9G                                                                              9C  9C  9C  3C,7G                                                                              4C,9G                                                                              4C,9G                                                                              9C   4C,9G                                                                              5C,9G                RICE         9C  9C  9C  9C  9C  9C  9C  9C  9C  9C   9C  9C                   SORGHUM      3C,9G                                                                              3C,9G                                                                              9C  5C,9G                                                                              5C,9G                                                                              9C  4C,9G                                                                              9C  5C,9G                                                                              10C  5C,9G                                                                              9C                   CHEATGRASS   8G  3C,9G                                                                              2C,9G                                                                              5C,9G                                                                              6C,9G                                                                              9C  7G  3C,8G                                                                              3C,8G                                                                              9C   7G  3C,9G                SUGAR BEETS  3C,8H                                                                              10C 9C  10C 10C 10C 10C     9C  9C   4C,9H                                                                              10C                  VELVETLEAF   9C  10C 10C 10C 10C 10C 10C 10C 4C,9H                                                                              10C  4C,9H                                                                              10C                  GIANT FOXTAIL                                                                               3C,8G                                                                              9C  9C  10C 9C  10C 3C,8G                                                                              9C  4C,8H                                                                              10C  3C,8G                                                                              9C                   BARLEY       8G  3C,9G                                                                              4C,9G                                                                              5C,9G                                                                              9C  9C  6G  9G  7G  3C,9G                                                                               5G  8G                   PRSOL                                                                          COTTON       2G  8G  5G  8G  6G  8G  2G  7G  6G  8G   2G  6G                   MORNING GLORY                                                                               0   4G  0   9G      8G  0   5G  3H  9G   0   7H                   COCKLEBUR    0   0       3C,6H                                                                              1H      0   6G  2H  3C,7H    5G                   NUTSEDGE     0   10E 0   9G  3G  8G  0   5G  0   3G   0   0                    CRABGRASS    5G  3C,8H                                                                              4G  3C,8G                                                                              2G  7G  0   3G  3G       3G  3C,8G                BARNYARD GRASS                                                                              2H  9H  7G  9H  2C,4G                                                                              9H  6G  8H  8H  9H   4G  7G                   WILD OATS    5G  6G  6G  3C,6G                                                                              0   5G  2G  3G  4G  6G   0   3G                   WHEAT        5G  8G  6G  7G  0   8G  0   6G  7G  8H   0   8G                   CORN         5G  3C,9H                                                                              2C,4G                                                                              3C,9H                                                                              3G  2U,9H                                                                              2C,4G                                                                              3U,9H                                                                              3C,7G                                                                              4U,9H                                                                               2C,7G                                                                              4C,8G                SOYBEAN      2G  3C,6H                                                                              2H  9H  1H  3C,6H                                                                              0   1C  2C,2H                                                                              4C,9H                                                                               2C,2H                                                                              2C,4G                RICE         9H  9H  6G  10H 4G  9H  6G  10E 9H  10H  7G  10H                  SORGHUM      3C,9H                                                                              9H  3C,7G                                                                              10H 3C,7G                                                                              10E 8G  10H 9H  10H  9G  10H                  CHEATGRASS   5G  9H  7G  9H  6G  8G  2G  6G  5G  6H   0   3G                   SUGAR BEETS  7H  9G  6G  4C,9G                                                                              7G  9C  6H  8H  9G  9G   5H  8G                   VELVETLEAF   0   5G  4G  5G  2H  7G  0   2G  2G  7G   0   7G                   GIANT FOXTAIL                                                                               2G  9H  7G  8H  4G  9H  0   6G  3G  9H   0   8G                   BARLEY       7G  6G  3G  8G  2G  6G  0   7G  7G  9G   5G  8G                   __________________________________________________________________________                  CMPD 55 CMPD 56 CMPD 57 CMPD 58 CMPD 59  CMPD 60                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       2C,3G                                                                              4C,8H                                                                              4C,9H                                                                              2C,9G                                                                              3C,9G                                                                              10C 9C  10C 8G  6C,9G                                                                               3C,6G                                                                              4C,9G                MORNING GLORY                                                                               2C,7G                                                                              6G  3C,8H                                                                              10C 5C,9G                                                                              10C 9C  10C 3C,8G                                                                              10C  2C,5G                                                                              4C,8H                COCKLEBUR    5H  3H  7H  10C 9C  10C 10C 10C 10C 10C  3C,7G                                                                              10C                  NUTSEDGE     2G  3G  9G  2C,9G                                                                              9G  4C,9G                                                                              9G  6C,9G                                                                              9G  4C,9G                                                                               4G  3C,8G                CRABGRASS    4C,7G                                                                              2C,8G                                                                              4C,9G                                                                              9C  8G  4C,9G                                                                              7G  6C,9G                                                                              5G  8G   4C,9G                                                                              5C,9G                BARNYARD GRASS                                                                              2G  3H  4C,8H                                                                              9C  4C,9H                                                                              9C  6C,9H                                                                              10C 9C  10C  9C  10C                  WILD OATS    3G  4G  4C,8G                                                                              4C,9G                                                                              3C,8G                                                                              6C,9G                                                                              2C,9G                                                                              4C,9G                                                                              4G  9G   9G  9G                   WHEAT        2G  2G  9C  9C  8G  6C,9G                                                                              9G  4C,9G                                                                              5G  3C,9G                                                                               5C,9G                                                                              3C,9G                CORN         3C,9H                                                                              2C,8H                                                                              10C 10C 4U,9C                                                                              10C 4U,9C                                                                              10C 5U,9G                                                                              10C  5C,9G                                                                              10C                  SOYBEAN      1H  4G  4C,9G                                                                              9C  3C,9G                                                                              9C  9C  9C  2C,8G                                                                              6C,9G                                                                               4C,8G                                                                              5C,9G                RICE         4C,8G                                                                              7G  5C,9G                                                                              5C,9G                                                                              9C  9C  5C,9G                                                                              6C,9G                                                                              4C,9G                                                                              6C,9G                                                                               5C,9G                                                                              6C,9G                SORGHUM      4C,8G                                                                              2C,8G                                                                              2C,9G                                                                              3C,9G                                                                              3C,9G                                                                              9C  3C,7G                                                                              10C 3C,9G                                                                              9C   4C,9G                                                                              9C                   CHEATGRASS   3G  3G  8G  5C,9G                                                                              4C,8G                                                                              6C,9G                                                                              3C,9G                                                                              9C  5G  8G   2C,8G                                                                              9C                   SUGAR BEETS  4G  5G  9C  10C 9C  9C  9C  9C  5C,9G                                                                              6C,9G                                                                               3C,7H                                                                              9C                   VELVETLEAF   3C,8H                                                                              3C,8H                                                                              4C,8H                                                                              5C,9G                                                                              5C,9H                                                                              10C 9C  10C 7G  9C   3C,7G                                                                              4C,8H                GIANT FOXTAIL                                                                               4C,8G                                                                              2C,8G                                                                              5C,9H                                                                              9C  5C,9G                                                                              9C  9C  9C  9C  9C   5C,9G                                                                              9C                   BARLEY       0   3G  9G  5C,9G                                                                              2C,8G                                                                              9C  5C,9G                                                                              9C  2C,9G                                                                              2C,9G                                                                               8G  5C,9G                PRSOL                                                                          COTTON       4G  0   5G  6G  1C  8G  3G  8G  2G  7G   2G  7G                   MORNING GLORY                                                                               0   0   0   7H  0   9G  3G  9G  2G  9G   2G  2C,4G                COCKLEBUR    0   0   2H      0   8H  0   8H      8H   0   2C,2G                NUTSEDGE     0   0   9G  10E 8G  10E 5G  10E 10E 10E  2G  9G                   CRABGRASS    0   8G  0   3C,8G                                                                              3C,6G                                                                              4C,8H                                                                              4G  8H  3G  9G   2G  9H                   BARNYARD GRASS                                                                              0   2G  0   2C,3G                                                                              2C  4C,9H                                                                              3G  9H  5G  9H   2C,7G                                                                              9H                   WILD OATS    0   2G  0   4G  4G  2C,6G                                                                              3G  2C,6G                                                                              2G  3C,7G                                                                               4G  7G                   WHEAT        0   0   0   7G  5G  8G  5G  7G  7G  8G   8H  4C,9H                CORN         0   3C,3G                                                                              3C,6G                                                                              3C,9G                                                                              3C,5G                                                                              4C,9G                                                                              2C,5G                                                                              3C,8H                                                                              3C,7G                                                                              9H   2C,8G                                                                              3C,8G                SOYBEAN      0   4H  3G  2C,5G                                                                              2G  3C,7H                                                                              3G  3C,7H                                                                              3G  3C,8H                                                                               3G  3C,3H                RICE         0   0   0   8G  3C,4G                                                                              3C,9H                                                                              3G  9H  8H  10H  6G  9H                   SORGHUM      0   4G  3C,7G                                                                              9H  3C,8H                                                                              5C,9H                                                                              3C,8H                                                                              4C,9H                                                                              3C,8H                                                                              10E  2C,8H                                                                              3C,9H                CHEATGRASS   0   2G  0   7G  6G  4C,8G                                                                              2G  9G  5G  7G   6G  9H                   SUGAR BEETS  5G  6H  5G  7G  6G  8G  3H  7G  2C  7G   2G  4C,9G                VELVETLEAF   0   2H  1H  2C,4H                                                                              0   7G  0   9G  0   5G   2G  2C,5H                GIANT FOXTAIL                                                                               0   5G  0   2C,9G                                                                              3C,6G                                                                              4C,9H                                                                              2C,7G                                                                              9H  2G  9H   5G  9H                   BARLEY       0   0   2G  2C,8G                                                                              4G  4C,8G                                                                              4G  3C,7G                                                                              8G  9H   8G  3C,9H                __________________________________________________________________________                  CMPD 61 CMPD 62 CMPD 63 CMPD 64 CMPD 65  CMPD 66                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       4C,9H                                                                              4C,9G                                                                              7G  3C,9G                                                                              4C,9G                                                                              9G  9G  10C 7G  9C   8H  3C,9G                MORNING GLORY                                                                               4C,8H                                                                              4C,9G                                                                              6H  2C,9G                                                                              4C,9G                                                                              9C  4C,9G                                                                              10C 2C,6G                                                                              9C   4C,9H                                                                              5C,9G                COCKLEBUR    2C,5G                                                                              9C  5H  5C,9G                                                                              8H  10C 2C,8G                                                                              10C 2C,7G                                                                              10C  3C,9G                                                                              10C                  NUTSEDGE     5G  2C,9G   9G  2C,8G                                                                              10C 9G  5C,9G                                                                              0   8G   0   3C,6G                CRABGRASS    4C,9G                                                                              6C,9G   8G              8G  0   6G   6G                       BARNYARD GRASS                                                                              3C,9H                                                                              10C 6H  3C,9H                                                                              9H  5C,9H                                                                              9H  9C  8H  4C,9H                                                                               3C,9H                                                                              9C                   WILD OATS    7G  3C,9G                                                                              3G  9G  5G  9G  6G  5C,9G                                                                              0   2G   2G  2C,5G                WHEAT        7G  9C  6G  9G  9G  9G  8G  2C,9G                                                                              3G  5G   2G  3C,9G                CORN         5U,9G                                                                              10C 2C,9H                                                                              2C,9G                                                                              9G  9H  9H  3U,9C                                                                              8H  9H   3C,9H                                                                              3U,9C                SOYBEAN      3C,8G                                                                              5C,9G                                                                              5G  3C,8G                                                                              3C,6G                                                                              9C  5C,9G                                                                              9C  0   3G   3C,8G                                                                              9C                   RICE         5C,9G                                                                              5C,9G                                                                              4C,9G                                                                              5C,9G                                                                              3C,9G                                                                              5C,9G   6C,9G                                                                              9G  9C   5C,9G                                                                              5C,9G                SORGHUM      5C,9G                                                                              9C  3C,7H                                                                              4C,9G                                                                              3C,7G                                                                              4C,9G                                                                              8H  9C  5G  2C,9H                                                                               3C,8G                                                                              9C                   CHEATGRASS   3C,7G                                                                              9G  9G  2C,8G                                                                              8G  3C,9G                                                                              4C,9G                                                                              5C,9G                                                                              0   3G   0   2C,7G                SUGAR BEETS  2C,4G                                                                              9C  9C  5C,9G   10C 10C 9C  10C 10C  10C 9C                   VELVETLEAF   3C,7G                                                                              4C,8H                                                                              5G  3C,9G                                                                              9G  9C  5C,9G   7G  5C,9G                                                                               3C,7H                                                                              4C,9H                GIANT FOXTAIL                                                                               5C,9G                                                                              9C  3C,7G                                                                              7G  7G  4C,9G   5C,9G                                                                              2G  8G   2C,2G                                                                              3C,8G                BARLEY       7G  3C,9G                                                                              2G  9G  5G  9G  2C,9G                                                                              4C,9G                                                                              2G  7G   3C,5G                                                                              3C,7G                PRSOL                                                                          COTTON       0   7G  0   7G  3G  9G  3G  8G  0   6G   6G  8G                   MORNING GLORY                                                                               0   3C,4G                                                                              2G  8H  0   8G  5G  7G  0   8G   7H  8G                   COCKLEBUR    0   3C,4G                                                                              0   6H  0   0   0   0   0   9H   0                        NUTSEDGE     5G  10E 5G  10E 0   9G  0   9G  0   4G   0   0                    CRABGRASS    5G  10E 4G  2C,8G                                                                              3G  7G  0   0   0   3G   0   3C,8H                BARNYARD GRASS                                                                              0   9H  0   9H  5G  9H  2G  9H  3G  8H   5G  9H                   WILD OATS    2G  3C,7G                                                                              0   6G  0   3C,7G                                                                              2G  7G  0   0    2G  3C,3G                WHEAT        0   2C,8G                                                                              5G  7G  4G  8G  2G  7G  0   2G   2G  8G                   CORN         2C,2G                                                                              3C,8G                                                                              2C,2G                                                                              2C,8G                                                                              4C,8G                                                                              8H  0   2C,7G                                                                              1C  3C,7G                                                                               3C,7G                                                                              3C,8G                SOYBEAN      1H  2C,7G                                                                              1H  3C,7H                                                                              2C,4H                                                                              3C,6G                                                                              1H  3C,6H                                                                              0   3H   3G  3C,8H                RICE         3G  10H 9H  10H 9H  9H  5G  10H 8G  10E  9H  10H                  SORGHUM      3C,8H                                                                              5C,9H                                                                              3C,5G                                                                              9H  3C,8H                                                                              4C,9H                                                                              0   9H  3C,3G                                                                              9H   2C,9G                                                                              2C,9G                CHEATGRASS   0   4C,9H                                                                              9H  9H  8G  3C,8G                                                                              0   9H  0   5G   2G  2C,7G                SUGAR BEETS  0   7G  0   8G  7G  9G  3G  9G  0   8G   3G  9G                   VELVETLEAF   0   1C  0   8G  2H  8G  1H  7G  0   7G   0   8H                   GIANT FOXTAIL                                                                               5G  9H  0   6G  0   2C,8H                                                                              2G  8H  0   3G   0   3G                   BARLEY       2G  3C,9G                                                                              3G  7G  0   5G  0   3G  0   4G   2G  8G                   __________________________________________________________________________                  CMPD 67 CMPD 68 CMPD 69 CMPD 70 CMPD 71  CMPD 72                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       5G  9G  2C,5G                                                                              5C,9G                                                                              7G  9C  7G  4C,8G                                                                              4C,9G                                                                              5C,9G                                                                               3C,7G                                                                              4C,9G                MORNING GLORY                                                                               4C,9H                                                                              4C,9G                                                                              3C,8G                                                                              10C 3C,7G                                                                              10C 3C,7H                                                                              10C 3C,7G                                                                              9C   3C,8G                                                                              4C,9H                COCKLEBUR    2H  4C,8H                                                                              2H,6G                                                                              10C 3C,8H                                                                              10C 2C,8G                                                                              10C 10C 10C  6C,9G                                                                              10C                  NUTSEDGE     0   0   2C,8G                                                                              4C,8G                                                                              3C,5G                                                                              5C,9G                                                                              3C,5G                                                                              10C 5G  5C,9G                                                                               10C 3C,8G                CRABGRASS    0   0   2G  3C,7G                                                                              2C  3C,7G                                                                              0   2C,6G                                                                              0   3C,8G                                                                               0   2C,5G                BARNYARD GRASS                                                                              2H  4C,9H                                                                              8H  5C,9H                                                                              4C,9H                                                                              9C  3C,9H                                                                              5C,9H                                                                              9H  9C   0   4C,9H                WILD OATS    0   3G  2C,3G                                                                              4C,9H                                                                              3C,6G                                                                              3C,7G                                                                              0   2C,2G                                                                              0   2C   0   3C,3G                WHEAT        0   3G  6G  9G  3G  8G  3G  5G  0   6G   0   5G                   CORN         0   3C,9H                                                                              2C,9H                                                                              4C,9H                                                                              3C,9H                                                                              9C  3C,8H                                                                              9C  2C,8H                                                                              9C   1C,3H                                                                              9C                   SOYBEAN      3C,8H                                                                              5C,9G                                                                              2C,4H                                                                              3C,8H                                                                              3H,7G                                                                              4C,9G                                                                              4G  3C,5G                                                                              4C,9G                                                                              5C,9G                                                                               3C,8G                                                                              5C,9G                RICE         3C,7G                                                                              5C,9G                                                                              5C,9G                                                                              9C  4C,8G                                                                              9C  4C,9G                                                                              9C  4C,9G                                                                              9C   7G  9C                   SORGHUM      0   3C,5G                                                                              2C,6G                                                                              9G  3C,9G                                                                              3C,9G                                                                              3C,9H                                                                              9C  9G  3C,9G                                                                               3C,8H                                                                              4C,9G                CHEATGRASS   0   2G  6G  4C,9G                                                                              7G  3C,8G                                                                              2C,2G                                                                              7G  0   2C,5G                                                                               0   1C                   SUGAR BEETS  10C 10C 3C,8G                                                                              9C  3C,7G                                                                              10C 3C,6G                                                                              9C  9C  9C   9C  10C                  VELVETLEAF   2G  3C,6G                                                                              6G  4C,9H                                                                              3C,8G                                                                              9C  7G  5C,9G                                                                              3C,8H                                                                              9C   2H  3C,8G                GIANT FOXTAIL                                                                               0   4G  3G  4C,8H                                                                              2C,5G                                                                              4C,9G                                                                              3G  3C,7H                                                                              2G  3C,7H                                                                               2C,3G                                                                              3C,5G                BARLEY       0   2C,5G                                                                              2C,8G                                                                              8G  2C,5G                                                                              2C,8G                                                                              2C,6G                                                                              2C,9G                                                                              0   2C,4G                                                                               0   3C,5G                PRSOL                                                                          COTTON       2G  5G  9G  9G  2C,8G                                                                              9G  8G  9G  0   0    8G  2C,8G                MORNING GLORY                                                                               5G  7G  8G  8G  9C  9G  9G  9G  3G  0    9G  9C                   COCKLEBUR    0   0   8H  8H  8H  9H      8H  0   0    3C,7H                                                                              9H                   NUTSEDGE     0   0   8G  10E 8G  10E 5G  10E 0   0    5G  7G                   CRABGRASS    0   0   0   9C  2C,5G                                                                              3C,7G                                                                              0   2G  0   0    3C,6G                                                                              3C,6G                BARNYARD GRASS                                                                              0   2G  2C,4G                                                                              3C,9H                                                                              9H  3C,9H                                                                              2C,8G                                                                              9H  0   0    4C,9H                                                                              6C,9H                WILD OATS    0   2G  2C,8G                                                                              3C,9G                                                                              5C,9G                                                                              9C  3C,8G                                                                              8G  0   0    2C,5G                                                                              3C,8G                WHEAT        0   0   3C,9H                                                                              5C,9H                                                                              5C,9G                                                                              9C  2C,7H                                                                              2C,8H                                                                              0   2G   3C,9H                                                                              9C                   CORN         2G  2C,5G                                                                              3C,9H                                                                              10H 3U,9G                                                                              3C,9G                                                                              3C,8G                                                                              3C,9G                                                                              0   2C,5G                                                                               2C,9G                                                                              4C,9G                SOYBEAN      1C  2C,4G                                                                              3C,7G                                                                              4C,8H                                                                              4C,8G                                                                              3C,9H                                                                              3C,4G                                                                              2C,8H                                                                              0   0    3C,5G                                                                              3C,8G                RICE         3G  9H  9H  10E 10E 10E 9H  10E 0   3G   4C,9G                                                                              10E                  SORGHUM      0   8G  3C,9G                                                                              9H  9H  4C,9H                                                                              9G  9H  0   3C,3G                                                                               4C,9G                                                                              4C,9G                CHEATGRASS   0   2G  8G  9H  4C,9H                                                                              5C,9H                                                                              5G  8H  0   5G   3C,7G                                                                              7C,9H                SUGAR BEETS  4G  8G  3C,8G                                                                              9G  4C,9G                                                                              5C,9G                                                                              7G  9G  0   2H   9C  5C,9G                VELVETLEAF   0   0   8G  9G  9G  9G  9G  9G  0   0    3C,7G                                                                              3C,9G                GIANT FOXTAIL                                                                               0   0   0   3C,7G                                                                              3C,8G                                                                              3C,9H                                                                              2C  2C,6G                                                                              0   0    2C,3G                                                                              3C,7G                BARLEY       0   0   9G  2C,9G                                                                              4C,9G                                                                              4C,9G                                                                              9G  3C,9G                                                                              0   2G   9G  3C,9G                __________________________________________________________________________                  CMPD 73 CMPD 74 CMPD 75 CMPD 76 CMPD 77  CMPD 78                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       0   3C,7G                                                                              0   0   0   3G  0   0   0   0    0   0                    MORNING GLORY                                                                               0   2C  0   2C,4G                                                                              0   3C,7G                                                                              0   0   0   0    0   0                    COCKLEBUR    0   1H  0   0   0   0   0   0   0   0    0   0                    NUTSEDGE     0   0   0   0   0   0   0   0   0   0    0   0                    CRABGRASS    0   2G  0   0   0   0   0   0   0   0    0   0                    BARNYARD GRASS                                                                              0   3H  0   2H  0   0   0   0   0   0    0   0                    WILD OATS    0   2C  0   6G  0   0   0   0   0   0    0   0                    WHEAT        0   2G  0   5G  0   0   0   0   0   0    0   0                    CORN         0   3C,4G                                                                              0   4G  0   0   0   0   0   0    0   0                    SOYBEAN      0   0   0   4G  0   0   0   0   0   0    2H  0                    RICE         0   3C,8G                                                                              0   0   0   0   0   0   0   0    0   0                    SORGHUM      0   2C,4G                                                                              0   2G  0   0   0   0   0   0    0   0                    CHEATGRASS   0   3C,5G                                                                              0   0   0   0   0   0   0   0    0   0                    SUGAR BEETS  0   3C,5G                                                                              0   0   0   3C,7G                                                                              0   0   0   0    0   0                    VELVETLEAF   0   2G  0   0   0   0   0   0   0   0    0   0                    GIANT FOXTAIL                                                                               0   2C,5G                                                                              0   2G  0   0   0   0   0   0    0   0                    BARLEY       0   0   0   0   0   0   0   0   0   0    0   0                    PRSOL                                                                          COTTON       7G  9G  0   6G  0   0   0   0   0   0    0   0                    MORNING GLORY                                                                               8G  9C  0   7G  0   0   0   0   0   0    0   0                    COCKLEBUR    2C,4G                                                                              3C,7H                                                                              0   9H  0   0   0   0   0   0    0   0                    NUTSEDGE     7G  3G  0   0   0   0   0   0   0   0    0   0                    CRABGRASS    2G  2C,3G                                                                              0       0   0   0   0   0   0    0   0                    BARNYARD GRASS                                                                              3C,7G                                                                              9H  0   2C,6G                                                                              0   0   0   0   0   0    0   0                    WILD OATS    0   3C,8G                                                                              0   3C,8G                                                                              0   0   0   0   0   0    0   0                    WHEAT        0   8H  0   5G  0   0   0   0   0   0    0   0                    CORN         3C,6G                                                                              3C,9G                                                                              2G  3C,9H                                                                              0   0   0   0   0   0    0   0                    SOYBEAN      3C,4G                                                                              3C,7G                                                                              0   2C,2H                                                                              0   0   0   0   0   0    0   0                    RICE         4C,9H                                                                              9H  6G  9H  0   0   0   0   0   0    0   0                    SORGHUM      4C,8G                                                                              4C,8G                                                                              5G  3C,9G                                                                              0   0   0   0   0   0    0   0                    CHEATGRASS   2G  7G  3G  8G  0   0   0   0   0   0    0   0                    SUGAR BEETS  8G  5C,9G                                                                              2H  5G  0   0   0   0   0   0    0   0                    VELVETLEAF   2G  8G  0   7G  0   0   0   0   0   0    0   0                    GIANT FOXTAIL                                                                               5G  6G  0   3C,7G                                                                              0   0   0   0   0   0    0   0                    BARLEY       9G  9G  2G  8G  0   0   0   0   0   0    0   0                    __________________________________________________________________________                  CMPD 79 CMPD 80 CMPD 81 CMPD 82 CMPD 83  CMPD 84                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       0   0   2C,5G                                                                              4C,8G                                                                              2C,7G                                                                              10C 5C,9G                                                                              10C 2C,3G                                                                              4C,9G                                                                               10C 5C,9G                MORNING GLORY                                                                               0   0   2C,2G                                                                              3C,8G                                                                              5C,9G                                                                              10C 4C,8G                                                                              10C 10C 10C  4C,8H                                                                              10C                  COCKLEBUR    0   0   4C,9H                                                                              9C  10C 9C  10C 10C 3H  10C  9C  10C                  NUTSEDGE     0   0       9C  3C,8G                                                                              10C 9C      0   9C   6G  7G                   CRABGRASS    0   0   7G  5C,9G                                                                              3C,7G                                                                              9C  5C,9G                                                                              5C,9G                                                                              3G  7G   7G  9C                   BARNYARD GRASS                                                                              0   0   9C  10C 9C  10C 9C  10C 5C,9G                                                                              10C  9C  10C                  WILD OATS    0   0   2C,3G                                                                              5C,9G                                                                              5C,9G                                                                              5C,9G                                                                              3C,7G                                                                              9C  0   2C,3G                                                                               0   2C,3G                WHEAT        0   0   8G  2C,9G                                                                              9G  5C,9G                                                                              8G  9G  2G  5G   4G  3C,9G                CORN         0   0   9C  9C  9C  10C 10C 10C 9C  9C   9C  10C                  SOYBEAN      0   0   3C,6G                                                                              5C,9G                                                                              3C,8H                                                                              9C  5C,9G                                                                              9C  2C,3H                                                                              4C,9G                                                                               5C,9G                                                                              5C,9G                RICE         0   0   9C  9C  9C  9C  9C  9C  9C  9C   9C  9C                   SORGHUM      0   0   9G  9C  9C  10C 9C  9C  9C  9C   9C  9C                   CHEATGRASS   0   0   3C,7G                                                                              4C,9G                                                                              5C,9G                                                                              10C 9C  9C  2G  6G   0   3C,9G                SUGAR BEETS  0   0   9C  10C 10C 10C 10C 10C 9C  9C   10C 10C                  VELVETLEAF   0   0   3C,7G                                                                              9C  3C,8G                                                                              9C  10C 10C 5C,9G                                                                              10C  3C,7H                                                                              4C,8H                GIANT FOXTAIL                                                                               0   0   5G  3C,8G                                                                              3C,9H                                                                              9C  9C  10C 3C,6G                                                                              3C,7G                                                                               3C,6G                                                                              9C                   BARLEY       0   0   2C,3G                                                                              3C,6G                                                                              3C,6G                                                                              9G  7G  5C,9G                                                                              0   3C,8G                                                                               2G  5G                   PRSOL                                                                          COTTON       0   0   0   7G  5G  8G  8G  8G  3G  3G   3G  4G                   MORNING GLORY                                                                               0   0   0   2C,3G                                                                              1C  5G  6G  8G  2C  8G   3G  9H                   COCKLEBUR        0   0   2G  1C  1C  0   2G  0   0    0   3H                   NUTSEDGE     0   0   0   10E 0   10E 0   4C,9G                                                                              5G  0    0   0                    CRABGRASS    0   0   0   4G  0   5G  0   5C,9G                                                                              2G  0    0   5G                   BARNYARD GRASS                                                                              0   0   0   2G  0   3C,6G                                                                              0   3C,7H                                                                              0   5H   0   1C                   WILD OATS    0   0   0   0   0   3G  0   2C,4G                                                                              0   0    0   0                    WHEAT        0   0   0   0   0   6G  0   0   0   0    0   0                    CORN         0   0   0   2C,8G                                                                              5G  3C,9G                                                                              0   3C,7G                                                                              2G  2G   0   3C,7G                SOYBEAN      0   0   0   1H  2G  3C,6H                                                                              3C,3H                                                                              4C,8H                                                                              2G  3G   2G  3C,8G                RICE         0   0   2C,5G                                                                              9H  5G  9H  3C,3G                                                                              8G  5G  8G   2G  3C,7G                SORGHUM      0   0   0   3C,7G                                                                              2G  3C,9G                                                                              3G  3C,7G                                                                              2G  7G   3G  3C,9G                CHEATGRASS   0   0   0   5G  0   7G  0   3G  2G  0    0   0                    SUGAR BEETS  0   0   7G  9G  7G  9G  8G  9G  7G  8G   7G  8G                   VELVETLEAF   0   0   0   8G  0   5H  5G  4C,8G                                                                              0   3H   2H  3C,6H                GIANT FOXTAIL                                                                               0   0   0   3G  0   3C,7G                                                                              3G  3C,8G                                                                              0   0    0   3G                   BARLEY       0   0   0   1C  2G  2C,4G                                                                              0   3C,5G                                                                              0   0    0   0                    __________________________________________________________________________                  CMPD 85 CMPD 86 CMPD 87 CMPD 88 CMPD 89  CMPD 90                  RATE = KG/HA 0.01                                                                               0.05                                                                                0.01                                                                              0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       2H,5G                                                                              3C,8G                                                                              0   4C,9H                                                                              3C,7G                                                                              5C,9G                                                                              6G  3C,7G                                                                              0   8G   0   3C,8G                MORNING GLORY                                                                               5C,9G                                                                              9C  1H  2C,5G                                                                              3C,8H                                                                              4C,9G                                                                              4G  9C  3C,4H                                                                              4C,9G                                                                               3G  4C,8H                COCKLEBUR    1H  6G  5G  5C,9G                                                                              3C,8H                                                                              9C  4C,9G                                                                              10C 2C,4H                                                                              3C,7G                                                                               4C,9G                                                                              5C,9G                NUTSEDGE     3G  0   6G  9C  0   4C,9G                                                                              5G  10C 0   4G   0   0                    CRABGRASS    3G  7G  0   2C,5G                                                                              5G  3C,7G                                                                              5G  9C  0   3C,7G                                                                               0   4C,9G                BARNYARD GRASS                                                                              4C,8H                                                                              9C  2C,5H                                                                              3C,8H                                                                              4C,9G                                                                              9C  4C,9G                                                                              5C,9H                                                                              4C,9H                                                                              10C  4C,9H                                                                              9C                   WILD OATS    0   2C,5G                                                                              0   2G  2C,5G                                                                              3C,8G                                                                              0   2C,5G                                                                              0   0    0   0                    WHEAT        0   2G  0   3G  2G  3C,7G                                                                              2G  2C,8G                                                                              0   2G   2G  3G                   CORN         4C,9H                                                                              9C  3C,9G                                                                              4C,9G                                                                              9C  9C  10C 10C 3C,9G                                                                              10C  9C  10C                  SOYBEAN      3C,8H                                                                              5C,9G                                                                              3C,3H                                                                              3C,9H                                                                              4C,8G                                                                              5C,9G                                                                              4C,9G                                                                              9C  3C,6H                                                                              4C,9G                                                                               3C,7H                                                                              3C,9G                RICE         5G  9C  4C,9G                                                                              5C,9G                                                                              5C,9G                                                                              5C,9G                                                                              4C,9G                                                                              9C  3C,9G                                                                              5C,9G                                                                               4C,9G                                                                              9C                   SORGHUM      8G  3C,9G                                                                              3C,8G                                                                              5C,9G                                                                              4C,9G                                                                              9C  3C,9H                                                                              10C 9G  9C   5C,9G                                                                              9C                   CHEATGRASS   0   0                                                             SUGAR BEETS  9C  10C 3C,6H                                                                              5C,9G                                                                              5C,9G                                                                              10C 10C 10C 3C,5G                                                                              10C  3G  9C                   VELVETLEAF   1C,1H                                                                              9C  0   3G  6G  9C  3C,7G                                                                              10C 3C,7G                                                                              3C,7H                                                                               0   3H                   GIANT FOXTAIL                                                                               2G  3C,6G                                                                              0   4G  3C,6G                                                                              9C  3G  9C  0   3G   2G  4C,9G                BARLEY       0   0   0   3G  2C,5G                                                                              4C,9G                                                                              3G  4C,9G                                                                              0   3G   0   2G                   DOWNY BROME          0   3C,7G                                                                              3C,8G                                                                              9C  5C,9G                                                                              9C  0   0    0   3C,5G                PRSOL                                                                          COTTON       0   6G  0   0   0   3G  7G  8G  0   3G   0   0                    MORNING GLORY                                                                               0   5G  0   0   0   0   2G  8G  2C,2H                                                                              3G   0   0                    COCKLEBUR    0   0   0   0   0   0   0   3C,6G                                                                              0   0    0   7G                   NUTSEDGE     0   0   0   0   0   0   0   0   0   0    0   0                    CRABGRASS    0   0   0   0   0   2C,5G                                                                              0   3C,8G                                                                              0   0    0   0                    BARNYARD GRASS                                                                              0   2C  0   0   0   0   0   5G  0   3G   0   0                    WILD OATS    0   0   0   0   0   0   0   0   0   0    0   0                    WHEAT        0   0   0   2G  0   0   0   5G  0   5G   0   0                    CORN         0   2G  0   0   0   3G  2G  2C,5G                                                                              0   2C,6G                                                                               0   0                    SOYBEAN      2G  3C,6G                                                                              0   2G  2C,7H                                                                              3C,8H                                                                              2C,7G                                                                              9H  2G  3G   0   0                    RICE         0   0   0   0   0   5G  2G  8G  2G  6G   0   3G                   SORGHUM      0   0   0   0   0   3G  0   3C,7G                                                                              3G  6G   0   0                    CHEATGRASS   0   0                                                             SUGAR BEETS  5G  9G  0   0   0   8G  6G  8G  0   5G   0   2H                   VELVETLEAF   0   2G  0   0   0   0   3H  5H  0   1H   0   0                    GIANT FOXTAIL                                                                               0   0   0   0   0   3G  0   3H  0   0    0   0                    BARLEY       0   0   0   2G  0   3G  0   4G  0   3G   0   0                    DOWNY BROME          0   0   0   3G  2G  5G  0   0    0   0                    __________________________________________________________________________                  CMPD 91 CMPD 92 CMPD 93 CMPD 94 CMPD 95  CMPD 96                  RATE = KG/HA 0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05                                                                               0.01                                                                               0.05 0.01                                                                               0.05                 __________________________________________________________________________     POSOL                                                                          COTTON       0   3C,7G                                                                              5G  4C,9G                                                                              3C,9G                                                                              5C,9G                                                                              3C,9G                                                                              2C,9G                                                                              2C,7G                                                                              3C,8G                                                                               5C,9G                                                                              9C                   MORNING GLORY                                                                               0   0   2C,3H                                                                              3C,8G                                                                              9C  9C  10C 9C  10C 10C  9C  9C                   COCKLEBUR    0   4H  5C,9G                                                                              10C 10C 9C  10C 10C 10C 10C  10C 10C                  NUTSEDGE     0       3G  5C,9G                                                                              2C,5G                                                                              3C,7G                                                                              9C  4C,8G                                                                              3C,3G                                                                              3C,7G                                                                               0   2G                   CRABGRASS    0   3G  3G  2C,5G                                                                              3C,6G                                                                              9C  2C,5G                                                                              4C,8G                                                                              2G  3C,7G                                                                               2C  9C                   BARNYARD GRASS                                                                              3H  4C,9H                                                                              2C,3G                                                                              4C,9H                                                                              10C 9C  3C,8G                                                                              4C,9G                                                                              3C,8H                                                                              9C   4C,9H                                                                              9C                   WILD OATS    0   2G  2G  2C,8G                                                                              3C,5G                                                                              4C,9G                                                                              2C,5G                                                                              2C,9G                                                                              0   2C,3G                                                                               0   2C,2G                WHEAT        0   2G  3G  9G  5G  3C,9G                                                                              5G  8G  0   3C,5G                                                                               0   2C,4G                CORN         3C,9H                                                                              5C,9G                                                                              4U,9G                                                                              5C,9G                                                                              9C  10C 5C,9G                                                                              9C  4C,9G                                                                              3C,9G                                                                               4C,9G                                                                              10C                  SOYBEAN      0   4C,8H                                                                              3C,8G                                                                              4C,9G                                                                              9C  9C  5C,9G                                                                              9C  3C,7G                                                                              4C,9G                                                                               3C,8G                                                                              4C,9G                RICE         2G  4C,9G                                                                              3C,9G                                                                              4C,9G                                                                              5C,9G                                                                              9C  3C,9G                                                                              5C,9G                                                                              8G  5C,9G                                                                               5C,9G                                                                              9C                   SORGHUM      7H  3C,9G                                                                              3C,8G                                                                              3C,9G                                                                              5C,9G                                                                              9C  3C,8G                                                                              9C  3C,6G                                                                              3C,9G                                                                               2C,9G                                                                              9C                   SUGAR BEETS  2G  3C,7G                                                                              9C  9C  9C  9C  9C  10C 10C 9C   9C  10C                  VELVETLEAF   0   3G  5C,9G                                                                              9C  3C,9G                                                                              4C,9G                                                                              3C,9H                                                                              9C  1C,5G                                                                              9C   4C,8G                                                                              9C                   GIANT FOXTAIL                                                                               0   3C,7G                                                                              0   2C,5G                                                                              3C,6G                                                                              9C  2C,5G                                                                              5C,9G                                                                              0   5C,6G                                                                               2C,2G                                                                              9C                   BARLEY       0   0   3G  6G  3C,5G                                                                              2C,8G                                                                              4G  2C,8G                                                                              0   4G   0   2G                   DOWNY BROME  4G  4G  4C,9G                                                                              9C  3C,9G                                                                              5C,9G                                                                              3C,8G                                                                              9C  0   5G   0   8G                   PRSOL                                                                          COTTON       0   0   5G  6G  3G  8G  6G  9C  4G  2G   7G  8G                   MORNING GLORY                                                                               0   0   0   5G  3G  9G  0   5G  4G  9G   3C,5G                                                                              8G                   COCKLEBUR    0   0   2C,2H                                                                              3C,5H                                                                              2G  3C,5H                                                                              2C,3G                                                                              3C,6H                                                                              1H  2C,3H                                                                               4C,9G                                                                              3C,8H                NUTSEDGE     0   0   5G  5G  0   10E 0   9G  0   8G   0   3G                   CRABGRASS    0   0   3C,5G                                                                              3C,6G                                                                              2C,5G                                                                              3C,8G                                                                              0   3C,8G                                                                              3G  3C,7G                                                                               0   4C,9G                BARNYARD GRASS                                                                              0   0   0   2H  3G  3C,8H                                                                              2G  2G,2H                                                                              0   3G   1C  2C,8H                WILD OATS    0   0   4G  2C,7G                                                                              2G  3C,6G                                                                              0   5G  0   0    0   2G                   WHEAT        0   0   3G  6G  2G  5G  0   6G  0   4G   0   6G                   CORN         0   0   2C,6G                                                                              3C,7G                                                                              2C,5G                                                                              3C,8H                                                                              3G  3C,7G                                                                              2C,4G                                                                              3C,8G                                                                               2C,5G                                                                              3C,7H                SOYBEAN      0   3G  3C,6G                                                                              3C,8H                                                                              3C,7H                                                                              4C,9H                                                                              6G  3C,8H                                                                              3C,6G                                                                              3C,7G                                                                               3C,7H                                                                              4C,8G                RICE         0   0   8G  9H  7G  9H  5G  8G  5G  6G   3C,7G                                                                              9H                   SORGHUM      0   0   3C,4G                                                                              3C,6G                                                                              3C,6G                                                                              9H  2C  3C,7H                                                                              5G  3C,9H                                                                               3C,8G                                                                              4C,9H                SUGAR BEETS  0   3H  7H  7G  8H  5C,9G                                                                              10C 9C  2C,5G                                                                              9G   9C  5C,9G                VELVETLEAF   0   2G  2H  6H  2G  4C,9G                                                                              3G  2C,8G                                                                              2G  5H   1H  3C,8G                GIANT FOXTAIL                                                                               0   0   0   2G  2G  3C,7G                                                                              3G  3C,5G                                                                              0   3C,3G                                                                               0   3C,3G                BARLEY       0   0   5G  5G  2G  8G  3G  6G  0   4G   0   3C,7G                DOWNY BROME  0   0   3G  7G  2G  3C,8G   3C,8G                                                                              0   3G   0   5G                   __________________________________________________________________________                                                            CMPD 97                                                           RATE = KG/HA 0.01                                                                               0.05                __________________________________________________________________________                                               POSOL                                                                          COTTON       3C,8G                                                                              5C,9G                                                         MORNING GLORY                                                                               4C,9G                                                                              10C                                                           COCKLEBUR    3G  9C                                                            NUTSEDGE     0   0                                                             CRABGRASS    0   2G                                                            BARNYARD GRASS                                                                              2C,5H                                                                              3C,8H                                                         WILD OATS    0   2G                                                            WHEAT        2G  2G                                                            CORN         4C,9G                                                                              10C                                                           SOYBEAN      4C,9G                                                                              4C,9G                                                         RICE         0   3C,7G                                                         SORGHUM      2G  3C,5G                                                         SUGAR BEETS  9C  9C                                                            VELVETLEAF   4C,9G                                                                              5C,9G                                                         GIANT FOXTAIL                                                                               2C,5G                                                                              2C,5G                                                         BARLEY       0   0                                                             DOWNY BROME  2G  2C,5G                                                         PRSOL                                                                          COTTON           2C,6G                                                         MORNING GLORY                                                                               3C,3H                                                                              8G                                                            COCKLEBUR    0   2C,2G                                                         NUTSEDGE     0   0                                                             CRABGRASS    0   0                                                             BARNYARD GRASS                                                                              0   0                                                             WILD OATS    0   0                                                             WHEAT        0   0                                                             CORN         0   3G                                                            SOYBEAN      3C,7G                                                                              3C,7G                                                         RICE         2G  5G                                                            SORGHUM      0   4G                                                            SUGAR BEETS  5G  9C                                                            VELVETLEAF   2G  3C,5H                                                         GIANT FOXTAIL                                                                               0   0                                                             BARLEY       0   0                                                             DOWNY BROME  0   0                   __________________________________________________________________________

It is noted that certain compounds (i.e., 77, 78, etc.) do not show activity at the rate tested. It is thought that these compounds would show activity at higher rates.

TEST B Postemergence

Three round pans (25 cm diameter by 12.5 cm deep) were filled with Sassafras sandy loam soil. One pan was planted with nutsedge (Cyperus rotundus) tubers, crabgrass (Digitaria sanguinalis), sicklepod (Cassia obtusifolia), jimsonweed (Datura stramonium), velvetleaf (Abutilon theophrasti), lambsquartes (Chenopodium album), rice (Oryza sativa) and teaweed (Sida spinosa). The second pot was planted with green foxtail (Setaria viridis), cocklebur (Xantium pensylvanicum), morningglory (Ipomoea hederacea), cotton (Gossypium hirsutum), johnsongrass (Sorghum halepense), barnyardgrass (Echiochloa crusgalli), corn (Zea mays), soybean (Glycine max) and giant foxtail (Setaria faberi). The third pot was planted with wheat (Triticum aestivum), barley (Hordeum vulgare), wild buckwheat (Polgonum convolvulus L.), cheatgrass (Bromus secalinus L.), sugarbeet (Beta vulgaris), wild oats (Avena fatua), viola (Viola arvensis), blackgrass (Alopecurus myosuroides), and rape (Brassica napus). The plants were grown for approximately fourteen days, then sprayed postemergence with the chemicals dissolved in a non-phytotoxic solvent.

Preemergence

Three round pans (25 cm diameter by 12.5 cm deep) were filled with Sassafras sandy loam soil. One pan was planted with nutsedge tubers, crabgrass, sicklepod, jimsonweed, velvetleaf, lambsquarters, rice and teaweed. The second pot was planted with green foxtail, cocklebur, morningglory, cotton, johnsongrass, barnyardgrass, corn, soybean and giant foxtail. The third pot was planted with wheat, barley, wild buckwheat, cheatgrass, sugarbeet, wild oat, viola, blackgrass and rape. The three pans were sprayed preemergence with the chemicals dissolved in a non-phytotoxic solvent.

Treated plants and controls were maintained in the greenhouse for 24 days, then all rated plants were compared to controls and visually rated for plant response.

Response ratings are based on a scale of 0 to 100 where 0=no effect and 100=complete control. A dash (-) response means no test.

Response ratings are contained in Table B.

                  (TEST B)                                                         ______________________________________                                         CMPD 3                                                                         RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 90     100      100  100    --                                   VELVETLEAF    70     100      100  100    --                                   SUGAR BEETS   70     100      100  100    --                                   CRABGRASS      0     30        50   70    --                                   TEAWEED       30     50        70  100    --                                   JIMSONWEED    30     60       100  100    --                                   RICE          60     90       100  100    --                                   COCKLEBUR     70     80        90  100    --                                   COTTON        30     100      100  100    --                                   SOYBEAN       90     100      100  100    --                                   BARNYARD GRASS                                                                               70     100      100  100    --                                   WILD OATS      0     30        50   80    --                                   MORNINGGLORY  30     50        70   90    --                                   WHEAT         30     50        70  100    --                                   CASSIA        30     50        70   90    --                                   JOHNSONGRASS  30     60       100  100    --                                   NUTSEDGE      100    100      100  100    --                                   CORN          90     100      100  100    --                                   WILD BUCKWHEAT                                                                               30     60        90  100    --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       60   100    --                                   VELVETLEAF    --     0        30   50     --                                   SUGAR BEETS   --     50       70   90     --                                   CRABGRASS     --     0        30   70     --                                   TEAWEED       --     0         0    0     --                                   JIMSONWEED    --     0         0   30     --                                   RICE          --     0        30   80     --                                   COCKLEBUR     --     30       60   90     --                                   COTTON        --     0         0   30     --                                   SOYBEAN       --     0        20   40     --                                   BARNYARD GRASS                                                                               --     30       50   80     --                                   WILD OATS     --     20       40   60     --                                   MORNINGGLORY  --     0         0   30     --                                   WHEAT         --     0        30   70     --                                   CASSIA        --     0         0    0     --                                   JOHNSONGRASS  --     0        30   80     --                                   NUTSEDGE      --     0        30   70     --                                   CORN          --     0        30   60     --                                   WILD BUCKWHEAT                                                                               --     50       70   90     --                                   ______________________________________                                         CMPD 4                                                                         RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 0      30       50   --     --                                   VELVETLEAF    0      30       50   --     --                                   SUGAR BEETS   0      30       60   --     --                                   CRABGRASS     0      30       50   --     --                                   TEAWEED       0      30       50   --     --                                   JIMSONWEED    0       0       30   --     --                                   RICE          0      30       60   --     --                                   COCKLEBUR     0      30       60   --     --                                   COTTON        0      20       40   --     --                                   SOYBEAN       0       0       20   --     --                                   BARNYARD GRASS                                                                               40     60       80   --     --                                   WILD OATS     0       0        0   --     --                                   MORNINGGLORY  0       0       30   --     --                                   WHEAT         0       0        0   --     --                                   CASSIA        0       0       30   --     --                                   JOHNSONGRASS  0      30       90   --     --                                   NUTSEDGE      0      30       70   --     --                                   CORN          30     60       80   --     --                                   WILD BUCKWHEAT                                                                               0      30       50   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       50   70     90                                   VELVETLEAF    --      0       20   40     60                                   SUGAR BEETS   --      0       30   60     90                                   CRABGRASS     --      0       30   50     70                                   TEAWEED       --      0       30   60     90                                   JIMSONWEED    --     50       70   90     100                                  RICE          --     30       50   80     100                                  COCKLEBUR     --     20       40   60     80                                   COTTON        --      0        0    0     60                                   SOYBEAN       --      0        0   20     30                                   BARNYARD GRASS                                                                               --     30       50   80     90                                   WILD OATS     --      0        0   30     50                                   MORNINGGLORY  --      0        0   20     30                                   WHEAT         --      0        0    0     30                                   CASSIA        --      0        0   30     60                                   JOHSONGRASS   --     30       50   70     90                                   NUTSEDGE      --      0       30   60     90                                   CORN          --      0       20   50     90                                   WILD BUCKWHEAT                                                                               --     30       50   70     90                                   ______________________________________                                         CMPD 5                                                                         RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 30     50       70   --     --                                   VELVETLEAF    30     50       70   90     --                                   SUGAR BEETS   0       0       30   --     --                                   CRABGRASS     30     50       70   90     --                                   TEAWEED       0      30       50   70     --                                   JIMSONWEED    30     50       70   100    --                                   RICE          30     50       100  100    --                                   COCKLEBUR     0      30       60   100    --                                   COTTON        0       0       30   50     --                                   SOYBEAN       0      30       60   --     --                                   BARNYARD GRASS                                                                               50     70       100  100    --                                   WILD OATS     0       0       30   --     --                                   MORNINGGLORY  0       0       30   50     --                                   WHEAT         0       0       30   --     --                                   CASSIA        30     50       70   90     --                                   JOHNSONGRASS  30     50       70   90     --                                   NUTSEDGE      0      30       60   100    --                                   CORN          70     100      100  --     --                                   WILD BUCKWHEAT                                                                               0       0       30   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       50   70     100                                  VELVETLEAF    --      0        0   30     60                                   SUGAR BEETS   --      0        0   40     90                                   CRABGRASS     --     30       50   70     90                                   TEAWEED       --      0       30   50     70                                   JIMSONWEED    --      0       30   50     70                                   RICE          --      0       30   50     80                                   COCKLEBUR     --      0        0   30     50                                   COTTON        --      0        0   30     60                                   SOYBEAN       --      0        0    0     60                                   BARNYARD GRASS                                                                               --      0       30   60     90                                   WILD OATS     --      0        0   30     70                                   MORNINGGLORY  --      0        0    0     40                                   WHEAT         --      0        0   30     80                                   CASSIA        --     30       50   70     100                                  JOHNSONGRASS  --     30       50   70     100                                  NUTSEDGE      --      0        0   30     80                                   CORN          --      0        0   40     90                                   WILD BUCKWHEAT                                                                               --     50       70   80     90                                   ______________________________________                                         CMPD 6                                                                         RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 0      30       60   --     --                                   VELVETLEAF    0      0         0   60     --                                   SUGAR BEETS   0      0        30   --     --                                   CRABGRASS     30     50       70   90     --                                   TEAWEED       0      0        30   50     --                                   JIMSONWEED    0      30       60   90     --                                   RICE          0      30       60   90     --                                   COCKLEBUR     0      0        30   70     --                                   COTTON        0      0         0   50     --                                   SOYBEAN       0      40       60   --     --                                   BARNYARD GRASS                                                                               0      30       100  100    --                                   WILD OATS     0      0         0   --     --                                   MORNINGGLORY  0      0        30   50     --                                   WHEAT         0      0         0   --     --                                   CASSIA        0      0        30   70     --                                   JOHNSONGRASS  0      30       50   100    --                                   NUTSEDGE      0      0        30   90     --                                   CORN          30     60       90   --     --                                   WILD BUCKWHEAT                                                                               0      0        30   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       50   70     90                                   VELVETLEAF    --     0         0   30     60                                   SUGAR BEETS   --     0         0    0     30                                   CRABGRASS     --     0        30   50     70                                   TEAWEED       --     0         0   30     60                                   JIMSONWEED    --     0        30   50     70                                   RICE          --     0        30   60     90                                   COCKLEBUR     --     0         0    0     30                                   COTTON        --     0         0    0     20                                   SOYBEAN       --     0         0    0     40                                   BARNYARD GRASS                                                                               --     0        30   50     80                                   WILD OATS     --     0         0   30     50                                   MORNINGGLORY  --     0         0    0     30                                   WHEAT         --     0         0   30     60                                   CASSIA        --     0         0   30     50                                   JOHNSONGRASS  --     30       60   90     100                                  NUTSEDGE      --     0         0   30     70                                   CORN          --     20       40   60     90                                   WILD BUCKWHEAT                                                                               --     0        30   60     90                                   ______________________________________                                         CMPD 6                                                                         RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 30     50       70   100    --                                   VELVETLEAF    30     50       70   100    --                                   SUGAR BEETS   30     50       70   100    --                                   CRABGRASS     0      30       50   80     --                                   TEAWEED       0      30       50   80     --                                   JIMSONWEED    30     50       70   100    --                                   RICE          0      50       70   90     --                                   COCKLEBUR     30     50       70   80     --                                   COTTON        0       0       60   90     --                                   SOYBEAN       0      30       50   80     --                                   BARNYARD GRASS                                                                               30     50       70   100    --                                   WILD OATS     0      30       50   80     --                                   MORNINGGLORY  0       0       30   80     --                                   WHEAT         0      30       50   80     --                                   CASSIA        0      30       60   80     --                                   JOHNSONGRASS  30     50       70   100    --                                   NUTSEDGE      0      30       50   100    --                                   CORN          0      50       70   90     --                                   WILD BUCKWHEAT                                                                               30     50       70   90     --                                    PREEMERGENCE                                                                  GIANT FOXTAIL --     30       --   70     90                                   VELVETLEAF    --     30       --   60     80                                   SUGAR BEETS   --     60       --   90     100                                  CRABGRASS     --     30       --   70     100                                  TEAWEED       --     30       --   70     90                                   JIMSONWEED    --     50       --   90     100                                  RICE          --     30       --   70     100                                  COCKLEBUR     --      0       --   50     100                                  COTTON        --     20       --   60     80                                   SOYBEAN       --     30       --   70     80                                   BARNYARD GRASS                                                                               --     30       --   70     90                                   WILD OATS     --     30       --   70     90                                   MORNINGGLORY  --      0       --   60     90                                   WHEAT         --     30       --   70     90                                   CASSIA        --      0       --   50     70                                   JOHNSONGRASS  --     30       --   70     100                                  NUTSEDGE      --     30       --   70     100                                  CORN          --     20       --   60     80                                   WILD BUCKWHEAT                                                                               --     60       --   80     100                                  ______________________________________                                         CMPD 9                                                                         RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 30     50       --   90     --                                   VELVETLEAF    50     70       --   100    --                                   SUGAR BEETS   70     100      --   100    --                                   CRABGRASS     0      30       --   70     --                                   TEAWEED       0      30       --   70     --                                   JIMSONWEED    0      30       --   70     --                                   RICE          30     70       --   100    --                                   COCKLEBUR     50     70       --   100    --                                   COTTON        0       0       --   70     --                                   SOYBEAN       70     90       --   100    --                                   BARNYARD GRASS                                                                               30     50       --   90     --                                   WILD OATS     0      30       --   70     --                                   MORNINGGLORY  0      0        --   50     --                                   WHEAT         0       0       --   70     --                                   CASSIA        0      30       --   70     --                                   JOHNSONGRASS  0      30       --   80     --                                   NUTSEDGE      0       0       --   50     --                                   CORN          30     50       --   70     --                                   WILD BUCKWHEAT                                                                               20     40       --   80     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       --   70     100                                  VELVETLEAF    --     30       --   80     100                                  SUGAR BEETS   --     60       --   80     90                                   CRABGRASS     --     30       --   70     90                                   TEAWEED       --     30       --   70     90                                   JIMSONWEED    --     30       --   70     100                                  RICE          --     50       --   70     90                                   COCKLEBUR     --     30       --   70     90                                   COTTON        --      0       --   30     60                                   SOYBEAN       --     30       --   60     80                                   BARNYARD GRASS                                                                               --     30       --   70     90                                   WILD OATS     --     30       --   50     70                                   MORNINGGLORY  --      0       --   50     70                                   WHEAT         --     30       --   50     70                                   CASSIA        --      0       --   50     70                                   JOHNSONGRASS  --     50       --   90     100                                  NUTSEDGE      --      0       --   50     90                                   CORN          --      0       --   50     80                                   WILD BUCKWHEAT                                                                               --     30       --   70     100                                  ______________________________________                                         CMPD 10                                                                        RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 0      0        30   --     --                                   VELVETLEAF    0      30       60   90     --                                   SUGAR BEETS   30     50       70   --     --                                   CRABGRASS     0      0        30   50     --                                   TEAWEED       0      30       50   70     --                                   JIMSONWEED    0      0        30   50     --                                   RICE          0      30       50   70     --                                   COCKLEBUR     0      0        30   50     --                                   COTTON        0      0         0   20     --                                   SOYBEAN       0      0         0   --     --                                   BARNYARD GRASS                                                                               30     50       70   90     --                                   WILD OATS     0      0         0   --     --                                   MORNINGGLORY  0      0         0   30     --                                   WHEAT         0      0         0   --     --                                   CASSIA        0      30       50   80     --                                   JOHNSONGRASS  0      30       60   90     --                                   NUTSEDGE      0      0         0    0     --                                   CORN          0      0        40   --     --                                   WILD BUCKWHEAT                                                                               0      30       50   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       50   70     90                                   VELVETLEAF    --     30       50   70     90                                   SUGAR BEETS   --     60       80   90     100                                  CRABGRASS     --     0        30   60     100                                  TEAWEED       --     30       50   70     90                                   JIMSONWEED    --     30       50   80     100                                  RICE          --     30       60   90     100                                  COCKLEBUR     --     0        30   50     70                                   COTTON        --     0         0   30     60                                   SOYBEAN       --     0         0   30     60                                   BARNYARD GRASS                                                                               --     30       50   70     90                                   WILD OATS     --     0         0   30     60                                   MORNINGGLORY  --     30       50   70     90                                   WHEAT         --     0         0   30     50                                   CASSIA        --     0        30   50     70                                   JOHNSONGRASS  --     30       60   100    100                                  NUTSEDGE      --     0        30   60     90                                   CORN          --     20       40   60     80                                   WILD BUCKWHEAT                                                                               --     50       70   90     100                                  ______________________________________                                         CMPD 11                                                                        RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 0      0        30   --     --                                   VELVETLEAF    0      30       60   100    --                                   SUGAR BEETS   0      30       60   --     --                                   CRABGRASS     0      30       60   90     --                                   TEAWEED       0      0        30   50     --                                   JIMSONWEED    30     50       70   100    --                                   RICE          0      30       60   100    --                                   COCKLEBUR     30     50       70   90     --                                   COTTON        0      0        30   60     --                                   SOYBEAN       30     60       90   --     --                                   BARNYARD GRASS                                                                               0      30       60   100    --                                   WILD OATS     0      0         0   --     --                                   MORNINGGLORY  0      0        30   90     --                                   WHEAT         0      0         0   --     --                                   CASSIA        0      30       60   100    --                                   JOHNSONGRASS  0      0        30   50     --                                   NUTSEDGE      0      0         0   0      --                                   CORN          0      0        30   --     --                                   WILD BUCKWHEAT                                                                               0      30       50   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       50   70     90                                   VELVETLEAF    --     0        30   60     90                                   SUGAR BEETS   --     50       70   90     100                                  CRABGRASS     --     70       80   90     100                                  TEAWEED       --     30       50   70     90                                   JIMSONWEED    --     30       60   90     100                                  RICE          --     40       80   90     100                                  COCKLEBUR     --     0        30   60     90                                   COTTON        --     0        30   50     70                                   SOYBEAN       --     0         0   30     70                                   BARNYARD GRASS                                                                               --     30       60   90     100                                  WILD OATS     --     0        30   50     70                                   MORNINGGLORY  --     0        30   60     90                                   WHEAT         --     0        30   60     90                                   CASSIA        --     30       50   70     100                                  JOHNSONGRASS  --     50       70   100    100                                  NUTSEDGE      --     0         0   0      0                                    CORN          --     0        30   50     70                                   WILD BUCKWHEAT                                                                               --     50       70   80     90                                   ______________________________________                                         CMPD 12                                                                        RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL --     0        30   60     --                                   VELVETLEAF    --     30       50   70     100                                  SUGAR BEETS   --     0         0   30     --                                   CRABGRASS     --     0        30   60     90                                   TEAWEED       --     0        30   50     80                                   JIMSONWEED    --     30       50   70     100                                  RICE          --     0        30   60     100                                  COCKLEBUR     --     30       60   90     90                                   COTTON        --     0        30   50     70                                   SOYBEAN       --     60       80   100    --                                   BARNYARD GRASS                                                                               --     0        30   60     100                                  WILD OATS     --     0         0    0     --                                   MORNINGGLORY  --     0        30   50     70                                   WHEAT         --     0         0    0     --                                   CASSIA        --     30       50   70     100                                  JOHNSONGRASS  --     0         0   30     90                                   NUTSEDGE      --     0         0   30     80                                   CORN          --     0        30   70     --                                   WILD BUCKWHEAT                                                                               --     0         0   30     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       70   90                                          VELVETLEAF    --     0        30   50     70                                   SUGAR BEETS   --     0        50   70     90                                   CRABGRASS     --     0        30   60     90                                   TEAWEED       --     0        30   50     80                                   JIMSONWEED    --     30       50   70     90                                   RICE          --     30       50   70     90                                   COCKLEBUR     --     0        30   60     100                                  COTTON        --     0         0   30     50                                   SOYBEAN       --     0         0   30     60                                   BARNYARD GRASS                                                                               --     0        30   60     90                                   WILD OATS     --     0         0   30     60                                   MORNINGGLORY  --     0        30   60     90                                   WHEAT         --     0         0   30     50                                   CASSIA        --     0        30   60     100                                  JOHNSONGRASS  --     30       50   70     90                                   NUTSEDGE      --     0        30   50     80                                   CORN          --     0         0   20     50                                   WILD BUCKWHEAT                                                                               --     30       50   70     90                                   ______________________________________                                         CMPD 13                                                                        RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL  0     30       50   --     --                                   VELVETLEAF    30     60       100  100    --                                   SUGAR BEETS   70     90       100  --     --                                   CRABGRASS      0     30       60   90     --                                   TEAWEED       30     50       70   90     --                                   JIMSONWEED     0     30       60   100    --                                   RICE          30     60       90   100    --                                   COCKLEBUR     30     50       70   100    --                                   COTTON         0      0       30   60     --                                   SOYBEAN       30     50       80   --     --                                   BARNYARD GRASS                                                                               30     50       100  100    --                                   WILD OATS      0      0       50   --     --                                   MORNINGGLORY   0     30       60   90     --                                   WHEAT          0     30       50   --     --                                   CASSIA        30     50       70   100    --                                   JOHNSONGRASS  30     50       70   90     --                                   NUTSEDGE       0      0       30   70     --                                   CORN          70     90       100  --     --                                   WILD BUCKWHEAT                                                                                0     30       50   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       60   90     100                                  VELVETLEAF    --     30       60   80     90                                   SUGAR BEETS   --     30       50   80     90                                   CRABGRASS     --     30       50   70     100                                  TEAWEED       --     30       50   70     90                                   JIMSONWEED    --     30       50   70     90                                   RICE          --     70       90   100    100                                  COCKLEBUR     --      0       30   60     90                                   COTTON        --     30       50   70     90                                   SOYBEAN       --      0       20   60     80                                   BARNYARD GRASS                                                                               --     30       60   90     100                                  WILD OATS     --      0       30   50     70                                   MORNINGGLORY  --      0       30   60     90                                   WHEAT         --      0       30   50     70                                   CASSIA        --     30       50   70     90                                   JOHNSONGRASS  --     70       90   100    100                                  NUTSEDGE      --      0       70   90     100                                  CORN          --      0       30   60     100                                  WILD BUCKWHEAT                                                                               --     30       50   70     90                                   ______________________________________                                         CMPD 14                                                                        RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 30     50       70   --     --                                   VELVETLEAF    50     90       100  100    --                                   SUGAR BEETS   50     70       100  --     --                                   CRABGRASS     30     50       70   100    --                                   TEAWEED       30     50       70   90     --                                   JIMSONWEED    30     60       100  100    --                                   RICE          30     60       100  100    --                                   COCKLEBUR     30     60       90   100    --                                   COTTON         0     30       60   90     --                                   SOYBEAN       70     80       90   --     --                                   BARNYARD GRASS                                                                               30     60       100  100    --                                   WILD OATS      0     30       60   --     --                                   MORNINGGLORY  50     70       90   100    --                                   WHEAT         30     50       70   --     --                                   CASSIA        30     60       90   100    --                                   JOHNSONGRASS  30     60       100  100    --                                   NUTSEDGE       0     30       60   90     --                                   CORN          70     100      100  --     --                                   WILD BUCKWHEAT                                                                               30     50       70   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     80       90   100    100                                  VELVETLEAF    --     30       60   90     100                                  SUGAR BEETS   --     70       90   100    100                                  CRABGRASS     --     30       60   80     90                                   TEAWEED       --     40       60   80     90                                   JIMSONWEED    --     50       70   80     90                                   RICE          --     50       70   90     100                                  COCKLEBUR     --     30       50   70     90                                   COTTON        --     30       50   80     90                                   SOYBEAN       --     20       50   70     90                                   BARNYARD GRASS                                                                               --     50       70   90     100                                  WILD OATS     --     20       30   60     80                                   MORNINGGLORY  --     30       50   70     90                                   WHEAT         --      0       30   50     70                                   CASSIA        --     50       70   90     100                                  JOHNSONGRASS  --     70       80   90     100                                  NUTSEDGE      --      0       50   90     100                                  CORN          --     60       80   100    100                                  WILD BUCKWHEAT                                                                               --     70       80   90     90                                   ______________________________________                                         CMPD 15                                                                        RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL 50     80       100  --     --                                   VELVETLEAF    60     100      100  100    --                                   SUGAR BEETS   100    100      100  --     --                                   CRABGRASS      0     30       50   80     --                                   TEAWEED       30     60       90   100    --                                   JIMSONWEED    30     50       70   90     --                                   RICE          50     70       100  100    --                                   COCKLEBUR     60     80       100  100    --                                   COTTON        30     50       70   100    --                                   SOYBEAN       70     90       100  --     --                                   BARNYARD GRASS                                                                               60     90       100  100    --                                   WILD OATS      0     0        50   --     --                                   MORNINGGLORY  70     90       100  100    --                                   WHEAT         30     50       70   --     --                                   CASSIA        50     70       90   100    --                                   JOHNSONGRASS  60     90       100  100    --                                   NUTSEDGE      50     70       80   90     --                                   CORN          70     100      100  --     --                                   WILD BUCKWHEAT                                                                               30     50       70   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     60       100  100    100                                  VELVETLEAF    --     50       70   90     100                                  SUGAR BEETS   --     70       80   90     100                                  CRABGRASS     --     30       50   70      90                                  TEAWEED       --     50       70   80      90                                  JIMSONWEED    --     60       80   90     100                                  RICE          --     50       80   90     100                                  COCKLEBUR     --     70       80   90     100                                  COTTON        --     40       60   80      90                                  SOYBEAN       --     30       50   80      90                                  BARNYARD GRASS                                                                               --     50       80   90     100                                  WILD OATS     --      0       30   50      80                                  MORNINGGLORY  --     50       70   90     100                                  WHEAT         --      0       30   50      90                                  CASSIA        --     30       50   70      90                                  JOHNSONGRASS  --     60       100  100    100                                  NUTSEDGE      --      0       60   90     100                                  CORN          --      0        0   60      90                                  WILD BUCKWHEAT                                                                               --     60       70   80     90                                   ______________________________________                                         CMPD 16                                                                        RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL  0      0       30   --     --                                   VELVETLEAF    30     60       100  100    --                                   SUGAR BEETS   70     90       100  --     --                                   CRABGRASS      0     30       50   80     --                                   TEAWEED       30     50       70   80     --                                   JIMSONWEED    30     60       90   100    --                                   RICE          30     60       100  100    --                                   COCKLEBUR     30     50       70   100    --                                   COTTON         0      0       0    60     --                                   SOTBEAN        40    30       60   --     --                                   BARNYARD GRASS                                                                               30     60       90   100    --                                   WILD OATS      0      0       0    --     --                                   MORNINGGLORY  30     50       70   90     --                                   WHEAT          0      0       0    --     --                                   CASSIA         0     30       50   80     --                                   JOHNSONGRASS  30     60       100  100    --                                   NUTSEDGE      30     50       70   90     --                                   CORN          70     100      100  --     --                                   WILD BUCKWHEAT                                                                                0     30       50   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       50   80     100                                  VELVETLEAF    --     30       50   80     90                                   SUGAR BEETS   --     70       80   90     100                                  CRABGRASS     --      0       30   60     90                                   TEAWEED       --     60       80   100    100                                  JIMSONWEED    --     50       70   80     90                                   RICE          --     70       80   90     100                                  COCKLEBUR     --      0       30   60     80                                   COTTON        --     30       50   70     90                                   SOYBEAN       --      0       30   60     80                                   BARNYARD GRASS                                                                               --     30       60   90     100                                  WILD OATS     --      0        0   30     70                                   MORNINGGLORY  --     30       50   80     90                                   WHEAT         --      0        0   30     50                                   CASSIA        --     30       50   80     90                                   JOHNSONGRASS  --     60       90   100    100                                  NUTSEDGE      --      0       50   80     100                                  CORN          --     30       50   70     90                                   WILD BUCKWHEAT                                                                               --     50       70   80     90                                   ______________________________________                                         CMPD 17                                                                        RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL  0      0       40   --     --                                   VELVETLEAF    30     70       100  100    --                                   SUGAR BEETS   90     100      100  --     --                                   CRABGRASS     30     50       70   90     --                                   TEAWEED        0     30       50   80     --                                   JIMSONWEED    50     70       90   100    --                                   RICE          30     90       100  100    --                                   COCKLEBUR     50     70       90   100    --                                   COTTON         0      0       40   70     --                                   SOTBEAN       40     80       90   --     --                                   BARNYARD GRASS                                                                               30     60       100  100    --                                   WILD OATS      0      0       30   --     --                                   MORNINGGLORY  30     60       70   90     --                                   WHEAT         40     80       100  --     --                                   CASSIA        30     50       90   100    --                                   JOHNSONGRASS  30     60       100  100    --                                   NUTSEDGE       0     30       50   70     --                                   CORN          70     100      100  --     --                                   WILD BUCKWHEAT                                                                                0     30       50   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       60   90     100                                  VELVETLEAF    --     50       70   90     100                                  SUGAR BEETS   --     70       90   100    100                                  CRABGRASS     --     30       60   90     100                                  TEAWEED       --     30       50   70      90                                  JIMSONWEED    --     70       90   90     100                                  RICE          --     80       90   100    100                                  COCKLEBUR     --     50       70   90     100                                  COTTON        --      0       30   60      90                                  SOYBEAN       --     30       50   80      90                                  BARNYARD GRASS                                                                               --     70       90   100    100                                  WILD OATS     --      0       30   50      80                                  MORNINGGLORY  --     50       70   80      90                                  WHEAT         --      0       30   60      90                                  CASSIA        --     50       70   100    100                                  JOHNSONGRASS  --     70       90   100    100                                  NUTSEDGE      --      0       30   50      70                                  CORN          --      0        0   70      90                                  WILD BUCKWHEAT                                                                               --     50       70   80      90                                  ______________________________________                                         CMPD 18                                                                        RATE RATE = G/HA                                                                             0001   0004     0016 0062   0250                                 ______________________________________                                         POSTEMERGENCE                                                                  GIANT FOXTAIL  0     30       50   --     --                                   VELVETLEAF    30     50       70   90     --                                   SUGAR BEETS   30     50       70   --     --                                   CRABGRASS     30     50       70   90     --                                   TEAWEED       30     50       70   90     --                                   JIMSONWEED    30     50       70   90     --                                   RICE          30     60       90   100    --                                   COCKLEBUR     30     50       70   100    --                                   COTTON         0     30       50   70     --                                   SOYBEAN       30     70       90   --     --                                   BARNYARD GRASS                                                                               30     50       70   100    --                                   WILD OATS      0      0       30   --     --                                   MORNINGGLORY  30     50       70   90     --                                   WHEAT          0      0        0   --     --                                   CASSIA        30     60       90   100    --                                   JOHNSONGRASS  30     60       90   100    --                                   NUTSEDGE       0     30       50   70     --                                   CORN          50     70       100  --     --                                   WILD BUCKWHEAT                                                                                0      0       30   --     --                                   PREEMERGENCE                                                                   GIANT FOXTAIL --     30       50   70     100                                  VELVETLEAF    --     30       50   70     90                                   SUGAR BEETS   --     30       50   70     90                                   CRABGRASS     --      0       30   60     90                                   TEAWEED       --     30       50   70     90                                   JIMSONWEED    --     30       50   80     90                                   RICE          --     50       70   90     100                                  COCKLEBUR     --      0        0   30     80                                   COTTON        --      0       30   50     80                                   SOYBEAN       --      0       30   60     90                                   BARNYARD GRASS                                                                               --     30       50   70     100                                  WILD OATS     --      0         0  30     70                                   MORNINGGLORY  --     30       50   70     90                                   WHEAT         --      0        0   30     50                                   CASSIA        --     30       50   70     100                                  JOHNSONGRASS  --     50       70   100    100`                                 NUTSEDGE      --      0        0   30     80                                   CORN          --      0       30   60     100                                  WILD BUCKWHEAT                                                                               --     30       50   70     90                                   ______________________________________                                     

What is claimed is:
 1. A compound selected from ##STR69## wherein E is CH₂ or a single bond;W is O or S; R is H or CH₃ ; R_(X) is H, F, Cl, CH₃, OCH₃, N(CH₃)₂ or OCHF₂ ; R₁ is F, Cl, Br, NO₂, C₁ -C₄ alkyl, C₂ -C₄ alkenyl, C₂ -C₄ haloalkenyl, C₂ -C₄ alkynyl, C₁ -C₄ haloalkyl, C₁ -C₄ akloxy, OCH₂ CH₂ OCH₃, C₁ -C₄ haloalkoxy, C₃ -C₄ alkenyloxy, C₂ -C₄ haloalkenyloxy, C₃ -C₄ alkynyloxy, CO₂ R₃, CONR₄ R₅, SO₂ NR₄ 'R₅ ', S(O)_(n) R₆, OSO₂ R₇, C₁ -C₂ alkyl substituted with C₁ -C₂ alkoxy, OH or C₁ -C₂ alkylthio, CH₂ CN, C₆ H₅, ##STR70## R₂ is ##STR71## R₃ is C₁ -C₄ alkyl, C₃ -C₄ alkenyl, C₃ -C₄ or alkynyl, ##STR72## CH₂ CH₂ Cl, CH₂ CH₂ F, C₁ -C₂ alkyl substituted with OCH₃, SCH₃ or CN; R₄ is C₁ -C₃ alkyl or C₁ -C₂ alkoxy; R₄ ' is C₁ -C₃ alkyl or C₁ -C₂ alkoxy; R₅ is H or C₁ -C₃ alkyl; R₅ ' is H or C₁ -C₃ alkyl; R₄ and R₅ may be taken together to form --(CH₂)₃ -- or --(CH₂)₄ --; R₄ ' and R₅ ' may be taken together to form --(CH₂)₃ -- or --(CH₂)₄ --; R₆ is C₁ -C₃ alkyl, --CH₂ CH═CH₂ or CH₂ C.tbd.CH; R₇ is C₁ -C₃ alkyl or N(CH₃)₂ ; R₈ is H, C₁ -C₄ alkyl, C₃ -C₄ alkenyl, C₃ -C₄ alkynyl, CH₂ CH₂ Cl, CH₂ CH₂ F, C₁ -C₂ alkyl substituted with OCH₃ or SCH₃ or C₃ -C₆ cycloalkyl; R₉ is C₁ -C₂ alkyl; R₁₀ and R₁₁ are independently C₁ -C₂ alkyl, C₁ -C₂ alkoxy, C₁ -C₂ alkylthio, NHCH₃ or N(CH₃)₂ ; R₁₂ and R₁₃ are independently H or C₁ -C₂ alkyl; R₁₄ is C₁ -C₃ alkyl; R₁₅ is H or CH₃ ; R₁₆ is H, C₁ -C₂ alkyl or F; R₁₇ is H or C₁ -C₂ alkyl; R₁₇ ' is H, C₁ -C₂ alkyl, CN, Cl, OCH₃, SCH₃ or N(CH₃)₂ ; R₁₈ is C₁ -C₂ alkyl; R₁₉ is H, Si(CH₃)₃ or C₁ -C₂ alkyl; R₂₀ is H or C₁ -C₂ alkyl; R₂₁ is H, C₁ -C₃ alkyl or allyl; R₂₂ is C₁ -C₂ alkyl or C₁ -C₂ haloalkyl; R₂₃ is H, CH₃, Cl or Br; R₂₄ is H or CH₃ ; p is 1 or 2; n is 0, 1 or 2; A is ##STR73## X is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ haloalkyl, C₁ -C₄ haloalkylthio, C₁ -C₄ alkylthio, halogen, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino or di(C₁ -C₃ alkyl)amino; Y is H, C₁ -C₄ alkyl, C₁ -C₄ alkoxy, C₁ -C₄ haloalkoxy, C₁ -C₄ haloalkylthio, C₁ -C₄ alkylthio, C₂ -C₅ alkoxyalkyl, C₂ -C₅ alkoxyalkoxy, amino, C₁ -C₃ alkylamino, di(C₁ -C₃ alkyl)amino, C₃ -C₄ alkenyloxy, C₃ -C₄ alkynyloxy, C₂ -C₅ alkylthioalkyl, C₂ -C₅ alkylsulfinylalkyl, C₂ -C₅ alkylsulfonylalkyl, C₁ -C₄ haloalkyl, C₂ -C₄ alkynyl, C₃ -C₅ cycloalkyl, azido, cyano, ##STR74## m is 2 or 3: Q₁ and Q₂ are independently O or S; R_(a) is H or C₁ -C₃ alkyl; R_(b) and R_(c) are independently C₁ -C₃ alkyl; and Z is CH, CCH₃, CC₂ H₅, CCl or CBr;and their agriculturally suitable salts; provided that (1) when X is halogen, then Z is CH and Y is OCH₃, OC₂ H₅, NH₂, NHCH₃, N(CH₃)₂, OCF₂ H, OCF₂ Br or N(OCH₃)CH₃ ; (2) when X or Y is C₁ haloalkoxy, then Z is CH; (3) when W is S, then R is H, Z is CH and Y is CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃, C₂ H₅, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CH(OCH₃)₂ or ##STR75## (4) when the total number of carbon atoms of X and Y is greater than four, then the combined number of carbons of R₁ and R₂ is less than or equal to six; (5) when R₂ is --C(O)R₁₇, --C(R₂₃)(R₁₇)Cl or --C(R₂₄)(R₁₇)Br then Y is other than cyclopropyl; (6) when Y is C₂ -C₅ alkylthioalkyl, C₂ -C₅ alkylsulfinylalkyl or C₂ -C₅ alkylsulfonylalkyl, then R₂ is other than --CH(R₁₇)NO₂, ##STR76## (7) when R₄ ' is C₁ -C₂ alkoxy and R₅ ' is H, then R₂ is other than CH(R₁₇)CN, C(R₂₃)(R₁₇)Cl and C(R₂₄)(R₁₇)Br; (8) when R₂ is C(O)R₁₇, C(R₂₃)(R₁₇)Cl or C(R₂₄)(R₁₇)Br, then R₁ is other than C₁ -C₄ haloalkyl or C₂ alkyl substituted with C₁ -C₂ alkoxy, OH or C₁ -C₂ alkylthio; (9) when R₂ is C(R₂₃)(R₁₇)Cl or C(R₂₄)(R₁₇)Br, then X and Y are other than C₁ -C₄ haloalkoxy or C₁ -C₄ haloalkylthio; (10) when R₂ is C(R₂₃)(R₁₇)Cl or C(R₂₄)(R₁₇)Br, then R₁ is other than C₁ -C₄ haloalkoxy, C₃ -C₄ alkenyloxy, C₂ -C₄ haloalkenyloxy, C₂ -C₄ alkynyl, C₃ -C₄ alkynyloxy, C₂ -C₄ haloalkenyl and R₁ --A through R₁ --W; (11) when R₁ is R₁ --X, R₁ --Y, R₁ --Z, R₁ --AA, R₁ --AB, R₁ --AC or R₁ --AD, then R₂ is other than CH(R₁₆)CN, C(R₂₃)--(R₁₇)Cl and C(R₂₄)(R₁₇)Br; (12) when R₂ is C(O)R₁₇, then R₁ is other than SO₂ NR₄ 'R₅ '; and (13) when R₂ is CO₂ R₃, then both R₁₂ and R₁₃ are other than H.
 2. A compound of claim 1 whereW is O.
 3. A compound of claim 2 whereE is a single bond; X is C₁ -C₂ alkyl, C₁ -C₂ alkoxy, Cl, F, Br, I, OCF₂ H, CH₂ F, CF₃, OCH₂ CH₂ F, OCH₂ CHF₂, OCH₂ CF₃, CH₂ Cl or CH₂ Br; and Y is H, C₁ -C₂ alkyl, C₁ -C₂ alkoxy, CH₂ OCH₃, CH₂ OCH₂ CH₃, NHCH₃, N(OCH₃)CH₃, N(CH₃)₂, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CH₂ SCH₃, ##STR77## OCF₂ H, SCF₂ H, OCF₂ Br, cyclopropyl, C.tbd.CH or C.tbd.CCH₃ ; Z is CH; R_(a) is H or CH₃ ; R₂₃ is H; and R₂₄ is H.
 4. A compound of claim 3 whereR₂ is --CH₂ CN, --CH₂ N₃, ##STR78## R₁₇ ' is H, C₁ -C₂ alkyl, Cl or CN.
 5. A compound of claim 4 whereR₁ is F, Cl, Br, NO₂, C₁ -C₃ alkyl, C₁ -C₂ alkyl substituted with 1-3 F or Cl or 1 Br, C₂ -C₃ alkenyl, C₂ -C₃ alkenyl substituted with 1-3 F or Cl, C₁ -C₂ alkoxy, C₁ -C₂ alkoxy substituted with 1-3 F or Cl or 1-Br, allyloxy, propargyloxy, OC(Cl)═CHCl, CO₂ CH₃, CO₂ C₂ H₅, CO₂ CH₂ CH═CH₂, CO₂ CH₂ CH₂ Cl, CO₂ CH₂ CH₂ OCH₃, CONH(C₁ -C₂ alkyl), CONCH₃ (C₁ -C₂ alkyl), SO₂ N(OCH₃)CH₃, SO₂ NH(C₁ -C₂ alkyl), SO₂ N(C₁ -C₂ alkyl)₂, S(O)_(n) C₁ -C₃ alkyl, OSO₂ C₁ -C₃ alkyl, C₁ -C₂ alkyl substituted with OCH.sub. 3 or SCH₃, C₆ H₅ and R₁ --A, R₁ --B, R₁ --C, R₁ --D, R₁ --E, R₁ --F, R₁ --G, R₁ --H, R₁ --I, R₁ --J, R₁ --K, R₁ --L, R₁ --M, R₁ --N, R₁ --O, R₁ --P, R₁ --Q, R₁ --R, R₁ --S, R₁ --T, R₁ --U, R₁ --V, R₁ --W, R₁ --X, R₁ --Y, R₁ --Z, R₁ --AA, R₁ --AB, R₁ --AC or R₁ --AD.
 6. A compound of claim 5 whereX is CH₃, OCH₃, OCH₂ CH₃, Cl, OCF₂ H or OCH₂ CF₃ ; and Y is CH₃, OCH₃, C₂ H₅, CH₂ OCH₃, NHCH₃ or CH(OCH₃)₂.
 7. A compound of claim 6 whereR is H; R₁ is F, Cl, Br, NO₂, CH₃, CF₃ C₁ -C₂ alkoxy, allyloxy, OC(Cl)═CHCl, CO₂ CH₃, CO₂ C₂ H₅, CO₂ NHCH₃, CO₂ N(CH₃)₂, SO₂ NHCH₃ SO₂ N(CH₃)₂, SO₂ CH₃, SO₂ C₂ H₅, OSO₂ CH₃, OSO₂ C₂ H₅, R₁ --A, R₁ --B, R₁ --C, R₁ --X, R₁ --Z or R₁ --AB; and R_(X) is H.
 8. The compound of claim 1 that is 2-(cyanomethyl)-6-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]aminosulfonyl]benzoic acid, ethyl ester.
 9. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 1 and at least one of the following: surfactant, solid inert diluent or liquid inert diluent and mixtures of the foregoing.
 10. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 2 and at least one of the following: surfactant, solid inert diluent or liquid inert diluent and mixtures of the foregoing.
 11. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 3 and at least one of the following: surfactant, solid inert diluent or liquid inert diluent and mixtures of the foregoing.
 12. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 4 and at least one of the following: surfactant, solid inert diluent or liquid inert diluent and mixtures of the foregoing.
 13. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 5 and at least one of the following: surfactant, solid inert diluent or liquid inert diluent and mixtures of the foregoing.
 14. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 6 and at least one of the following: surfactant, solid inert diluent or liquid inert diluent and mixtures of the foregoing.
 15. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of a compound of claim 7 and at least one of the following: surfactant, solid inert diluent or liquid inert diluent and mixtures of the foregoing.
 16. A composition suitable for controlling the growth of undesired vegetation which comprises an effective amount of the compound of claim 8 and at least one of the following: surfactant, solid inert diluent or liquid inert diluent and mixtures of the foregoing.
 17. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 1. 18. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 2. 19. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 3. 20. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 4. 21. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 5. 22. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 6. 23. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of a compound of claim
 7. 24. A method for controlling the growth of undesired vegetation which comprises applying to the locus to be protected an effective amount of the compound of claim
 8. 